Welcome to LookChem.com Sign In|Join Free
  • or
Home > Catalyst and Auxiliary > 94 > 

94-36-0

Basic Information
CAS No.: 94-36-0
Name: Benzoyl peroxide
Molecular Structure:
Molecular Structure of 94-36-0 (Benzoyl peroxide)
Formula: C14H10O4
Molecular Weight: 242.23
Synonyms: Nyper BMT;Nayper B and BO;Nyper BO;Benzoyl superoxide;Desquam-X;Oxy-5;Cadox 40E;Sanperox BPO;Benoxyl (5&10) Lotion;Benzoyl Peroxide,BPO;Crosslink agent BPO PERKADOX L;Di-Benzoyl Peroxide;Lucidol B 50;Clear By Design;Abcat 40;Dibenzoyl peroxide 75% with water;Benzoylperoxide;Benzoyl Peroxide 50%;Diphenylglyoxal peroxide;benzoyl benzenecarboperoxoate;Quinolor compound;Benoxyl;Desquam X;Persa-Gel;Nyper FF;Superox 744;Cadox B;Desquam E;Peroxide,dibenzoyl;PanOxyl;Component of Oxy-5;Component of Vanoxide;TC 1 (peroxide);Lucidol G 20;Nyper B;Lucidol 78;Vanoxide;Benzagel;Benzac W;Peroxide, dibenzoyl;Brevoxyl;143928-58-9;Luperox FL;Oxy 5;Nayper BO;Superox 46-750;Novadelox;Resdan Akne;Peroxyde de benzoyle [French];Cadox B 75W;Aztec BPO;B 75W;Luperco AST;Perossido di benzoile;Benzoyl peroxide [USAN];Debroxide;Nyper FF-K;Dibenzoylperoxid;Oxy-10;Cadat BPO;Benzol peroxide;Cadet BPO 78W;Cadox B-CH 50;Oxylite;Incidol;Acnegel;Lucidol KL 50;Benzoic acid, peroxide;Xerac;Fostex;Benox 50;BPO;Duresthin 5;Chaloxyd BP 50FT;Oxy-10 Cover;Benzashave;Persadox;Benzoylperoxid [German];Benzoylperoxyde [Dutch];Lucidol-70;Nyper BS;Clearasil Antibacterial Acne Lotion;Nyper BMT 40;Benzoylperoxyde;Eloxyl;W 75;Dibenzoyl peroxide;Cadox B 70W;Cadox BS;G20;Diphenylperoxyanhydride;pHisoAc BP;Lucidol 98;Nyper BW;Lucidol 50P;Acne-Aid Cream;Cadox B 50P;G 20;Lucidol (peroxide);Perossido di benzoile [Italian];BZF-60;Benzoperoxide;Dibenzoylperoxid [German];Benzagel 10;Aksil 5;Lucidol;Dry and Clear;Clearasil BP Acne Treatment Cream;Cadox B 40E;Topex;Nyper NS;Theraderm;Epi Clear Antiseptic Lotion;Norox bzp-250;Lucidol BW 50T;Benzamycin;Benzaknen;Desanden;Stri-dex B.P.;Norox bzp-C-35;Fostex BPO;Xerac BP;Lucidol KH 50;Akneroxide L;Lucidol 70;Mytolac;Loroxide;Acetoxyl;Akneroxid 5;Benbel C;Garox;Dibenzoylperoxyde [Dutch];Dibenzoylperoxyde;Benzoylperoxid;Peroxyde de benzoyle;Asidopan;
EINECS: 202-327-6
Density: 1.254 g/cm3
Melting Point: 105 °C(lit.)
Boiling Point: 349.747 °C at 760 mmHg
Flash Point: 154.239 °C
Solubility: insoluble in water
Appearance: white powder or crystals
Hazard Symbols: ExplosiveE,IrritantXi
Risk Codes: 8-36/37/38-43-36-2-7-1-51/53-21/22-62-50-61
Safety: 53-17-26-36/37-45-60-36/37/39-3/7-14A-14-47-35-7-61
Transport Information: UN 3108
PSA: 52.60000
LogP: 2.61540
Synthetic route
65-85-0

