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Name	5-Chloro-2-Fluoroaniline	EINECS	218-284-1
CAS No.	2106-05-0	Density	1.349 g/cm³
PSA	26.02000	LogP	2.64250
Solubility	N/A	Melting Point	N/A
Formula	C₆H₅ClFN	Boiling Point	214.4 °C at 760 mmHg
Molecular Weight	145.564	Flash Point	83.5 °C
Transport Information	UN 2810	Appearance	COLORLESS TO BROWN LIQUID
Safety	26-36-2636/37/39-23-36/37/39-45	Risk Codes	36/37/38-20/21/22-23/24/25
Molecular Structure		Hazard Symbols	Xn, Xi, T
Synonyms	Aniline,5-chloro-2-fluoro- (6CI,8CI);(5-Chloro-2-fluorophenyl)amine;3-Chloro-6-fluoroaniline;5-Chloro-2-fluorobenzenamine;NSC 10291;	Article Data	5

5-Chloro-2-Fluoroaniline Synthetic route

: 345-18-6
2-fluoro-5-chloronitrobenzene

: 2106-05-0
5-chloro-2-fluoroaniline

Conditions

Conditions	Yield
With hydrogen; platinum on activated charcoal In 1,2-dimethoxyethane under 2585.74 Torr; for 24h; Catalytic hydrogenation;

: 89-61-2
2,5-dichloronitrobenzene

potassium-compound of 1-<4-hydroxy-phenyl>-ethanone: potassium-compound of 1-<4-hydroxy-phenyl>-ethanone

: 2106-05-0
5-chloro-2-fluoroaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 52 percent / KF; 18-crown-6 / tetrahydrothiophene 1,1-dioxide / 32 h / 180 °C 2: H2 / 5 percent Pt/C / 1,2-dimethoxy-ethane / 24 h / 2585.74 Torr View Scheme

: 345-18-6
2-fluoro-5-chloronitrobenzene

A: 348-54-9
2-Fluoroaniline

B: 2106-05-0
5-chloro-2-fluoroaniline

Conditions

Conditions	Yield
With 5%-palladium/activated carbon; hydrazine hydrate In methanol at 80℃; for 0.0833333h; Overall yield = 25 %;

: C15H14ClFN2

: 2106-05-0
5-chloro-2-fluoroaniline

Conditions

Conditions	Yield
With sodium tetrahydroborate; copper(l) chloride In ethanol at 20℃;	24 mg

: 15426-14-9, 106131-20-8, 106131-24-2
3,3'-dichloroazobenzene

: 2106-05-0
5-chloro-2-fluoroaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: bis(dibenzylideneacetone)-palladium(0); N-fluorobis(benzenesulfon)imide; potassium nitrate / ethyl acetate / 12 h / 90 °C / Sealed tube 2: sodium tetrahydroborate; copper(l) chloride / ethanol / 20 °C View Scheme

: 1-(3-chlorophenyl)-2-(2,4,6-trimethylphenyl)diazene

: 2106-05-0
5-chloro-2-fluoroaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: bis(dibenzylideneacetone)-palladium(0); N-fluorobis(benzenesulfon)imide; potassium nitrate / ethyl acetate / 12 h / 100 °C / Sealed tube 2: sodium tetrahydroborate; copper(l) chloride / ethanol / 20 °C View Scheme

: C12H7Cl2FN2

: 2106-05-0
5-chloro-2-fluoroaniline

Conditions

Conditions	Yield
With sodium tetrahydroborate; copper(l) chloride In ethanol at 20℃;	28.8 mg

: 2106-05-0
5-chloro-2-fluoroaniline

: C6H4ClFIN

Conditions

Conditions	Yield
With iodine; silver sulfate In ethanol at 0 - 20℃; for 1h; Large scale;	98%

: 1089278-78-3
methyl 3-(3-{2-[(3-{[2-(dimethylamino)ethyl]oxy}phenyl)amino]-4-pyrimidinyl}-imidazo[1,2-a]pyridin-2-yl)benzoate

: 2106-05-0
5-chloro-2-fluoroaniline

: 1089278-77-2
N-(5-chloro-2-fluorophenyl)-3-(3-{2-[(3-{[2-(dimethylamino)ethyl]oxy}phenyl)amino]-4-pyrimidinyl}imidazo[1,2-a]pyridin-2-yl)benzamide

Conditions

Conditions	Yield
Stage #1: methyl 3-(3-{2-[(3-{[2-(dimethylamino)ethyl]oxy}phenyl)amino]-4-pyrimidinyl}-imidazo[1,2-a]pyridin-2-yl)benzoate; 5-chloro-2-fluoroaniline With sodium hexamethyldisilazane In tetrahydrofuran at 20℃; for 0.5h; Stage #2: With methanol In tetrahydrofuran	94%

: 2106-05-0
5-chloro-2-fluoroaniline

: 116369-24-5
4-bromo-5-chloro-2-fluoroaniline

Conditions

Conditions	Yield
With N-Bromosuccinimide In acetonitrile at 25℃; for 1h;	91%

5-Chloro-2-Fluoroaniline Chemical Properties

MF: C₆H₅ClFN
Synonyms: BUTTPARK 44\01-98;5-CHLORO-2-FLUOROPHENYLAMINE;5-CHLORO-2-FLUOROANILINE;5-Chloro-2-fluoroaniline 98%;5-Chloro-2-fluoroaniline98%
MW: 145.56
EINECS: 218-284-1
Product Categories: Anilines, Aromatic Amines and Nitro Compounds;Aniline;Miscellaneous
density : 1.29 g/mL at 25 °C(lit.)
bp : 102-105 °C20 mm Hg(lit.)
refractive index : n 20/D 1.561(lit.)
Fp : 219 °F

5-Chloro-2-Fluoroaniline Safety Profile

Risk Statements : 36/37/38-20/21/22-23/24/25
Safety Statements : 26-36-2636/37/39-23-36/37/39-45
Hazard Codes : Xi,T,Xn
Hazard Note : Toxic
RIDADR : UN2810
WGK Germany : 3
HazardClass : 6.1
PackingGroup : III

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