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Cas Database |
| Name |
3,3-Dichloro-1,1,1,2,2-pentafluoropropane |
EINECS | 207-016-9 |
| CAS No. | 422-56-0 | Density | 1.55 |
| PSA | 0.00000 | LogP | 2.98770 |
| Solubility | N/A | Melting Point |
-94 ºC |
| Formula | C3H Cl2 F5 | Boiling Point | 53.3 °C at 760 mmHg |
| Molecular Weight | 202.939 | Flash Point | °C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Low toxicity ingestion, inhalation, and skin contact. When heated to decomposition it emits toxic vapors of F− and Cl−. | Risk Codes | 20/21/22-59 |
| Molecular Structure |
|
Hazard Symbols | Low toxicity ingestion, inhalation, and skin contact. |
| Synonyms |
1,1,1,2,2-Pentafluoro-3,3-dichloropropane;1,1-Dichloro-2,2,3,3,3-pentafluoropropane; 3,3-Dichloro-1,1,1,2,2-pentafluoropropane;Fron 225; HCFC 225ca; R 225b; R 225ca |
Article Data | 9 |
3,3-Dichloro-1,1,1,2,2-pentafluoropropane Synthetic route
- 422-54-8
1,1,3-trichloro-2,2,3,3-tetrafluoropropane
A
- 422-57-1
3-chloro-1,1,1,2,2,3-hexafluoropropane
B
- 422-55-9
1-chloro-1,1,2,2,3,3-hexafluoropropane
C
- 422-56-0
3,3-dichloro-1,1,1,2,2-pentafluoropropane
D
- 507-55-1
1,3-dichloro-1,1,2,2,3-pentafluoropropane
| Conditions | Yield |
|---|---|
| With hydrogen fluoride; chromium(III) oxide at 280℃; | A 3% B 16% C 5% D 44% |
- 75-45-6
Chlorodifluoromethane
- 79-38-9
Chlorotrifluoroethylene
A
- 422-56-0
3,3-dichloro-1,1,1,2,2-pentafluoropropane
B
- 507-55-1
1,3-dichloro-1,1,2,2,3-pentafluoropropane
C
- 422-54-8
1,1,3-trichloro-2,2,3,3-tetrafluoropropane
D
- 422-47-9
1,1,2-trichloro-2,3,3,3-tetrafluoropropane
| Conditions | Yield |
|---|---|
| With aluminium trichloride at 0 - 10℃; for 10h; Further byproducts given; | A 0.6% B 12.4% C 30.5% D 12.5% |
| Conditions | Yield |
|---|---|
| With water; chlorine Irradiation.mit UV-Licht; |
- 422-02-6
3-chloro-1,1,1,2,2-pentafluoropropane
A
- 422-56-0
3,3-dichloro-1,1,1,2,2-pentafluoropropane
B
- 4259-43-2
1,1,1-trichloro-2,2,3,3,3-pentafluoropropane
| Conditions | Yield |
|---|---|
| With chlorine at 250℃; |
- 422-58-2
3-chloro-1,1,1,2,2-pentafluoro-3-iodo-propane
- 422-56-0
3,3-dichloro-1,1,1,2,2-pentafluoropropane
| Conditions | Yield |
|---|---|
| With chlorine Irradiation; |
- 422-58-2
3-chloro-1,1,1,2,2-pentafluoro-3-iodo-propane
- 7782-50-5
chlorine
- 422-56-0
3,3-dichloro-1,1,1,2,2-pentafluoropropane
| Conditions | Yield |
|---|---|
| im UV-Licht; |
- 4259-43-2
1,1,1-trichloro-2,2,3,3,3-pentafluoropropane
A
- 422-02-6
3-chloro-1,1,1,2,2-pentafluoropropane
B
- 1599-41-3
2,2,3-trichloro-1,1,1,3,3-pentafluoropropane
C
- 754-12-1
2,3,3,3-tetrafluoro-propene
D
- 422-56-0
3,3-dichloro-1,1,1,2,2-pentafluoropropane
E
- 422-86-6
perfluoropropyl chloride
F
- 421-48-7
1,1,1,2-tetrafluoropropane
G
- 677-55-4
1-chloro-1,1,2,2,3-pentafluoropropane
I
- 162763-52-2
3,4-dichlorodecafluorohex-3-ene
J
- 1814-88-6
1,1,1,2,2-pentafluoropropane
| Conditions | Yield |
|---|---|
| With hydrogen fluoride; hydrogen; fluorided Pd on Al2O3 at 350℃; Product distribution / selectivity; |
- 4259-43-2
1,1,1-trichloro-2,2,3,3,3-pentafluoropropane
A
- 422-02-6
3-chloro-1,1,1,2,2-pentafluoropropane
B
- 1599-41-3
2,2,3-trichloro-1,1,1,3,3-pentafluoropropane
C
- 421-07-8
1,1,1-trifluoropropane
D
- 422-56-0
3,3-dichloro-1,1,1,2,2-pentafluoropropane
E
- 422-86-6
perfluoropropyl chloride
F