benzoic acid

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
With Eosin Y; triphenylphosphine In ethanol at 20℃; Irradiation;95%
With dihydrogen peroxide; dicyclohexyl-carbodiimide In diethyl ether; dichloromethane at 0℃; for 2h; Mechanism;90%
With dihydrogen peroxide; dicyclohexyl-carbodiimide In diethyl ether; dichloromethane at 0 - 2℃;90%
98-88-4

benzoyl chloride

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
With sodium hydroxide; dihydrogen peroxide In 1,1,2-Trichloro-1,2,2-trifluoroethane at 0 - 5℃;93%
With 1,2-ethanediol, dibenzoate; dihydrogen peroxide; sodium 4-dodecylbenzenesulfonate; sodium hydroxide In 2-Methylpentane; water at 20℃; for 0.5h; Reagent/catalyst; Solvent; Temperature;84.7%
With dihydrogen peroxide; sodium carbonate
93-59-4

Perbenzoic acid

71-43-2

benzene

A

93-99-2

benzoic acid phenyl ester

B

92-52-4

biphenyl

C

65-85-0

benzoic acid

D

94-36-0

dibenzoyl peroxide

E

product X 4percent,

product X 4percent,

Conditions
ConditionsYield
cobalt(III) acetylacetonate at 24.9℃; for 5h; Mechanism; Product distribution; Thermodynamic data; Ea; other metal 2,4-pentandioates (Co(II), Fe(III), Mn(III), Cr(III)).;A 6%
B 8%
C 90%
D 2%
E n/a
100-52-7

benzaldehyde

A

93-59-4

Perbenzoic acid

B

65-85-0

benzoic acid

C

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
With oxygen; ozone; lithium chloride In tetrachloromethane at 40℃;A n/a
B n/a
C 83.2%
618-32-6

Benzoyl bromide

PtBr(PPh3)2

PtBr(PPh3)2

A

93-97-0

benzoic acid anhydride

B

94-36-0

dibenzoyl peroxide

C

cis-PtBr2(PPh3)2

cis-PtBr2(PPh3)2

Conditions
ConditionsYield
In dichloromethane at -78℃; for 6h;A 27%
B 22%
C n/a
26274-19-1

5-bromo-3,4-dihydro-2H-pyran

A

32513-73-8

3-bromo-2-ethoxy-5,6-dihydro-2H-pyran

B

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
With tetrachloromethane; N-Bromosuccinimide Erwaermen des Reaktionsprodukts mit Natriumaethylat in Aethanol und Aether;
644-31-5

acetyl benzoyl peroxide

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
With sodium carbonate at 50℃;
79-21-0

peracetic acid

127-09-3

sodium acetate

98-88-4

benzoyl chloride

A

644-31-5

acetyl benzoyl peroxide

B

94-36-0

dibenzoyl peroxide

93-59-4

Perbenzoic acid

98-88-4

benzoyl chloride

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
With sodium hydrogencarbonate
93-97-0

benzoic acid anhydride

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
With barium peroxide
With potassium hydroxide; dihydrogen peroxide
With dioxygenbis(triphenylphosphine)platinum(0) In dichloromethane for 2h;9 % Chromat.
93-97-0

benzoic acid anhydride

A

93-59-4

Perbenzoic acid

B

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
With potassium hydroxide; dihydrogen peroxide at 0℃;
93-59-4

Perbenzoic acid

98-09-9

benzenesulfonyl chloride

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
at 0℃;
93-59-4

Perbenzoic acid

1076-43-3

benzene-d6

A

20637-23-4

2,3,4,5,6-pentadeuterio-biphenyl

B

Benzoic perdeuterophenyl ester

C

65-85-0

benzoic acid

D

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
cobalt(III) acetylacetonate at 25℃; Mechanism; Product distribution;
52947-05-4

[α-13C]benzoyl chloride

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
With sodium peroxide
56-23-5

tetrachloromethane

100-52-7

benzaldehyde

ozone containing oxygen

ozone containing oxygen

A

65-85-0

benzoic acid

B

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
at 0℃;
7722-84-1

dihydrogen peroxide

98-88-4

benzoyl chloride

furan-2,3,5(4H)-trione pyridine (1:1)

