100124-06-9

Basic information

• Product Name: DIBENZOFURAN-4-BORONIC ACID
• Synonyms: RARECHEM AH PB 0052;TIMTEC-BB SBB003426;DIBENZO[B,D]FURAN-4-YLBORONIC ACID;DIBENZOFURAN-4-BORONIC ACID;4-DIBENZOFURANBORONIC ACID;AKOS BRN-0085;Dibenzofuran-4-boronic acid, 98+%;dibenzofuran-4-ylboronic acid
• CAS NO: 100124-06-9
• Molecular Formula: C₁₂H₉BO₃
• Molecular Weight: 212.01
• EINECS: -0
• Product Categories: Heterocyclic Compounds;Boronic acid;Dibenzofuran;Organoborons;Boronic Acids;Boronic Acids and Derivatives;Heteroaryl;OLED materials,pharm chemical,electronic
• Mol File: 100124-06-9.mol

Chemical Properties

• Melting Point: 286-291 °C(lit.)
• Boiling Point: 438.5 °C at 760 mmHg
• Flash Point: 219 °C
• Appearance: Off-white to beige powder
• Density: 1.34 g/cm³
• Vapor Pressure: 0.011mmHg at 25°C
• Refractive Index: 1.485
• Storage Temp.: 0-6°C
• PKA: 8.04±0.30(Predicted)
• BRN: 1645426
• CAS DataBase Reference: DIBENZOFURAN-4-BORONIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: DIBENZOFURAN-4-BORONIC ACID(100124-06-9)
• EPA Substance Registry System: DIBENZOFURAN-4-BORONIC ACID(100124-06-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26-24/25
• WGK Germany: 3
• TSCA: No
• HazardClass: IRRITANT
• Hazardous Substances Data: 100124-06-9(Hazardous Substances Data)

Usage

Uses

Used in Pharmaceutical Industry:
Dibenzofuran-4-boronic acid is used as a cross-coupling agent for the synthesis of various pharmaceutical compounds. Its bond cleavage and hydrogen bonding properties make it a good target for drug synthesis, particularly in the development of anti-inflammatory medications.
Used in Chemical Synthesis:
Dibenzofuran-4-boronic acid is used as a reagent in chemical synthesis, particularly in the Suzuki coupling reaction. Advances in this area have been made through the use of methanol extraction and photophysical properties, improving the efficiency of the reaction and the overall yield of the desired product.
Used in Research and Development:
Dibenzofuran-4-boronic acid is used as a research compound for studying its properties and potential applications in various fields, including pharmaceuticals, materials science, and chemical synthesis. Its unique bond cleavage and hydrogen bonding characteristics make it an interesting target for further investigation and development.

InChI:InChI=1/C6H5BF2O2/c8-4-1-2-5(7(10)11)6(9)3-4/h1-3,10-11H

Synthetic route

4-bromodibenzofuran (89827-45-2) + Triisopropyl borate (5419-55-6) → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Stage #1: 4-bromodibenzofuran With n-butyllithium In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere; Stage #2: Triisopropyl borate In tetrahydrofuran at 20℃; for 8h;	94%
Stage #1: 4-bromodibenzofuran With n-butyllithium In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere; Stage #2: Triisopropyl borate In tetrahydrofuran at 20℃; for 8h;

dibenzofuran (132-64-9) + Trimethyl borate (121-43-7) + water (7732-18-5) → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Stage #1: dibenzofuran With n-butyllithium In tetrahydrofuran; hexane; acetone at -60 - 20℃; for 5h; Inert atmosphere; Stage #2: Trimethyl borate In tetrahydrofuran; hexane; acetone at -45 - 20℃; for 15h; Inert atmosphere; Stage #3: water With hydrogenchloride In tetrahydrofuran; hexane; acetone at 10 - 20℃; for 4h; Inert atmosphere;	93.8%
Stage #1: dibenzofuran With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1.5h; Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 12.5h; Stage #3: water With hydrogenchloride In tetrahydrofuran; hexane at 0℃;	69.3%

