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Name |
3-Amino-2-methylphenol |
EINECS | 258-438-5 |
CAS No. | 53222-92-7 | Density | 1.157g/cm3 |
PSA | 46.25000 | LogP | 1.86400 |
Solubility | N/A | Melting Point |
127-133 ºC |
Formula | C7H9 N O | Boiling Point | 267.1°Cat760mmHg |
Molecular Weight | 123.155 | Flash Point | 115.4°C |
Transport Information | N/A | Appearance | N/A |
Safety | Risk Codes | R36/37/38 | |
Molecular Structure | Hazard Symbols | ||
Synonyms |
o-Cresol,3-amino- (6CI); 2-Amino-6-hydroxytoluene; 2-Methyl-3-aminophenol;3-Amino-2-methylphenol; 3-Amino-o-cresol; 3-Hydroxy-2-methylaniline |
Article Data | 16 |
3-nitro-o-cresol
amino-6 hydroxy-2 toluene
Conditions | Yield |
---|---|
palladium on charcoal In ethanol | 100% |
palladium on charcoal In ethanol | 100% |
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; for 24h; | 99% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; antimony pentafluoride In hydrogen fluoride at -20℃; for 0.25h; Mechanism; Product distribution; | A 21% B 42% |
With dihydrogen peroxide; antimony pentafluoride In hydrogen fluoride at -20℃; for 0.25h; | A 21% B 42% |
3-nitro-o-tolylamine
amino-6 hydroxy-2 toluene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: Diazotization 2: tin; tin dichloride; hydrochloric acid / auf dem Wasserbade View Scheme | |
Multi-step reaction with 2 steps 1: concentrated sulfuric acid; water; sodium nitrite / Diazotization 2: sodium disulfite View Scheme |
2,6-dinitrotoluene
amino-6 hydroxy-2 toluene
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: alcohol; hydrogen sulfide; ammoniacal 2: concentrated sulfuric acid; water; sodium nitrite / Diazotization 3: sodium disulfite View Scheme |
amino-6 hydroxy-2 toluene
Conditions | Yield |
---|---|
With caesium carbonate In dimethyl sulfoxide at 120℃; for 1h; Sealed tube; | 100% |
1-(tert-butoxycarbonyl)-L-proline
amino-6 hydroxy-2 toluene
Conditions | Yield |
---|---|
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 5h; | 99% |
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 5h; |
5-bromo-1,3-xylene
amino-6 hydroxy-2 toluene
3-[(3,5-dimethylphenyl)amino]-2-methylphenol
Conditions | Yield |
---|---|
With chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(ll); sodium t-butanolate In 1,4-dioxane at 90℃; for 1h; Inert atmosphere; | 94% |
para-bromotoluene
amino-6 hydroxy-2 toluene
3-[(4-methylphenyl)amino]-2-methylphenol
Conditions | Yield |
---|---|
With chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(ll); sodium t-butanolate In 1,4-dioxane at 90℃; for 1h; Inert atmosphere; | 92% |
Conditions | Yield |
---|---|
With 1,3-bis-(diphenylphosphino)propane; palladium diacetate; potassium carbonate In acetonitrile at 100℃; under 10343.2 Torr; for 15h; chemoselective reaction; | 92% |
para-chlorotoluene
amino-6 hydroxy-2 toluene
3-[(4-methylphenyl)amino]-2-methylphenol
Conditions | Yield |
---|---|
With chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(ll); sodium t-butanolate In 1,4-dioxane at 90℃; for 1.16667h; Inert atmosphere; | 91% |
Molecular Structure:
Molecular Formula: C7H9NO
Molecular Weight: 123.1525
IUPAC Name: 3-Amino-2-methylphenol
Synonyms of 2-Amino-o-cresol (CAS NO.53222-92-7): EINECS 258-438-5 ; 3-Amino-o-cresol ; 2-Methyl-3-hydroxy aniline ; 2-Amino-o-cresol ; 2-Amino-6-hydroxytoluene ; 3-Amino-o-cresol,95%
CAS NO: 53222-92-7
Melting point: 129-130 °C
Index of Refraction: 1.616
Molar Refractivity: 37.19 cm3
Molar Volume: 106.4 cm3
Surface Tension: 51.9 dyne/cm
Density: 1.157 g/cm3
Flash Point: 115.4 °C
Enthalpy of Vaporization: 52.55 kJ/mol
Boiling Point: 267.1 °C at 760 mmHg
Vapour Pressure: 0.00504 mmHg at 25°C
Hazard Codes of 2-Amino-o-cresol (CAS NO.53222-92-7): Xi
Risk Statements: 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: Wear suitable gloves and eye/face protection.
WGK Germany: 3