94-36-0

dibenzoyl peroxide

98-88-4

benzoyl chloride

barium peroxide hydrate

barium peroxide hydrate

94-36-0

dibenzoyl peroxide

98-88-4

benzoyl chloride

barium peroxide hydrate

barium peroxide hydrate

94-36-0

dibenzoyl peroxide

93-97-0

benzoic acid anhydride

barium peroxide hydrate

barium peroxide hydrate

94-36-0

dibenzoyl peroxide

93-59-4

Perbenzoic acid

98-88-4

benzoyl chloride

sodium bicarbonate

sodium bicarbonate

94-36-0

dibenzoyl peroxide

98-88-4

benzoyl chloride

sodium peroxide

sodium peroxide

94-36-0

dibenzoyl peroxide

7722-84-1

dihydrogen peroxide

93-97-0

benzoic acid anhydride

potassium hydroxide

potassium hydroxide

A

93-59-4

Perbenzoic acid

B

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
at 0℃;
127-09-3

sodium acetate

98-88-4

benzoyl chloride

acetyl hydrogen peroxide

acetyl hydrogen peroxide

A

644-31-5

acetyl benzoyl peroxide

B

94-36-0

dibenzoyl peroxide

93-59-4

Perbenzoic acid

7726-95-6

bromine

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
at 20℃;
93-59-4

Perbenzoic acid

7782-50-5

chlorine

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
at 25℃;
17088-73-2

bis-hydroxymethyl peroxide

98-88-4

benzoyl chloride

aqueous NaOH-solution

aqueous NaOH-solution

94-36-0

dibenzoyl peroxide

644-31-5

acetyl benzoyl peroxide

natrium carbonate

natrium carbonate

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
at 50℃;
98-88-4

benzoyl chloride

acetyl hydrogen peroxide

acetyl hydrogen peroxide

A

644-31-5

acetyl benzoyl peroxide

B

94-36-0

dibenzoyl peroxide

Conditions
ConditionsYield
With water; sodium acetate
644-31-5

acetyl benzoyl peroxide

diluted NaOH-solution

diluted NaOH-solution

A

65-85-0

benzoic acid

B

94-36-0

dibenzoyl peroxide

C

sodium peroxide

sodium peroxide

D

oxygen

oxygen

111-92-2

dibutylamine

94-36-0

dibenzoyl peroxide

87662-94-0

O-benzoyl-N,N-dibutylhydroxylamine

Conditions
ConditionsYield
With disodium hydrogenphosphate In diethyl ether for 15h; Heating;100%
With Carbonate buffer In dichloromethane; water at 20℃; pH=10.5;94%
With dipotassium hydrogenphosphate In N,N-dimethyl-formamide at 20℃; for 12h; Inert atmosphere;59%
128-08-5

N-Bromosuccinimide

N-bromosuccinamide

122670-62-6

2-Bromo-5-(trifluoromethyl)-6-methoxy-1-naphthalene-carboxylic acid

122670-68-2

2-chloro-6-methoxy-1-methyl-5-(trifluoromethyl)naphthalene

94-36-0

dibenzoyl peroxide

122670-63-7

1-bromomethyl-2-chloro-6-methoxy-5-trifluoromethylnaphthalene

Conditions
ConditionsYield
In tetrachloromethane100%
128-08-5

N-Bromosuccinimide

N-bromosuccinamide

122670-68-2

2-chloro-6-methoxy-1-methyl-5-(trifluoromethyl)naphthalene

94-36-0

dibenzoyl peroxide

122670-63-7

1-bromomethyl-2-chloro-6-methoxy-5-trifluoromethylnaphthalene

Conditions
ConditionsYield
In tetrachloromethane100%
166180-60-5

ethyl [4-methyl-5-(2-thienyl)isoxazol-3-yl]carboxylate

94-36-0

dibenzoyl peroxide

166180-61-6

ethyl [4-bromomethyl-5-(2-thienyl)isoxazol-3-yl]carboxylate

Conditions
ConditionsYield
With N-Bromosuccinimide In CCl4was100%
20427-59-2

copper hydroxide

94-36-0

dibenzoyl peroxide

copper(II) oxide

Conditions
ConditionsYield
Stage #1: copper hydroxide; dibenzoyl peroxide In water at 60℃; for 0.5h; Inert atmosphere;
Stage #2: In water for 5h; Sonication; Inert atmosphere;
100%