dibenzofuran (132-64-9) + bis(diisopropylamino)chloroborane (28049-80-1) + water (7732-18-5) → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Stage #1: dibenzofuran With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In hexane for 2h; Inert atmosphere; Reflux; Stage #2: bis(diisopropylamino)chloroborane In hexane at 0℃; Inert atmosphere; Stage #3: water With hydrogenchloride at 10℃; pH=2 - 3;	88%

dibenzofuran (132-64-9) + bromobis(dimethylamino)borane (6990-27-8) + water (7732-18-5) → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Stage #1: dibenzofuran With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In hexane for 2h; Inert atmosphere; Reflux; Stage #2: bromobis(dimethylamino)borane In hexane at -10℃; for 3h; Inert atmosphere; Stage #3: water With hydrogenchloride at -10 - 10℃; pH=2 - 3;	82%

4-bromodibenzofuran (89827-45-2) + Trimethyl borate (121-43-7) → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Stage #1: 4-bromodibenzofuran With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: Trimethyl borate In tetrahydrofuran; hexane at -78 - 20℃; for 2h; Inert atmosphere; Stage #3: With hydrogenchloride In tetrahydrofuran; hexane; water at 20℃; for 3h;	80%
Stage #1: 4-bromodibenzofuran With n-butyllithium In tetrahydrofuran at -78 - 0℃; for 1h; Inert atmosphere; Stage #2: Trimethyl borate In tetrahydrofuran at -78℃; Stage #3: With hydrogenchloride In tetrahydrofuran; water for 0.5h;	73%
Stage #1: 4-bromodibenzofuran With n-butyllithium In tetrahydrofuran at -78 - 0℃; for 1h; Inert atmosphere; Stage #2: Trimethyl borate In tetrahydrofuran at -78℃; for 12h; Stage #3: With hydrogenchloride; water In tetrahydrofuran for 0.5h;	73%
Stage #1: 4-bromodibenzofuran With n-butyllithium In tetrahydrofuran for 1h; Stage #2: Trimethyl borate In tetrahydrofuran at 20℃;	70%
Stage #1: 4-bromodibenzofuran With n-butyllithium In tetrahydrofuran for 2h; Cooling with acetone-dry ice; Stage #2: Trimethyl borate In tetrahydrofuran at -78 - 0℃; for 1h; Stage #3: With hydrogenchloride In tetrahydrofuran; water at 0 - 20℃; for 8h;

dibenzofuran (132-64-9) + chloro-bis(dimethylamino)borane (6562-41-0) + water (7732-18-5) → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Stage #1: dibenzofuran With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In hexane for 2h; Inert atmosphere; Reflux; Stage #2: chloro-bis(dimethylamino)borane In hexane at -10℃; Inert atmosphere; Stage #3: water With hydrogenchloride at 10℃; pH=2 - 3;	77%

dibenzofuran (132-64-9) + Trimethyl borate (121-43-7) → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Stage #1: dibenzofuran With n-butyllithium In tetrahydrofuran at -78℃; for 1h; Inert atmosphere; Stage #2: Trimethyl borate In tetrahydrofuran at 20℃; for 1h; Inert atmosphere;	48.5%

dibenzofuran (132-64-9) + Triisopropyl borate (5419-55-6) → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Stage #1: dibenzofuran With n-butyllithium In tetrahydrofuran; hexane at -68 - -20℃; for 1h; Inert atmosphere; Stage #2: Triisopropyl borate In tetrahydrofuran; hexane at -68 - 20℃; for 5h; Stage #3: With hydrogenchloride In tetrahydrofuran; hexane; water; ethyl acetate

