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Cas Database

Name	3-Phenoxybenzyl alcohol	EINECS	237-525-1
CAS No.	13826-35-2	Density	1.151 g/cm³
PSA	29.46000	LogP	2.97120
Solubility	insoluble in water	Melting Point	4-7°C
Formula	C₁₃H₁₂O₂	Boiling Point	377.8 °C at 760 mmHg
Molecular Weight	200.237	Flash Point	151.3 °C
Transport Information	N/A	Appearance	colourless liquid
Safety	26-36/37	Risk Codes	22
Molecular Structure		Hazard Symbols	Xn, Xi
Synonyms	Benzylalcohol, m-phenoxy- (7CI,8CI);(3-Phenoxyphenyl)methanol;1-Hydroxymethyl-3-phenoxybenzene;3-(Hydroxymethyl)diphenyl ether;3-Phenoxybenzenemethanol;m-Phenoxybenzyl alcohol;	Article Data	48

3-Phenoxybenzyl alcohol Synthetic route

: 39515-51-0
3-Phenoxybenzaldehyde

: 13826-35-2
3-Phenoxybenzyl alcohol

Conditions

Conditions	Yield
With sodium tetrahydroborate In methanol at 0 - 20℃; for 1.5h;	99%
With hydrogen In methanol at 20℃; for 4.3h; chemoselective reaction;	99%
With sodium tetrahydroborate In tetrahydrofuran; 1,2-dimethoxyethane for 3h; Cooling with ice;	99.2%

methanolic potassium hydroxide: methanolic potassium hydroxide

: 50789-44-1
3-phenoxybenzyl acetate

: 13826-35-2
3-Phenoxybenzyl alcohol

Conditions

Conditions	Yield
	97.2%

: 2-(3-phenoxy-benzyloxy)-tetrahydro-pyran

: 13826-35-2
3-Phenoxybenzyl alcohol

Conditions

Conditions	Yield
With copper dichloride In methanol at 20℃; Hydrolysis;	95%
With CuCl2*2H2O In methanol at 20℃; for 1.25h;	95%

: 50789-44-1
3-phenoxybenzyl acetate

: 13826-35-2
3-Phenoxybenzyl alcohol

Conditions

Conditions	Yield
With hydrogenchloride; sodium hydroxide In methanol; dichloromethane; water	95%
With hydrogenchloride; sodium hydroxide In methanol; dichloromethane; water	90%
With sodium hydroxide In methanol; dichloromethane; water	90%

: 3739-38-6
3-phenoxybenzoic acid

: 13826-35-2
3-Phenoxybenzyl alcohol

Conditions

Conditions	Yield
In ethanol; sulfuric acid; water electrochemical reduction;	93%
Multi-step reaction with 3 steps 1: phosphorus (V)-chloride 2: toluene; palladium/barium sulfate 3: concentrated aqueous KOH / 60 °C View Scheme
Multi-step reaction with 2 steps 1: sulfuric acid / 3 h / 60 °C 2: methanol; sodium tetrahydroborate / tetrahydrofuran / 0.5 h / Reflux View Scheme

: 148-24-3
8-quinolinol

: 620-24-6
3-Hydroxybenzyl alcohol

: 13826-35-2
3-Phenoxybenzyl alcohol

Conditions

Conditions	Yield
With sodium chloride; sulfuric acid; sodium hydrogencarbonate; potassium carbonate; copper(I) chloride In chlorobenzene	93%
With sodium chloride; sulfuric acid; sodium hydrogencarbonate; potassium carbonate; copper(I) chloride In chlorobenzene

: 620-24-6
3-Hydroxybenzyl alcohol

: 108-90-7
chlorobenzene

: 13826-35-2
3-Phenoxybenzyl alcohol

Conditions

Conditions	Yield
With potassium phosphate; copper(l) iodide; N1-benzyl-N2-(5-methyl-[1,1'-biphenyl]-2-yl)oxalamide In dimethyl sulfoxide at 120℃; for 24h; Inert atmosphere;	92%
With potassium carbonate; 8-quinolinol; copper(l) chloride In various solvent(s) at 150 - 170℃; for 15h;	88 % Chromat.
With potassium carbonate; 8-quinolinol; copper(l) chloride In dimethyl sulfoxide at 150 - 170℃; for 15h; Product distribution; solvents varied;	58 % Chromat.

: 108-86-1
bromobenzene

: 620-24-6
3-Hydroxybenzyl alcohol

: 13826-35-2
3-Phenoxybenzyl alcohol

Conditions

Conditions	Yield
With potassium phosphate; copper(l) iodide; N,N’-bis(2-phenylphenyl)oxalic acid In N,N-dimethyl-formamide at 90℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube;	92%

: 620-24-6
3-Hydroxybenzyl alcohol

A: 112-35-6
triethylene glucol monomethyl ether

B: 13826-35-2
3-Phenoxybenzyl alcohol

Conditions

Conditions	Yield
	A n/a B 87%

: 15852-73-0
(3-Bromophenyl)methanol

: 108-95-2
phenol

: 13826-35-2
3-Phenoxybenzyl alcohol

Conditions

Conditions	Yield
With sodium dodecyl-sulfate; potassium carbonate In water at 80℃; under 760.051 Torr; for 10h; Ullmann Condensation; Green chemistry; chemoselective reaction;	84%

3-Phenoxybenzyl alcohol Chemical Properties

IUPAC Name: 3-Phenoxybenzyl alcohol
The MF of 3-Phenoxybenzyl alcohol (13826-35-2) is C₁₃H₁₂O₂.

The MW of 3-Phenoxybenzyl alcohol (13826-35-2) is 200.23.
Synonyms of 3-Phenoxybenzyl alcohol (13826-35-2): (3-Phenoxyphenyl)methanol ; Benzenemethanol, 3-phenoxy- ; 3-(Hydroxymethyl)diphenyl ether
Product Categories: Benzhydrols,Benzyl & Special Alcohols;Alcohols;Oxygen Compounds
Form: colourless liquid
Index of Refraction: 1.595
EINECS: 237-525-1
Density: 1.151 g/ml
Flash Point: 151.3 °C
Boiling Point: 377.8 °C
Melting Point: 4-7 °C
Water Solubility: Insoluble
BRN: 475312
Stability: Stable

3-Phenoxybenzyl alcohol Uses

3-Phenoxybenzyl alcohol (13826-35-2) is permethrin, phenothrin and permethrin and other pesticides in the middle of ether, pharmaceutical intermediates.

3-Phenoxybenzyl alcohol Toxicity Data With Reference

1.	orl-rat LD50:3 g/kg	GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 35 (1)(1991),47.
2.	orl-mus LD50:2040 mg/kg	GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 35 (1)(1991),47.
3.	ipr-mus LD50:575 mg/kg	JAFCAU Journal of Agricultural and Food Chemistry. 25 (1977),9.

3-Phenoxybenzyl alcohol Consensus Reports

Reported in EPA TSCA Inventory.

3-Phenoxybenzyl alcohol Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits acrid smoke and irritating vapors.
Safety information of 3-Phenoxybenzyl alcohol (13826-35-2):
Hazard Codes Xn,Xi
Risk Statements
22 Harmful if swallowed
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37 Wear suitable protective clothing and gloves
WGK Germany 3
RTECS DP0775400
Hazard Note Irritant

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