1-tert-butyl 3-methyl 2-(2-phenylethyl)malonate

94-36-0

dibenzoyl peroxide

1-tert-butyl 3-methyl 2-benzoyloxy-2-(2-phenylethyl)malonate

Conditions
ConditionsYield
With (2R,5R,1'S)-1-(9-anthracenyl)methyl-5-ethylene-2-[1-hydroxy-1-(quinol-4-yl)]methyl-1-azoniabicyclo[2.2.2]octane chloride; potassium hydroxide In water; toluene at -40℃; for 48h; enantioselective reaction;99%
4491-46-7

2-benzyl-malonic acid tert-butyl ester methyl ester

94-36-0

dibenzoyl peroxide

tert-butyl methyl (S)-2-(benzoyloxy)-2-benzylmalonate

Conditions
ConditionsYield
With (2R,5R,1'S)-1-(9-anthracenyl)methyl-5-ethylene-2-[1-hydroxy-1-(quinol-4-yl)]methyl-1-azoniabicyclo[2.2.2]octane chloride; potassium hydroxide In water; toluene at -40℃; for 48h; Catalytic behavior; Reagent/catalyst; Temperature; enantioselective reaction;99%

1-tert-butyl 3-methyl 2-(4-methoxybenzyl)malonate

94-36-0

dibenzoyl peroxide

1-tert-butyl 3-methyl 2-benzoyloxy-2-(4-methoxybenzyl)malonate

Conditions
ConditionsYield
With (2R,5R,1'S)-1-(9-anthracenyl)methyl-5-ethylene-2-[1-hydroxy-1-(quinol-4-yl)]methyl-1-azoniabicyclo[2.2.2]octane chloride; potassium hydroxide In water; toluene at -40℃; for 48h; enantioselective reaction;99%

1-tert-butyl 3-methyl 2-(4-trifluoromethylbenzyl)malonate

94-36-0

dibenzoyl peroxide

1-tert-butyl 3-methyl 2-benzoyloxy-2-(4-trifluoromethylbenzyl)malonate

Conditions
ConditionsYield
With (2R,5R,1'S)-1-(9-anthracenyl)methyl-5-ethylene-2-[1-hydroxy-1-(quinol-4-yl)]methyl-1-azoniabicyclo[2.2.2]octane chloride; potassium hydroxide In water; toluene at -40℃; for 48h; enantioselective reaction;99%

1-tert-butyl 3-methyl 2-naphthalen-2-ylmethylmalonate

94-36-0

dibenzoyl peroxide

1-tert-butyl 3-methyl 2-benzoyloxy-2-naphthalen-2-ylmethylmalonate

Conditions
ConditionsYield
With (2R,5R,1'S)-1-(9-anthracenyl)methyl-5-ethylene-2-[1-hydroxy-1-(quinol-4-yl)]methyl-1-azoniabicyclo[2.2.2]octane chloride; potassium hydroxide In water; toluene at -40℃; for 48h; enantioselective reaction;99%

1-oxo-indan-2-carboxylic acid adamantan-1-yl ester

94-36-0

dibenzoyl peroxide

1-adamantyl 2-benzoyloxy-1-oxo-2,3-dihydro-1H-indene-2-carboxylate

Conditions
ConditionsYield
With (+)-N-benzylcinchonineammonium bromide; potassium carbonate In toluene at 25℃; for 24h; Temperature; Reagent/catalyst;99%
With C35H35N2O3(1+)*Br(1-); potassium carbonate In toluene at 15℃; for 12h; Time; enantioselective reaction;98%
1403881-80-0

