- 14024-56-7Magnesium,bis(2,4-pentanedionato-kO2,kO4)-, (T-4)-
- 14024-58-9Manganese,bis(2,4-pentanedionato-kO2,kO4)-
- 14024-61-4Palladium,bis(2,4-pentanedionato-kO2,kO4)-, (SP-4-1)-
- 14024-63-6Zinc acetoacetonate
- 14024-64-7Titanium,oxobis(2,4-pentanedionato-kO2,kO4)-
- 14024-81-8Benzoic acid,4-methyl-, methyl ester
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Cas Database |
| Name |
Bis(acetylacetonato)cobalt |
EINECS | 237-855-6 |
| CAS No. | 14024-48-7 | Density | 0.83 g/cm3 (20℃) |
| PSA | 68.28000 | LogP | 1.10900 |
| Solubility | 5 g/L (20 °C) in water | Melting Point |
165-170 °C |
| Formula | C10H14CoO4 | Boiling Point | 138.4ºC at 760mmHg |
| Molecular Weight | 257.212 | Flash Point | 43.1ºC |
| Transport Information | N/A | Appearance | Purple fine crystalline powder |
| Safety | 22-36/37-45-24-37/39-26-7 | Risk Codes | 42/43-40-22-41-20/21/22 |
| Molecular Structure |
|
Hazard Symbols |
 Xn
|
| Synonyms |
Cobalt,bis(2,4-pentanedionato)- (6CI,8CI);Cobalt, bis(2,4-pentanedionato-O,O')-,(SP-4-1)-;Cobalt, bis(2,4-pentanedionato-kO,kO')-, (SP-4-1)- (9CI);Bis(2,4-pentanedionato)cobalt;Bis(2,4-pentanedionato)cobalt(II);Bis(acetylacetonate)cobalt;Bis(acetylacetonato)cobalt;Bis(acetylacetonato)cobalt(II);Cobaltbis(acetylacetonate);Cobalt diacetylacetonate;Cobalt(2+) acetylacetonate;Cobalt(2+) bis(acetylacetonate);Cobalt(II) acetylacetonate;Cobalt(II)bis(acetylacetonate);Cobaltous acetylacetonate;NSC 4652;NSC 52329;NacemCobalt; |
Article Data | 1 |
Bis(acetylacetonato)cobalt Synthetic route
- 14024-48-7
bis(acetylacetonato)cobalt(II)
- 776-74-9
Bromodiphenylmethane
- 19672-37-8
3-benzhydryl-pentane-2,4-dione
| Conditions | Yield |
|---|---|
| In chloroform for 17h; Heating; | 97% |
- 872290-35-2
3-bromo-5-methylcyclohex-1-ene
- 14024-48-7
bis(acetylacetonato)cobalt(II)
| Conditions | Yield |
|---|---|
| In chloroform at 85℃; for 2h; | 95% |
- 2746-25-0
p-Methoxybenzyl bromide
- 14024-48-7
bis(acetylacetonato)cobalt(II)
- 30881-24-4
3<(p-methoxyphenyl)methyl>-2,4-pentanedione
| Conditions | Yield |
|---|---|
| In chloroform for 17h; Heating; | 88% |
- 768-90-1
1-Adamantyl bromide
- 14024-48-7
bis(acetylacetonato)cobalt(II)
- 102402-84-6
3-(adamantan-1-yl)pentane-2,4-dione
| Conditions | Yield |
|---|---|
| In chlorobenzene for 24h; Heating; | 81% |
| In chloroform at 80℃; for 17h; | 76% |
- 14024-48-7
bis(acetylacetonato)cobalt(II)
- 585-71-7, 38661-81-3
(1-bromoethyl)benzne
- 5186-08-3
3-(1-phenyl-ethyl)-pentane-2,4-dione
| Conditions | Yield |
|---|---|
| In chloroform for 17h; Heating; | 75% |
- 7318-66-3
5-methylcyclohex-2-enyl chloride
- 14024-48-7
bis(acetylacetonato)cobalt(II)
| Conditions | Yield |
|---|---|
| In chloroform at 120℃; for 2h; | 71% |
- 14024-48-7
bis(acetylacetonato)cobalt(II)
- 585-71-7, 38661-81-3
(1-bromoethyl)benzne
A
- 1857-74-5, 2726-21-8, 4539-34-8, 4613-11-0, 71606-46-7, 5789-35-5
2,3-diphenylbutane
B
- 5186-08-3
3-(1-phenyl-ethyl)-pentane-2,4-dione
| Conditions | Yield |
|---|---|
| In chloroform at 80℃; for 1h; | A 21% B 54% |
- 14024-48-7
bis(acetylacetonato)cobalt(II)
- 585-71-7, 38661-81-3
(1-bromoethyl)benzne
A
