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422-56-0

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Basic Information
CAS No.: 422-56-0
Name: 3,3-Dichloro-1,1,1,2,2-pentafluoropropane
Article Data: 9
Molecular Structure:
Molecular Structure of 422-56-0 (3,3-Dichloro-1,1,1,2,2-pentafluoropropane)
Formula: C3H Cl2 F5
Molecular Weight: 202.939
Synonyms: 1,1,1,2,2-Pentafluoro-3,3-dichloropropane;1,1-Dichloro-2,2,3,3,3-pentafluoropropane; 3,3-Dichloro-1,1,1,2,2-pentafluoropropane;Fron 225; HCFC 225ca; R 225b; R 225ca
EINECS: 207-016-9
Density: 1.55
Melting Point: -94 ºC
Boiling Point: 53.3 °C at 760 mmHg
Flash Point: °C
Hazard Symbols: Low toxicity ingestion, inhalation, and skin contact.
Risk Codes: 20/21/22-59
Safety: Low toxicity ingestion, inhalation, and skin contact. When heated to decomposition it emits toxic vapors of F− and Cl−.
PSA: 0.00000
LogP: 2.98770
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Synthetic route
422-54-8

1,1,3-trichloro-2,2,3,3-tetrafluoropropane

A

422-57-1

3-chloro-1,1,1,2,2,3-hexafluoropropane

B

422-55-9

1-chloro-1,1,2,2,3,3-hexafluoropropane

C

422-56-0

3,3-dichloro-1,1,1,2,2-pentafluoropropane

D

507-55-1

1,3-dichloro-1,1,2,2,3-pentafluoropropane

Conditions
ConditionsYield
With hydrogen fluoride; chromium(III) oxide at 280℃;A 3%
B 16%
C 5%
D 44%
...Expand
75-45-6

Chlorodifluoromethane

79-38-9

Chlorotrifluoroethylene

A

422-56-0

3,3-dichloro-1,1,1,2,2-pentafluoropropane

B

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1,3-dichloro-1,1,2,2,3-pentafluoropropane

C

422-54-8

1,1,3-trichloro-2,2,3,3-tetrafluoropropane

D

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1,1,2-trichloro-2,3,3,3-tetrafluoropropane

Conditions
ConditionsYield
With aluminium trichloride at 0 - 10℃; for 10h; Further byproducts given;A 0.6%
B 12.4%
C 30.5%
D 12.5%
...Expand
422-02-6

3-chloro-1,1,1,2,2-pentafluoropropane

422-56-0

3,3-dichloro-1,1,1,2,2-pentafluoropropane

Conditions
ConditionsYield
With water; chlorine Irradiation.mit UV-Licht;
422-02-6

3-chloro-1,1,1,2,2-pentafluoropropane

A

422-56-0

3,3-dichloro-1,1,1,2,2-pentafluoropropane

B

4259-43-2

1,1,1-trichloro-2,2,3,3,3-pentafluoropropane

Conditions
ConditionsYield
With chlorine at 250℃;
422-58-2

3-chloro-1,1,1,2,2-pentafluoro-3-iodo-propane

422-56-0

3,3-dichloro-1,1,1,2,2-pentafluoropropane

Conditions
ConditionsYield
With chlorine Irradiation;
422-58-2

3-chloro-1,1,1,2,2-pentafluoro-3-iodo-propane

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chlorine

422-56-0

3,3-dichloro-1,1,1,2,2-pentafluoropropane

Conditions
ConditionsYield
im UV-Licht;
4259-43-2

1,1,1-trichloro-2,2,3,3,3-pentafluoropropane

A

422-02-6

3-chloro-1,1,1,2,2-pentafluoropropane

B

1599-41-3

2,2,3-trichloro-1,1,1,3,3-pentafluoropropane

C

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2,3,3,3-tetrafluoro-propene

D

422-56-0

3,3-dichloro-1,1,1,2,2-pentafluoropropane

E

422-86-6

perfluoropropyl chloride

F

421-48-7

1,1,1,2-tetrafluoropropane

G

677-55-4

1-chloro-1,1,2,2,3-pentafluoropropane

H

C2F5CH=CClC2F5

I

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3,4-dichlorodecafluorohex-3-ene

J

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1,1,1,2,2-pentafluoropropane

Conditions
ConditionsYield
With hydrogen fluoride; hydrogen; fluorided Pd on Al2O3 at 350℃; Product distribution / selectivity;
...Expand
4259-43-2