1-indanone-2-carboxylic acid-(3-ethyl)-3-pentyl ester

94-36-0

dibenzoyl peroxide

A

C24H26O5

B

3-ethyl 3-pentanyl 2-benzoyloxy-1-oxo-2,3-dihydro-1H-indene-2-carboxylate

Conditions
ConditionsYield
With C35H35N2O3(1+)*Br(1-); potassium carbonate In toluene at 15℃; for 12h; enantioselective reaction;A n/a
B 99%
With C35H35N2O3(1+)*Br(1-); potassium carbonate In toluene at 15℃; for 24h; Overall yield = 99 %;A n/a
B n/a

allyl 6,6-dimethyl-2-oxotetrahydro-2H-pyran-3-carboxylate

94-36-0

dibenzoyl peroxide

allyl 3-(benzoyloxy)-6,6-dimethyl-2-oxotetrahydro-2H-pyran-3-carboxylate

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran at -10℃; for 1h; Inert atmosphere;99%

allyl 7,7-dimethyl-2-oxooxepane-3-carboxylate

94-36-0

dibenzoyl peroxide

allyl 3-(benzoyloxy)-7,7-dimethyl-2-oxooxepane-3-carboxylate

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran at -10℃; for 1h; Inert atmosphere;99%
74559-43-6

tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane

94-36-0

dibenzoyl peroxide

A

((CH3)3SiCH2)3SnPr(OCOC6H5)2

B

42202-20-0

((CH3)3SiCH2)3Sn(OCOC6H5)

Conditions
ConditionsYield
In benzene soln. of Pr-Sn complex was shaken with soln. of benzoylperoxide at 50°C for 12 h; Sn-Pr complex pptd.; elem. anal.; org. layer was sepd. by distn.;A 98.4%
B 75%
3222-48-8

6-methylnicotinonitrile

94-36-0

dibenzoyl peroxide

2-aminomethyl-5-carbobenzyloxyamidinopyridine dihydrogen chloride

Conditions
ConditionsYield
Stage #1: 6-methylnicotinonitrile; dibenzoyl peroxide With N-Bromosuccinimide In tetrachloromethane for 18h; Heating / reflux;
Stage #2: With 4-cyanobenzyl bromide
98%
82477-25-6

bis[tris(trifluoromethyl)germyl]mercury

94-36-0

dibenzoyl peroxide

A

82484-05-7

(benzoyloxy)tris(trifluoromethyl)germane

B

mercury

Conditions
ConditionsYield
In benzene dry oxygen-free solvents, evacuated glass ampoules; keeping Ge-compd. in benzene and benzoyl peroxide at 50°C (50 h); sepn. of metallic Hg from soln., removal of benzene in vac., distn. (0.01 mm, bath temp. 40°C); elem. anal.;A 57%
B 98%
1352166-68-7

tris(5-bromo-2-methoxyphenyl)antimony(III) benzene monosolvate

94-36-0

dibenzoyl peroxide

1352166-71-2

((2-methoxy-5-bromophenyl)3Sb(PhC(O)O)2

Conditions
ConditionsYield
In benzene mixt. of tris(2-methoxy-5-bromophenyl)antimony benzene monosolvate and benzoyl peroxide in C6H6 was heated for 3 h at 40°C; cooled; solvent removed; elem. anal.;98%

ethyl[bis(pentafluorophenyl)germyl]thallium(I)

94-36-0

dibenzoyl peroxide

A

85813-96-3

(C6F5)2Ge(C2H5)OCOC6H5

B

5630-31-9

thallium benzoate

Conditions
ConditionsYield
In benzene under Ar, benzene soln. of ethyl(bis(pentafluorophenyl)germyl)thallium(I) added to soln. of benzoyl peroxide in benzene, kept for 10 min at 20°C; org. layer decanted, benzene removed in vac., residue recrystd. from hexane, elem. anal.;A 86%
B 97%

1-indanone-2-carboxylic acid tert-amyl ester

94-36-0

dibenzoyl peroxide

1-tert-pentyl 2-benzoyloxy-1-oxo-2,3-dihydro-1H-indene-2-carboxylate

Conditions
ConditionsYield
With C35H35N2O3(1+)*Br(1-); potassium carbonate In toluene at 15℃; for 12h; enantioselective reaction;97%
89656-44-0

