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Ammonium fluoride

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Name

Ammonium fluoride

EINECS 235-185-9
CAS No. 12125-01-8 Density 1.009 g/cm3
PSA 0.00000 LogP -2.61980
Solubility soluble in water Melting Point 98 °C
Formula FH4N Boiling Point 115 °C at 760 mmHg
Molecular Weight 37.0369 Flash Point N/A
Transport Information UN 2505 6.1/PG 3 Appearance white crystals
Safety 26-45-1/2-36/37/39 Risk Codes 23/24/25
Molecular Structure Molecular Structure of 12125-01-8 (Ammonium fluoride) Hazard Symbols ToxicT
Synonyms

Ammoniumfluoride (8CI);Ammonium fluoride (FH4N);Neutral ammonium fluoride;Wako013-03095;

 

Ammonium fluoride Chemical Properties

Product Name: Ammonium fluoride (CAS NO.12125-01-8)

Molecular Formula: NH4F
Molecular Weight: 37.04g/mol
Mol File: 12125-01-8.mol
EINECS: 235-185-9
Melting Point: 98°C
Boiling point: 115 °C at 760 mmHg
Storage Temperature: Store at RT.
Water Solubility: soluble
Stability: Stable. Incompatible with strong oxidizing agents, water, most common metals, strong bases, strong acids. Attacks glass.
Enthalpy of Vaporization: 23.33 kJ/mol
Vapour Pressure: 5990 mmHg at 25°C
H-Bond Donor: 2
H-Bond Acceptor: 2
Structure Descriptors of Ammonium fluoride (CAS NO.12125-01-8):
  IUPAC Name: azane hydrofluoride
  Canonical SMILES: N.F
  InChI: InChI=1S/FH.H3N/h1H;1H3 
InChIKey: LDDQLRUQCUTJBB-UHFFFAOYSA-N
Product Categories: Industrial/Fine Chemicals; Inorganic Chemicals;Inorganics; A-B, Puriss p.a. ACS; Analytical Reagents for General Use; Puriss p.a. ACS; Fluoride Sources; Fluoride SourcesMicro/Nanoelectronics; Deprotecting Reagents; Electronic Chemicals; Protection and Derivatization; Semiconductor Grade Chemicals; Ammonium Salts; Metal and Ceramic Science; Salts; ACS GradeSynthetic Reagents; Ammonium; Essential Chemicals; Inorganic Salts; Routine Reagents

Ammonium fluoride Toxicity Data With Reference

1.    

ipr-rat LD50:31 mg/kg

    XEURAQ    U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) UR-154 ,1951.
2.    

scu-frg LDLo:280 mg/kg

    CRSBAW    Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. 124 (1937),133.

Ammonium fluoride Consensus Reports

Reported in EPA TSCA Inventory.

Ammonium fluoride Safety Profile

Poison by subcutaneous and intraperitoneal routes. See also FLUORIDES. When heated to decomposition it emits very toxic fumes of F, NOx, and NH3. Incompatible with ClF3.
Hazard Codes:  T
The Risk Statements information of  AMMONIUM FLUORIDE:
23/24/25:  Toxic by inhalation, in contact with skin and if swallowed 
The Safety Statements information of  AMMONIUM FLUORIDE:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
1/2:  Keep locked up and out of the reach of children 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection 

Ammonium fluoride Standards and Recommendations

OSHA PEL: TWA 2.5 mg(F)/m3
ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: (fluorides, inorganic) TWA 2.5 mg(F)/m3
DOT Classification:  6.1; Label: KEEP AWAY FROM FOOD

Ammonium fluoride Specification

 Ammonium fluoride , its CAS NO. is 12125-01-8, the synonyms are Fluorure d'ammonium ; Neutral ammonium fluoride  ; Fluorek amonowy .

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