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Cas Database |
| Name |
3-Chlorobenzyl Chloride |
EINECS | 210-629-4 |
| CAS No. | 620-20-2 | Density | 1.247 g/cm3 |
| PSA | 0.00000 | LogP | 3.07880 |
| Solubility | N/A | Melting Point |
69-71oC |
| Formula | C7H6Cl2 | Boiling Point | 213.7 °C at 760 mmHg |
| Molecular Weight | 161.031 | Flash Point | 98.9 °C |
| Transport Information | UN 2235 6.1/PG 3 | Appearance | Colorless to light yellow liquid |
| Safety | 26-36/37/39-45-61-14C | Risk Codes | 34-51/53-43-36-20/21/22 |
| Molecular Structure |
|
Hazard Symbols |
 C,  N,  Xn
|
| Synonyms |
Toluene,m,a-dichloro- (8CI);1-Chloro-3-(chloromethyl)benzene;NSC 76577;m,a-Dichlorotoluene;m-Chlorobenzyl chloride;m-Chlorophenylmethyl chloride;a,3-Dichlorotoluene;a,m-Dichlorotoluene; |
Article Data | 30 |
3-Chlorobenzyl Chloride Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With dmap; triethylamine; p-toluenesulfonyl chloride In dichloromethane at 0 - 15℃; for 12.5h; | 31% |
| With thionyl chloride | |
| With phosphorus pentachloride at 100℃; | |
| With thionyl chloride In pyridine Ambient temperature; |
Conditions
| Conditions | Yield |
|---|---|
| With hydrogenchloride; potassium chloride; tetrabutyl-ammonium chloride In water at 20℃; Irradiation; Green chemistry; | 91% |
| With N-chloro-succinimide; N-hydroxyphthalimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile at 80℃; for 3h; Sealed tube; Inert atmosphere; | 88% |
| With N-hydroxyphthalimide; carbon tetrabromide; trichloroisocyanuric acid; copper(II) acetate monohydrate In dichloromethane at 25℃; for 40h; | 55% |
Conditions
| Conditions | Yield |
|---|---|
| With thionyl chloride; benzene |
- 620-20-2
1-Chloro-3-chloromethyl-benzene
Conditions
| Conditions | Yield |
|---|---|
| With phosphorus pentachloride at 110℃; |
- 620-20-2
1-Chloro-3-chloromethyl-benzene
Conditions
| Conditions | Yield |
|---|---|
| In 1,2-dichloro-ethane at 25℃; Kinetics; |
B
- 620-20-2
1-Chloro-3-chloromethyl-benzene
Conditions
| Conditions | Yield |
|---|---|
| With phosphorus pentachloride at 110℃; |
B
- 620-20-2
1-Chloro-3-chloromethyl-benzene
Conditions
| Conditions | Yield |
|---|---|
| With phosphorus pentachloride at 110℃; entsteht analog aus Benzoyl-<2.4'-dichlor-dibenzylamin>; |
- 56-23-5
tetrachloromethane
- 123150-61-8
(Z)-hepta-1,2,4-trien-6-yne
A
- 114980-29-9
1-(2,2,2-trichloroethyl)-3-chlorobenzene
B
- 620-20-2
1-Chloro-3-chloromethyl-benzene
Conditions
| Conditions | Yield |
|---|---|
| at 100℃; Product distribution; |
- 7791-25-5
sulfuryl dichloride
- 591-17-3
meta-bromotoluene
- 94-36-0
dibenzoyl peroxide
A
- 823-78-9
meta-bromobenzyl bromide
B
- 620-20-2
1-Chloro-3-chloromethyl-benzene
C
- 932-77-4
3-bromobenzyl chloride
Conditions
| Conditions | Yield |
|---|---|
| at 110℃; |
...Expand
- 191402-55-8
1-(1-Chloro-2,2,2-trifluoro-ethyl)-3-methyl-benzene
- 65108-07-8
C7H6Cl(1+)
B
- 620-20-2
1-Chloro-3-chloromethyl-benzene
Conditions
| Conditions | Yield |
|---|---|
| at 69.85℃; Thermodynamic data; chloride-transfer; |
3-Chlorobenzyl Chloride Chemical Properties
MF: C7H6Cl2
MW: 161.03
EINECS: 210-629-4
3-Chlorobenzyl Chloride,it's bp is about 215-216 °C(lit.).density is 1.27 g/mL at 25 °C(lit.) Ihe appearance of 3-Chlorobenzyl Chloride is often colorless to light yellow liquid.the molecular structure is following:
MW: 161.03
EINECS: 210-629-4
3-Chlorobenzyl Chloride,it's bp is about 215-216 °C(lit.).density is 1.27 g/mL at 25 °C(lit.) Ihe appearance of 3-Chlorobenzyl Chloride is often colorless to light yellow liquid.the molecular structure is following:
3-Chlorobenzyl Chloride Safety Profile
Safety Information about 3-Chlorobenzyl Chloride:
Hazard Codes C,N,Xn
Risk Statements 34-51/53-43-36-20/21/22
Safety Statements 26-36/37/39-45-61-14C
RIDADR UN 2235 6.1/PG 3
Hazard Codes C,N,Xn
Risk Statements 34-51/53-43-36-20/21/22
Safety Statements 26-36/37/39-45-61-14C
RIDADR UN 2235 6.1/PG 3
3-Chlorobenzyl Chloride Specification
TRANSPORT INFORMATION:
UN Number : 2235
Land Transport
ADR/RIC Code/Class: 8 /Packing Group II
Maritime Transport IMDG Code/Class : 8 /Packing Group II
Air Transport IATA Code/Class : 8 /Packing Group II
UN Number : 2235
Land Transport
ADR/RIC Code/Class: 8 /Packing Group II
Maritime Transport IMDG Code/Class : 8 /Packing Group II
Air Transport IATA Code/Class : 8 /Packing Group II
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3-Chlorobenzyl chloride