2‐allylpiperidine

94-36-0

dibenzoyl peroxide

955404-30-5

O-benzoyl-2-allylpiperidin-1-ol

Conditions
ConditionsYield
With disodium hydrogenphosphate In tetrahydrofuran at 65℃;96%
862907-06-0

tert-butyl 3-(4-fluorophenyl)-2-oxoindoline-1-carboxylate

94-36-0

dibenzoyl peroxide

1271489-24-7

tert-butyl (S)-3-(benzoyloxy)-3-(4-fluorophenyl)-2-oxoindoline-1-carboxylate

Conditions
ConditionsYield
With Ca[(S)-VAPOL-Phosphate]2 In diethyl ether at 20℃; for 20h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;96%
923568-89-2

tert-butyl 5-methoxy-2-oxo-3-phenylindoline-1-carboxylate

94-36-0

dibenzoyl peroxide

1271489-34-9

tert-butyl (S)-3-(benzoyloxy)-5-methoxy-2-oxo-3-phenylindoline-1-carboxylate

Conditions
ConditionsYield
With Ca[(S)-VAPOL-Phosphate]2 In diethyl ether at 20℃; for 20h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;96%
1175713-10-6

C19H18FNO3

94-36-0

dibenzoyl peroxide

1271489-30-5

tert-butyl (S)-3-(benzoyloxy)-7-fluoro-2-oxo-3-phenylindoline-1-carboxylate

Conditions
ConditionsYield
With Ca[(S)-VAPOL-Phosphate]2 In diethyl ether at 20℃; for 20h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;96%
502-49-8

cycloactanone

94-36-0

dibenzoyl peroxide

(R)-2-benzoyloxy-4,4-dimethylcyclooctanone

Conditions
ConditionsYield
With ent-9-amino(9-deoxy)epi-hydroquinine; sodium carbonate; salicylic acid In toluene at 0℃; for 80h; optical yield given as %ee; enantioselective reaction;96%
1383187-31-2

tert-butyl 5-fluoro-1-oxo-2,3-dihydro-1H-indene-2-carboxylate

94-36-0

dibenzoyl peroxide

1-tert-butyl 2-benzoyloxy-5-fluorine-1-oxo-2,3-dihydro-1H-indene-2-carboxylate

Conditions
ConditionsYield
With C35H35N2O3(1+)*Br(1-); potassium carbonate In toluene at 15℃; for 12h; enantioselective reaction;96%
74559-40-3

tris[tris(trimethylsilylmethyl)stannyl]neodymium*1,2-dimethoxyethane

94-36-0

dibenzoyl peroxide

A

((CH3)3SiCH2)3SnNd(OCOC6H5)2

B

42202-20-0

((CH3)3SiCH2)3Sn(OCOC6H5)

Conditions
ConditionsYield
In benzene soln. of Nd-Sn complex was shaken with soln. of benzoylperoxide at 50°C for 12 h; Sn-Nd complex pptd.; elem. anal.; org. layer was sepd. by distn.;A 95.7%
B 75%
108-91-8

cyclohexylamine

94-36-0

dibenzoyl peroxide

1485-75-2

N-cyclohexyl-O-benzoylhydroxylamine

Conditions
ConditionsYield
With water; caesium carbonate In dichloromethane at 20℃; for 16h;95%
With pH 10.5 buffer In dichloromethane Ambient temperature;82%
With potassium carbonate In chloroform for 1h; Ambient temperature; Yield given;
In dichloromethane at 20℃; pH=10.5; Inert atmosphere; Schlenk technique;
With potassium hydrogenphosphate trihydrate In N,N-dimethyl-formamide at 20℃; Inert atmosphere;
70638-09-4

4-isopropyl-2H-1,4-thiazin-3-one

94-36-0

dibenzoyl peroxide

82409-32-3

Benzoic acid 4-isopropyl-3-oxo-3,4-dihydro-2H-[1,4]thiazin-2-yl ester

Conditions
ConditionsYield
In chloroform for 4h; Heating;95%
  • Display:default sort

    New supplier

  • Amadis Chemical offer CAS#94-36-0;CAT#A844933

  • Casno:

    94-36-0

    Amadis Chemical offer CAS#94-36-0;CAT#A844933

    Min.Order: 10 Milligram

    FOB Price:  USD $ 0.0-0.0/Milligram

    1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

    Founded in 2011, Amadis Chemical Company Limited is an innovative manufacturer of chemical products and technical service providers. Our business includes sales, manufacture, and s

  •  Amadis Chemical Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-571-89925085

    Address:Watts Cosine.No.166.Xiangmao Road.