- 421-48-7
1,1,1,2-tetrafluoropropane
G
- 677-55-4
1-chloro-1,1,2,2,3-pentafluoropropane
H
- 1814-88-6
1,1,1,2,2-pentafluoropropane
| Conditions | Yield |
|---|---|
| With hydrogen; fluorided platinum on aluminum oxide at 250℃; Product distribution / selectivity; |
- 4259-43-2
1,1,1-trichloro-2,2,3,3,3-pentafluoropropane
A
- 422-02-6
3-chloro-1,1,1,2,2-pentafluoropropane
B
- 1599-41-3
2,2,3-trichloro-1,1,1,3,3-pentafluoropropane
C
- 754-12-1
2,3,3,3-tetrafluoro-propene
D
- 422-56-0
3,3-dichloro-1,1,1,2,2-pentafluoropropane
E
- 422-86-6
perfluoropropyl chloride
F
- 677-55-4
1-chloro-1,1,2,2,3-pentafluoropropane
H
- 162763-52-2
3,4-dichlorodecafluorohex-3-ene
I
- 1814-88-6
1,1,1,2,2-pentafluoropropane
| Conditions | Yield |
|---|---|
| With hydrogen fluoride; hydrogen; fluorided Pd on Al2O3 at 350℃; Product distribution / selectivity; |
- 507-55-1
1,3-dichloro-1,1,2,2,3-pentafluoropropane
A
- 422-56-0
3,3-dichloro-1,1,1,2,2-pentafluoropropane
B
- 128903-21-9
2,2-dichloro-1,1,1,3,3-pentafluoropropane
| Conditions | Yield |
|---|---|
| aluminum (III) chloride; trichlorofluoromethane at 0 - 50℃; Product distribution / selectivity; |
3,3-Dichloro-1,1,1,2,2-pentafluoropropane Chemical Properties
Molecular Formula: C3HCl2F5
Molecular Weight: 202.94
EINECS: 207-016-9
Melting Point: -94°C
Density: 1.578 g/cm3
Index of Refraction: 1.331
CAS Registry Number: 422-56-0
Enthalpy of Vaporization: 28.42 kJ/mol
Boiling Point: 53.3 °C at 760 mmHg
Vapour Pressure: 270 mmHg at 25°C
Appearance: Colorless odorless liquid.
Air & Water Reactions: Slightly soluble in water.
IUPAC Name: 3,3-dichloro-1,1,1,2,2-pentafluoropropane
Synonyms: HCFC-225CA ; Dichloropentafluoropropane ; 1,1,1,2,2-pentafluoro-3,3-dichloropropane ; 1,1-Dichlor-2,2,3,3,3-pentafluorpropane ; 1,1-Dichloro-2,2,3,3,3-pentafluoropropane(HCFC-225ca) ; 3,3-dichloro-1,1,1,2,2-pentafluoropropane
Following is the molecular structure of 3,3-Dichloro-1,1,1,2,2-pentafluoropropane (CAS NO. 422-56-0):
.gif)
3,3-Dichloro-1,1,1,2,2-pentafluoropropane Production
Reactivity Profile: 3,3-Dichloro-1,1,1,2,2-pentafluoropropane (CAS NO. 422-56-0) is chemically inert in many situations, but can react violently with strong reducing agents such as the very active metals and the active metals. They suffer oxidation with strong oxidizing agents and under extremes of temperature. Strong bases may release toxic gases.
3,3-Dichloro-1,1,1,2,2-pentafluoropropane Toxicity Data With Reference
| 1. | orl-rat LD50:>5 g/kg | IJTOFN International Journal of Toxicology. 19 (2000),367. | ||
| 2. | ihl-rat LC50:37,300 ppm/4H | JJATDK JAT, Journal of Applied Toxicology. 19 (1999),101. | ||
| 3. | skn-rat LD50:>2 g/kg | IJTOFN International Journal of Toxicology. 19 (2000),367. |
3,3-Dichloro-1,1,1,2,2-pentafluoropropane Safety Profile
Low toxicity ingestion, inhalation, and skin contact. When heated to decomposition it emits toxic vapors of F− and Cl−.
Safety Information of 3,3-Dichloro-1,1,1,2,2-pentafluoropropane (CAS NO. 422-56-0):
Hazard Codes: Xi 
Risk Statements: 20/21/22-59
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed.
R59: Dangerous to the ozone layer.
Safety Statements: 23-36/37/39
S23: Do not breathe vapour.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: 3082
Hazard Note: Irritant
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