dibenzofuran (132-64-9) → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Multi-step reaction with 2 steps 1.1: n-butyllithium / tetrahydrofuran; hexane / 6 h / -78 - 0 °C / Inert atmosphere 1.2: 10 h / 20 °C 2.1: n-butyllithium / tetrahydrofuran / 2 h / Cooling with acetone-dry ice 2.2: 1 h / -78 - 0 °C 2.3: 8 h / 0 - 20 °C View Scheme
Multi-step reaction with 2 steps 1.1: n-butyllithium / tetrahydrofuran / 2.5 h / -40 - 20 °C / Inert atmosphere 1.2: 2.5 h / -78 - 20 °C 2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere 2.2: -78 °C 2.3: 0.5 h View Scheme
Multi-step reaction with 2 steps 1.1: n-butyllithium / tetrahydrofuran / 2.5 h / -40 - 20 °C / Inert atmosphere 1.2: 2.5 h / -78 - 20 °C 2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 - 0 °C / Inert atmosphere 2.2: 12 h / -78 °C 2.3: 0.5 h View Scheme

Triisopropyl borate (5419-55-6) + C17H16O3Zn → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
With copper(I) iodide-lithium chloride In tetrahydrofuran at 20℃; Schlenk technique; Inert atmosphere;

4-bromodibenzofuran (89827-45-2) + Triisopropyl borate (5419-55-6) + water (7732-18-5) → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Stage #1: 4-bromodibenzofuran With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h; Inert atmosphere; Stage #2: Triisopropyl borate In tetrahydrofuran at -78 - 20℃; for 0.5h; Stage #3: water With hydrogenchloride In tetrahydrofuran

1-bromo-2-fluoro-3 iodobenzene → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Multi-step reaction with 4 steps 1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate; tetrabutyl-ammonium chloride / water; toluene; ethanol / 12 h / 78 °C / Inert atmosphere 2.1: boron tribromide / dichloromethane / 3.33 h / 20 °C / Inert atmosphere 3.1: sodium hydroxide / 1-methyl-pyrrolidin-2-one / 3 h / Reflux 4.1: n-butyllithium / tetrahydrofuran / 1 h 4.2: 20 °C View Scheme

2-Methoxyphenylboronic acid (5720-06-9) → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Multi-step reaction with 4 steps 1.1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate; tetrabutyl-ammonium chloride / water; toluene; ethanol / 12 h / 78 °C / Inert atmosphere 2.1: boron tribromide / dichloromethane / 3.33 h / 20 °C / Inert atmosphere 3.1: sodium hydroxide / 1-methyl-pyrrolidin-2-one / 3 h / Reflux 4.1: n-butyllithium / tetrahydrofuran / 1 h 4.2: 20 °C View Scheme

C13H10BrFO → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Multi-step reaction with 3 steps 1.1: boron tribromide / dichloromethane / 3.33 h / 20 °C / Inert atmosphere 2.1: sodium hydroxide / 1-methyl-pyrrolidin-2-one / 3 h / Reflux 3.1: n-butyllithium / tetrahydrofuran / 1 h 3.2: 20 °C View Scheme

C12H8BrFO → 4-dibenzofurylboronic acid (100124-06-9)

Conditions	Yield
Multi-step reaction with 2 steps 1.1: sodium hydroxide / 1-methyl-pyrrolidin-2-one / 3 h / Reflux 2.1: n-butyllithium / tetrahydrofuran / 1 h 2.2: 20 °C View Scheme

4-dibenzofurylboronic acid (100124-06-9) + para-bromotoluene (106-38-7) → 4-(4-methylphenyl)dibenzofuran

Conditions	Yield
With tetra-butylammonium acetate; Pd EnCat-30TM In ethanol at 120℃; for 0.166667h; Suzuki cross-coupling; microwave irradiation;	100%

4-dibenzofurylboronic acid (100124-06-9) + 3,5-Dichloroaniline (626-43-7) + Glyoxilic acid (298-12-4) → (dibenzofuran-4-yl)-(3,5-dichlorophenylamino)acetic acid (745013-41-6)

Conditions	Yield
In dichloromethane at 20℃;	100%

4-dibenzofurylboronic acid (100124-06-9) + 2-nitrophenyl bromide (577-19-5) → 4-(2-nitrophenyl)dibenzo[b,d]furan (1246308-80-4)

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; toluene for 12h; Reflux;	100%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene for 24h; Reflux;	99.7%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 3h; Reflux;	98%