1,1,1-trichloro-2,2,3,3,3-pentafluoropropane

A

422-02-6

3-chloro-1,1,1,2,2-pentafluoropropane

B

1599-41-3

2,2,3-trichloro-1,1,1,3,3-pentafluoropropane

C

421-07-8

1,1,1-trifluoropropane

D

422-56-0

3,3-dichloro-1,1,1,2,2-pentafluoropropane

E

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perfluoropropyl chloride

F

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1,1,1,2-tetrafluoropropane

G

677-55-4

1-chloro-1,1,2,2,3-pentafluoropropane

H

1814-88-6

1,1,1,2,2-pentafluoropropane

Conditions
ConditionsYield
With hydrogen; fluorided platinum on aluminum oxide at 250℃; Product distribution / selectivity;
...Expand
4259-43-2

1,1,1-trichloro-2,2,3,3,3-pentafluoropropane

A

422-02-6

3-chloro-1,1,1,2,2-pentafluoropropane

B

1599-41-3

2,2,3-trichloro-1,1,1,3,3-pentafluoropropane

C

754-12-1

2,3,3,3-tetrafluoro-propene

D

422-56-0

3,3-dichloro-1,1,1,2,2-pentafluoropropane

E

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perfluoropropyl chloride

F

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1-chloro-1,1,2,2,3-pentafluoropropane

G

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H

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3,4-dichlorodecafluorohex-3-ene

I

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Conditions
ConditionsYield
With hydrogen fluoride; hydrogen; fluorided Pd on Al2O3 at 350℃; Product distribution / selectivity;
...Expand
507-55-1

1,3-dichloro-1,1,2,2,3-pentafluoropropane

A

422-56-0

3,3-dichloro-1,1,1,2,2-pentafluoropropane

B

128903-21-9

2,2-dichloro-1,1,1,3,3-pentafluoropropane

Conditions
ConditionsYield
aluminum (III) chloride; trichlorofluoromethane at 0 - 50℃; Product distribution / selectivity;
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  • 3,3-Dichloro-1,1,1,2,2-pentafluoropropane

  • Casno:

    422-56-0

    3,3-Dichloro-1,1,1,2,2-pentafluoropropane

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    high purity Application:Drug intermediates Materials intermediates and active molecules

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Chemistry

Molecular Formula: C3HCl2F5
Molecular Weight: 202.94
EINECS: 207-016-9
Melting Point: -94°C
Density: 1.578 g/cm3
Index of Refraction: 1.331
CAS Registry Number: 422-56-0
Enthalpy of Vaporization: 28.42 kJ/mol 
Boiling Point: 53.3 °C at 760 mmHg 
Vapour Pressure: 270 mmHg at 25°C 
Appearance: Colorless odorless liquid.
Air & Water Reactions: Slightly soluble in water.
IUPAC Name: 3,3-dichloro-1,1,1,2,2-pentafluoropropane
Synonyms: HCFC-225CA ; Dichloropentafluoropropane ; 1,1,1,2,2-pentafluoro-3,3-dichloropropane ; 1,1-Dichlor-2,2,3,3,3-pentafluorpropane ; 1,1-Dichloro-2,2,3,3,3-pentafluoropropane(HCFC-225ca) ; 3,3-dichloro-1,1,1,2,2-pentafluoropropane
Following is the molecular structure of 3,3-Dichloro-1,1,1,2,2-pentafluoropropane (CAS NO. 422-56-0):

Production

Reactivity Profile: 3,3-Dichloro-1,1,1,2,2-pentafluoropropane (CAS NO. 422-56-0) is chemically inert in many situations, but can react violently with strong reducing agents such as the very active metals and the active metals. They suffer oxidation with strong oxidizing agents and under extremes of temperature. Strong bases may release toxic gases.

Toxicity Data With Reference

1.    

orl-rat LD50:>5 g/kg

     IJTOFN    International Journal of Toxicology. 19 (2000),367.
2.    

ihl-rat LC50:37,300 ppm/4H

     JJATDK    JAT, Journal of Applied Toxicology. 19 (1999),101.
3.    

skn-rat LD50:>2 g/kg

     IJTOFN    International Journal of Toxicology. 19 (2000),367.

Safety Profile

Low toxicity ingestion, inhalation, and skin contact. When heated to decomposition it emits toxic vapors of F− and Cl−.
Safety Information of 3,3-Dichloro-1,1,1,2,2-pentafluoropropane (CAS NO. 422-56-0):
Hazard Codes: Xi Irritant
Risk Statements: 20/21/22-59 
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. 
R59: Dangerous to the ozone layer.
Safety Statements: 23-36/37/39
S23: Do not breathe vapour. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: 3082
Hazard Note: Irritant