       Inquiry Now

  • benzoylbenzenecarboperoxoate 94-36-0

  • Casno:

    94-36-0

    benzoylbenzenecarboperoxoate 94-36-0

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

    Russell Chemicals Technology Co.,Ltd is a new-tech research and development enterprise dedicated to providing high-value-added auxiliaries,such as photoinitiators monomers and olig

  •  Hunan Russell Chemicals Technology Co.,Ltd

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:0086-731-85415356

    Address:Buiding4,Lugu Enterprise Plaza, Yuelu Distric

       Inquiry Now

  • Benzoyl peroxide-Low Price High Quality

  • Casno:

    94-36-0

    MSDS/COA Download

    Benzoyl peroxide-Low Price High Quality

    Min.Order: 1 Metric Ton

    FOB Price:  USD $ 0.0-0.0/Metric Ton

    Our company is mainly engaged inR&D,Contract Manufacture and Scale-up production of Fine Chemicals , Amino Acid & Derivativesand Peptide Reagents . We have experienced team engaging in organic synthesisand have our own professional laborat

    Nantong Leadchem Industry Co.,Ltd is aHi-Tech Chemical Company Our company is mainly engaged inR&D,Contract Manufacture and Scale-up production of Fine Chemicals , Amino Acid & De

  • Nantong Leadchem Industry Co.,Ltd

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-513-81164889

    Address:Yangkou Chemical Industry Park,Nantong,Jiangsu

       Inquiry Now

  • China Diluted Benzoyl peroxide, 98%, wetted with ca. 25% H2O

  • Casno:

    94-36-0

    China Diluted Benzoyl peroxide, 98%, wetted with ca. 25% H2O

    Min.Order: 1 Metric Ton

    FOB Price:  USD $ 0.0-0.0/Metric Ton

    Product Name: BPO 75% solid CAS: 94-36-0 Remarks:Purity: as in COA Package: 20KG/Carton CustNote: Package:5kg,20kg Application:It is mainly used as polymerization initiator for acrylic resin, vinyl acetate resin, methacryli

    Arylchem is a fine chemical producer specializing in the synthesis and development of coupling reagents and chiral auxiliaries. Our main products include diboron esters for Suzuki-

  • Weifang Arylchem Chemical Co., LTD

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-536-5217866

    Address:Development Zone, Shouguang, Shandong Province

       Inquiry Now

  • Benzoyl peroxide

  • Casno:

    94-36-0

    Benzoyl peroxide

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    94-36-0 Application:Benzoyl peroxide

    PureChems is dedicated to bring high quality and cost effective chemical products and services to our clients. PureChems can provide high purity Natural Products, Research Chemical

  • Pure Chemistry Scientific Inc.

    United States  |  Contact Details

    Business Type:Trading Company

    Tel:+1-857-366-7588

    Address:14905 SW freeway street #232, Sugarland, TX 77478, USA

       Inquiry Now

  • Total:5 Page 1 of 1 1

Please post your buying leads,so that our qualified suppliers will soon contact you!
*Required Fields

Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 36 (1985),p. 267.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 36 (1985),p. 267.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Community Right-To-Know List.

Standards and Recommendations

OSHA PEL: TWA 5 mg/m3
ACGIH TLV: TWA 5 mg/m3; Not Classifiable as a Human Carcinogen
DFG MAK: 5 mg/m3; Weak allergin and skin irritant
NIOSH REL: (Benzoyl Peroxide) TWA 5 mg/m3

Analytical Methods

For occupational chemical analysis use NIOSH: Benzoyl Peroxide, 5009.