- 1857-74-5, 2726-21-8, 4539-34-8, 4613-11-0, 71606-46-7, 5789-35-5
2,3-diphenylbutane
B
- 5186-08-3
3-(1-phenyl-ethyl)-pentane-2,4-dione
| Conditions | Yield |
|---|---|
| In chloroform at 80℃; for 1h; Product distribution; Mechanism; other halogenides; | A 21% B 54% C n/a |
- 100-39-0
benzyl bromide
- 14024-48-7
bis(acetylacetonato)cobalt(II)
A
- 1134-87-8
3-benzyl-pentane-2,4-dione
B
- 53316-00-0
3,3-dibenzyl-pentane-2,4-dione
| Conditions | Yield |
|---|---|
| In chloroform at 120℃; for 1h; | A 51% B 15% |
- 61608-88-6
(1-chlorohex-5-en-1-yl)benzene
- 14024-48-7
bis(acetylacetonato)cobalt(II)
A
- 56644-04-3
(E)-1-phenyl-1,5-hexadiene
| Conditions | Yield |
|---|---|
| In chloroform at 100℃; for 17h; | A 46% B 10% C 42% |
Bis(acetylacetonato)cobalt Chemical Properties
IUPAC: cobalt(2+); (Z)-4-oxopent-2-en-2-olate
CAS:14024-48-7
The Molecular formula of COBALT(III) ACETYLACETONATE (14024-48-7):C15H21CoO6
The Molecular Weight of COBALT(III) ACETYLACETONATE (14024-48-7):356.26
EINECS:244-527-6
Synonyms: TRIS(ACETYLACETONATO)COBALT(III) ; TRIS(2,4-PENTANEDIONATO)COBALT ; TRIS(2,4-PENTANEDIONATO)COBALT(III) ; TRIS(2,4-PENTANEDIONATO)COBALT(3) ; 4-pentanedionato-o,o’)-bis((beta-4)-cobal ; Acetylacetone cobalt(II) ; Bis(2,4-pentanedionato)cobalt ; bis(2,4-pentanedionato-O,O’)-,(T-4)-Cobalt
Melting Point:165-170oC
Boiling Point:138.4oC at 760mmHg
Flash Point:43.1oC
Vapour Pressure:0.174 mmHg at 25oC
Water Solubility:5 g/L (20oC)
Appearance:Purple solid.
Product Categories:Pharmaceutical Intermediates;Classes of Metal Compounds;Co (Cobalt) Compounds;Transition Metal Compounds
Mol File:14024-48-7.mol
Bis(acetylacetonato)cobalt Uses
COBALT(III) ACETYLACETONATE (14024-48-7) is an important catalyst for organic reactions. It is also used as a paint drier.
Bis(acetylacetonato)cobalt Safety Profile
Safty informations about COBALT(III) ACETYLACETONATE (14024-48-7):
Hazard Codes:Xn.gif){kind=small}
Risk Statements:42/43-40-22-41-20/21/22
42/43(May cause sensitization by inhalation and skin contact)
40(Limited evidence of a carcinogenic effect)
22(Harmful if swallowed)
41(Risk of serious damage to eyes)
20/21/22(Harmful by inhalation, in contact with skin and if swallowed)
Safety Statements:22-36/37-45-24-37/39-26-7
22(Do not breathe dust)
36/37(Wear suitable protective clothing and gloves)
45(In case of accident or if you feel unwell, seek medical advice immediately (show label where possible))
24(Avoid contact with skin)
37/39(Wear suitable gloves and eye/face protection)
26(In case of contact with eyes, rinse immediately with plenty of water and seek medical advice)
7(Keep container tightly closed)
WGK Germany:3
F:21
TSCA:Yes
HS Code:29420000
Bis(acetylacetonato)cobalt Specification
Handling and Storage:
Storage:Store in a cool, dry place. Store in a tightly closed container.
Handling:Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
First Aid Measures:
Ingestion:Get medical aid. Wash mouth out with water.
Inhalation:Remove from exposure to fresh air immediately. Get medical aid.
Skin:Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
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