CAS No.13826-66-9,ZIRCONYL NITRATE Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	13826-66-9
Name:	ZIRCONYL NITRATE

Formula:	N₂O₇Zr
Molecular Weight:	231.233
Synonyms:	Zirconium,bis(nitrato-O)oxo-;Zirconium, dinitratooxo- (8CI);Zirconyl nitrate (6CI,7CI);Bis(nitrato)oxozirconium;Bis(nitrato-kO)oxozirconium;Dinitratooxozirconium;NSC 148480;Zirconium dinitrate oxide;Zirconium nitrate oxide (ZrO(NO3)2);Zirconium oxidedinitrate;Zirconium oxide nitrate (ZrO(NO3)2);Zirconium oxynitrate;Zirconiumoxynitrate (ZrO(NO3)2);Zirconyl dinitrate;Zirconyl nitrate (ZrO(NO3)2);Zircosol ZN;
EINECS:	237-529-3
Density:	1.45g/mLat 25°C
Boiling Point:	83 °C at 760 mmHg
Solubility:	Soluble in water
Hazard Symbols:	O, C
Risk Codes:	8-34
Safety:	17-26-36/37/39-45
Transport Information:	UN 3098 5.1/PG 2
PSA:	154.83000
LogP:	0.44940

Synthetic route

: 13826-66-9
zirconyl nitrate

: 7664-41-7
ammonia

: 7732-18-5
water

: zirconium hydroxide

Conditions

Conditions	Yield
at 65℃;

...Expand

: 13826-66-9
zirconyl nitrate

: chloroauric acid

Au/ZrO2: Au/ZrO2

Conditions

Conditions	Yield
Stage #1: zirconyl nitrate; chloroauric acid With sodium carbonate In water at 65 - 70℃; for 4h; Stage #2: With oxygen at 110 - 400℃; for 13h;

: 1336-21-6
ammonium hydroxide

: 13826-66-9
zirconyl nitrate

: 7440-67-7
zirconium(IV) oxide

Conditions

Conditions	Yield
Stage #1: ammonium hydroxide; zirconyl nitrate at 20℃; for 0.5h; Stage #2: at 499.84℃; for 6h; Calcination;

: 16774-21-3
ammonium cerium (IV) nitrate

: 13826-66-9
zirconyl nitrate

: cerium-zirconium oxide

Conditions

Conditions	Yield
Stage #1: ammonium cerium (IV) nitrate; zirconyl nitrate at 20℃; for 0.5h; Stage #2: at 499.84℃; for 6h; Calcination;

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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

OSHA PEL: TWA 5 mg(Zr)/m³; STEL 10 mg(Zr)/m³
ACGIH TLV: TWA 5 mg(Zr)/m³; STEL 10 mg(Zr)/m³
DFG MAK: 1 mg(Zr)/m³

Specification

The Zirconium, bis(nitrato-kO)oxo-, with the CAS registry number 13826-66-9 and EINECS registry number 237-529-3, has the systematic name of oxozirconium - nitric acid (1:2). It belongs to the following product categories: Inorganics; Metal and Ceramic Science; Salts; Zirconium Salts. And the molecular formula of this chemical is N₂O₇Zr. What's more, it is always used for the determination of potassium or fluoride.

The physical properties of Zirconium, bis(nitrato-kO)oxo- are as followings: (1)ACD/LogP: -0.13; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.13; (4)ACD/LogD (pH 7.4): -0.13; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)#H bond acceptors: 4; (8)#H bond donors: 1; (9)#Freely Rotating Bonds: 0; (10)Polar Surface Area: 55.05 Å².

You should be cautious while dealing with this chemical. If contact with combustible material, and may cause fire. And this chemical may cause burns. Therefore, you had better take the following instructions: Keep away from combustible material; Wear suitable protective clothing, gloves and eye/face protection, and in case of contact with eyes, rinse immediately with plenty of water and seek medical advice; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: O=[N+]([O-])O.[O-][N+](=O)O.O=[Zr]
(2)InChI: InChI=1/2HNO3.O.Zr/c2*2-1(3)4;;/h2*(H,2,3,4);;/r2HNO3.OZr/c2*2-1(3)4;1-2/h2*(H,2,3,4);
(3)InChIKey: UJVRJBAUJYZFIX-XSAJKTQWAD

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	intraperitoneal	1250mg/kg (1250mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)	Archives of Industrial Hygiene and Occupational Medicine. Vol. 1, Pg. 637, 1950.
rat	LD50	oral	2500mg/kg (2500mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)	Archives of Industrial Hygiene and Occupational Medicine. Vol. 1, Pg. 637, 1950.