Specification

The CAS registry number of Benzoyl peroxide is 94-36-0. The IUPAC name is benzoyl benzenecarboperoxoate. Its EINECS registry number is 202-327-6. In addition, the molecular formula is C14H10O4 and the molecular weight is 242.23. It is a kind of white powder or crystals and belongs to the classes of Industrial/Fine Chemicals; Organic Peroxide; Synthetic Organic Chemistry.

Physical properties about Benzoyl peroxide are: (1)ACD/LogP: 2.859; (2)ACD/LogD (pH 5.5): 2.86; (3)ACD/LogD (pH 7.4): 2.86; (4)ACD/BCF (pH 5.5): 87.62; (5)ACD/BCF (pH 7.4): 87.62; (6)ACD/KOC (pH 5.5): 855.31 ; (7)ACD/KOC (pH 7.4): 855.31; (8)#H bond acceptors: 4; (9)#Freely Rotating Bonds: 5; (10)Index of Refraction:1.585; (11)Molar Refractivity: 64.737 cm3; (12)Molar Volume: 193.103 cm3; (13)Polarizability: 25.664 10-24cm3; (14)Surface Tension: 49.6240005493164 dyne/cm; (15)Density: 1.254 g/cm3; (16)Flash Point: 154.239 °C; (17)Enthalpy of Vaporization: 59.427 kJ/mol; (18)Boiling Point: 349.747 °C at 760 mmHg

Preparation of Benzoyl peroxide: firstly, prepare the material of sodium hydroxide and oxydol. Next, drop benzoyl chloride into mixture with stirring at reaction temperature below 0 °C. Then keep the temperature about 0 °C for 2-3 hours with stirring. By means of stalling layered and drying at low temperature you can get the product.

Benzoyl peroxide can be prepared by sodium hydroxide, oxydol and benzoyl chloride

Uses of Benzoyl peroxide: it can be used to test formaldehyde and bravery sterol. And it can be used as quality improver of flour, intermediates of fine chemical products, additives of grain and oil, vulcanization agent of xylene silicone rubber and kyle F-rubber, catalyst of free radicals halogenating and radical sensitization reaction. In addition, it can react with piperidine to get 1-benzoyloxy-piperidine. This reaction will need reagent dipotassium hydrogen phosphate and solvent dimethylformamide. The reaction time is 21 hours by heating. The yield is about 60%.

Benzoyl peroxide can react with piperidine to get 1-benzoyloxy-piperidine

When you are using this chemical, please be cautious about it as the following:
This chemical is explosive when dry. It may cause fire when contact with combustible material. And ti is irritating to eyes, respiratory system and skin and harmful in contact with skin and if swallowed. In addition, it has risk of impaired fertility. It is toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Avoid exposure - obtain special instructions before use. It has refer to special instructions/safety data sheets. During using it, wear suitable protective clothing, gloves and eye/face protection. And keep away from combustible material. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. And in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.). In additon, this material and its container must be disposed of as hazardous waste and must be disposed of in a safe way. You shuld keep container tightly closed and avoid release to the environment.

You can still convert the following datas into molecular structure:
(1)SMILES: c1ccc(cc1)C(=O)OOC(=O)c2ccccc2
(2)InChI: InChI=1/C14H10O4/c15-13(11-7-3-1-4-8-11)17-18-14(16)12-9-5-2-6-10-12/h1-10H
(3)InChIKey: OMPJBNCRMGITSC-UHFFFAOYAV

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mammal (species unspecified) LD50 skin > 1gm/kg (1000mg/kg)   Kodak Company Reports. Vol. #900713,
mouse LD50 intraperitoneal 250mg/kg (250mg/kg)   International Polymer Science and Technology. Vol. 3, Pg. 93, 1976.
mouse LD50 oral 5700mg/kg (5700mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 32(3), Pg. 31, 1967.
rat LD50 oral 7710mg/kg (7710mg/kg) LIVER: OTHER CHANGES

LUNGS, THORAX, OR RESPIRATION: CYANOSIS

KIDNEY, URETER, AND BLADDER: OTHER CHANGES IN URINE COMPOSITION
ARCO Chemical Company Report. Vol. JUN1982,