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95-53-4

Basic Information
CAS No.: 95-53-4
Name: Benzenamine, 2-methyl-
Molecular Structure:
Molecular Structure of 95-53-4 (Benzenamine, 2-methyl-)
Formula: C7H9N
Molecular Weight: 107.17
Synonyms: NSC 15348;o-Aminotoluene;o-Methylaniline;o-Methylbenzenamine;o-Tolylamine;o-Toluidine(8CI);1-Amino-2-methylbenzene;2-Amino-1-methylbenzene;2-Aminotoluene;2-Methyl-1-aminobenzene;2-Methylaniline;2-Methylbenzenamine;2-Methylphenylamine;2-Tolylamine;
EINECS: 202-429-0
Density: 0.992 g/cm3
Melting Point: -23 °C
Boiling Point: 200.4 °C at 760 mmHg
Flash Point: 84 °C
Solubility: 1.5 g/100 mL (25 °C) in water
Appearance: Light beige purple liquid
Hazard Symbols: ToxicT, DangerousN, FlammableF
Risk Codes: 45-23/25-36-50-35-20/22-10-39/23/24/25-23/24/25-11
Safety: 53-45-61-36/37/39-26-36/37-16-7
Transport Information: UN 2920 8/PG 1
PSA: 26.02000
LogP: 2.15840
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Specification

The o-Toluidine, with the cas registry number 95-53-4, has the IUPAC name of 2-methylaniline. This is a kind of light yellow to light amber chemical, with the product categories including Intermediates of Dyes and Pigments; Azo dye; Amines; Aromatics; Mutagenesis Research Chemicals. Besides, it is slightly soluble in water and soluble in ethanol and ethyl ether, and is incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides.

The characteristics of this chemical are as follows: (1)ACD/LogP: 1.40; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.36; (4)ACD/LogD (pH 7.4): 1.4; (5)ACD/BCF (pH 5.5): 6.23; (6)ACD/BCF (pH 7.4): 6.77; (7)ACD/KOC (pH 5.5): 125.77; (8)ACD/KOC (pH 7.4): 136.81; (9)#H bond acceptors: 1; (10)#H bond donors: 2; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 26.02; (13)Index of Refraction: 1.567; (14)Molar Refractivity: 35.31 cm3; (15)Molar Volume: 107.9 cm3; (16)Polarizability: 13.99 ×10-24 cm3; (17)Surface Tension: 39.5 dyne/cm; (18)Density: 0.992 g/cm3; (19)Flash Point: 84 °C; (20)Enthalpy of Vaporization: 43.66 kJ/mol; (21)Boiling Point: 200.4 °C at 760 mmHg; (22)Vapour Pressure: 0.325 mmHg at 25°C; (23)Exact Mass: 107.073499; (24)MonoIsotopic Mass: 107.073499; (25)Topological Polar Surface Area: 26; (26)Heavy Atom Count: 8; (27)Formal Charge: 0; (28)Complexity: 70.8.

The production method of this chemical is as below: go through the catalytic hydrogenation and reduction of ortho-nitrotoluene to get this chemical. And if you use the hydrogenation catalyst of copper (Cu), the reaction temperature is 260 °C, and you could also use the nickel catalyzator.

As to its usage, it is widely applied in many ways. It could be used as the intermediate of pigment, pesticide, pharmaceutic and organic synthesis; It could be used as the analysis reagent.

When you are dealing with this chemical, you should be very careful and then take some measures to protect yourself. For one thing, it is toxic which could at low levels cause damage to health.  It will have danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed. Besides, it may cause cancer. For another thing, it is dangerous for the environment which may present an immediate or delayed danger to one or more components of the environment. This is very toxic to aquatic organisms. In addition, it is highly flammable which may catch fire in contact with air, only needing brief contact with an ignition source, and its has a very low flash point or evolve highly flammable gases in contact with water.

Due to so many dangers, you should take the following instructions to protect yourself. Wear suitable protective clothing, gloves and eye/face protection. If iin case of accident or if you feel unwell seek medical advice immediately (show the label where possible), and if in case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, avoid exposure - obtain special instructions before use. And while keeping it, keep container tightly closed, away from sources of ignition - No smoking. Lastly, remember not to release to the environment, and you could also refer to special instructions/safety data sheet.

Additionally, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: CC1=CC=CC=C1N
(2)InChI: InChI=1S/C7H9N/c1-6-4-2-3-5-7(6)8/h2-5H,8H2,1H3
(3)InChIKey: RNVCVTLRINQCPJ-UHFFFAOYSA-N 

Below are the toxicity information of this chemical:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo oral 150mg/kg (150mg/kg) BEHAVIORAL: COMA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN
U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 49, 1941.
frog LDLo oral 151mg/kg (151mg/kg) BEHAVIORAL: COMA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN
U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 49, 1941.
mammal (species unspecified) LD50 oral 1700mg/kg (1700mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 32(10), Pg. 25, 1988.
man TCLo inhalation 25mg/m3 (25mg/m3) KIDNEY, URETER, AND BLADDER: URINE VOLUME INCREASED

KIDNEY, URETER, AND BLADDER: HEMATURIA

BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 14(8), Pg. 7, 1970.
mouse LD50 intraperitoneal 150mg/kg (150mg/kg)   National Technical Information Service. Vol. AD691-490,
mouse LD50 oral 520mg/kg (520mg/kg) BLOOD: NORMOCYTIC ANEMIA

BLOOD: PIGMENTED OR NUCLEATED RED BLLOD CELLS

BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN
IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. Vol. 27, Pg. 155, 1982.
 
rabbit LD50 oral 840mg/kg (840mg/kg) BLOOD: NORMOCYTIC ANEMIA

BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN

BLOOD: PIGMENTED OR NUCLEATED RED BLLOD CELLS
IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. Vol. 27, Pg. 155, 1982.
 
rabbit LD50 skin 3250uL/kg (3.25mL/kg)   American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962.
 
rat LC50 inhalation 862ppm/4H (862ppm) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: TREMOR

LUNGS, THORAX, OR RESPIRATION: CYANOSIS
National Technical Information Service. Vol. OTS0570956,
rat LD50 oral 670mg/kg (670mg/kg) BLOOD: NORMOCYTIC ANEMIA

BLOOD: PIGMENTED OR NUCLEATED RED BLLOD CELLS

BLOOD: METHEMOGLOBINEMIA-CARBOXYHEMOGLOBIN
IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. Vol. 27, Pg. 155, 1982.
 

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