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Asbestos, crocidolite

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Name

Asbestos, crocidolite

EINECS N/A
CAS No. 12001-28-4 Density 3.3-3.4 g/cm3
PSA 460.24000 LogP -12.91380
Solubility N/A Melting Point N/A
Formula Fe2H16Mg3Na2O24Si8+14 Boiling Point N/A
Molecular Weight 765.98 Flash Point N/A
Transport Information N/A Appearance N/A
Safety Confirmed human carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data by inhalation. Human mutation data reported.

Analytical Methods:

   

For occupational chemical analysis use NIOSH: Fibers, 7400; Asbestos Fibers, 7402.

Risk Codes N/A
Molecular Structure Molecular Structure of 12001-28-4 (Crocidoliteasbestos) Hazard Symbols 3
Synonyms

Asbestos,crocidolite;Asbestos, magnesioriebeckite;Asbestos, riebeckite;Crocidolite;Riebeckite;Asbestos, crocidolite;Blue asbestos;Magnesioriebackite asbestos;Magnesioriebeckite;Magnesioriebeckite asbestos;Riebeckite asbestos;

 

Asbestos, crocidolite Chemical Properties

Molecular Formula: Na2(Fe,Mg)5Si8O22(OH)2
Mohs hardness: 5.0–6.0
Specific gravity: 3.0–3.4.
Water solubility: Insoluble

Asbestos, crocidolite History

Asbestos, crocidolite (12001-28-4) was named after German explorer Emil Riebeck (1853-1885).

Asbestos, crocidolite Uses

Asbestos, crocidolite (12001-28-4) was found on the island of Ailsa Craig in western Scotland, and it can be used in the manufacture of curling stones.It was also used for the facing stones of the Canton Viaduct from Moyles Quarry  now part of Borderland State Park in Massachusetts.

Asbestos, crocidolite Toxicity Data With Reference

1.    

oms-hmn:fbr 10 mg/L

    MUREAV    Mutation Research. 116 (1983),369.
2.    

dns-ham:oth 1280 ng/cm2

    CNREA8    Cancer Research. 42 (1982),3669.

Asbestos, crocidolite Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 14 (1977),p. 11.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) , IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 2 (1973),p. 17.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 14 (1977),p. 11.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . EPA Genetic Toxicology Program.

Asbestos, crocidolite Safety Profile

Confirmed human carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data by inhalation. Human mutation data reported.

Asbestos, crocidolite Standards and Recommendations

OSHA PEL: TWA 2 million fibers/m3; CL 10 million fibers/m3; Cancer Hazard
ACGIH TLV: TWA 0.1 fibers/cc; Confirmed Human Carcinogen
DFG MAK: DFG TRK: (Fine dust particles that are able to reach the alveolar area of the lung) crocidolite: 0.05 × 106 fibers/m3 (0.025 mg/m3) (definition of fiber: length greater than 5 µm; diameter less than 3 µm; length/diameter greater than 3:1, equivalent to 1 fiber/cc)
NIOSH REL: (asbestos): 0.1 fb/cc in a 400 L air sample
DOT Classification:  9; Label: CLASS 9

Asbestos, crocidolite Analytical Methods

For occupational chemical analysis use NIOSH: Fibers, 7400; Asbestos Fibers, 7402.

Asbestos, crocidolite Specification

Some forms of Asbestos, crocidolite (12001-28-4)'s are asbestiform, notably crocidolite, also known as blue asbestos.It is a sodium-rich member of the amphibole group of minerals. It crystallizes in the monoclinic system, usually as long prismatic crystals showing a diamond-shaped cross section, but also in fibrous, bladed, acicular, columnar, and radiating forms.Long term occupational exposure to the dust can result in lung cancer.Cleavage is perfect, two directions in the shape of a diamond; fracture is uneven, splintery. It is often translucent to nearly opaque.The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment.

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