4-dibenzofurylboronic acid (100124-06-9) + 2-(carboxymethyl)-4-iodobenzoic acid (1354742-59-8) → 2-(carboxymethyl)-4-(dibenzo[b,d]furan-4-yl)benzoic acid (1354742-90-7)

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water at 150℃; for 0.5h; Suzuki coupling; Inert atmosphere; Microwave irradiation;	100%

2-Chloro-3-nitropyridine (5470-18-8) + 4-dibenzofurylboronic acid (100124-06-9) → 2-(dibenzo[b,d]furan-4-yl)-3-nitropyridine

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene Inert atmosphere; Reflux;	100%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 6h; Inert atmosphere; Reflux;	84%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 6h; Suzuki Coupling; Reflux; Inert atmosphere;	84%

4-dibenzofurylboronic acid (100124-06-9) + 4-chlorobenzonitrile (100-00-5) → 4-(4'-nitrophenyl)dibenzofuran

Conditions	Yield
With caesium carbonate In N,N-dimethyl acetamide at 80℃; for 3.5h; Suzuki-Miyaura Coupling; Inert atmosphere; chemoselective reaction;	100%

benzoimidazole (51-17-2) + 4-dibenzofurylboronic acid (100124-06-9) → 1-(dibenzo[b,d]furan-4-yl)-1H-benzo[d]imidazole

Conditions	Yield
With copper(I) oxide In methanol at 20℃;	98%

4-dibenzofurylboronic acid (100124-06-9) + C10H9IO3 (1236563-13-5) → 5-(dibenzo[b,d]furan-4-yl)-2,2-dimethyl-4H-benzo[d][1,3]-dioxin-4-one (1456799-04-4)

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); sodium hydrogencarbonate In 1,2-dimethoxyethane; water at 110℃; for 0.0666667h; Suzuki Coupling; Inert atmosphere; Microwave irradiation;	98%

4-dibenzofurylboronic acid (100124-06-9) + 2-bromoaniline (615-36-1) → 2-(dibenzo[b,d]furan-4-yl)aniline (1559070-70-0)

Conditions	Yield
Stage #1: 4-dibenzofurylboronic acid; 2-bromoaniline With potassium carbonate In 1,2-dimethoxyethane; water at 20℃; for 0.5h; Inert atmosphere; Schlenk technique; Stage #2: With dichlorobis(tri-O-tolylphosphine)palladium In 1,2-dimethoxyethane; water at 80℃; for 12h; Inert atmosphere; Schlenk technique;	98%
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 120℃; for 3h;	88%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene for 5h; Reflux;	65%

p-nitrobenzene iodide (636-98-6) + 4-dibenzofurylboronic acid (100124-06-9) → 4-(4'-nitrophenyl)dibenzofuran

Conditions	Yield
With sodium phosphate; palladium on activated charcoal In water; isopropyl alcohol at 80℃; for 1h; Suzuki-Miyaura coupling reaction;	97%
With sodium phosphate dodecahydrate; palladium 10% on activated carbon In water; isopropyl alcohol at 80℃; for 1h; hetero-Suzuki-Miyaura cross-coupling; Inert atmosphere;	97%

4-dibenzofurylboronic acid (100124-06-9) + 2-chloro-5-bromonitrobenzene (41513-04-6) → C18H10ClNO3

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 120℃; for 2h;	97%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In water; toluene at 90℃; for 24h; Inert atmosphere;	65.49%

3-bromo-9-phenyl-9H-carbazole (1153-85-1) + 4-dibenzofurylboronic acid (100124-06-9) → 3-(dibenzofuran-4-yl)-9-phenyl-9H-carbazole

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 16h; Suzuki Coupling; Reflux;	97%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 16h; Suzuki Coupling; Reflux;	97%
In ethanol; water; toluene

4-dibenzofurylboronic acid (100124-06-9) + 3-bromo-N-phenyl-6-phenylcarbazole (1160294-85-8) → 3-dibenzofuran-4-yl-6,9-diphenyl-9H-carbazole

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 16h; Suzuki Coupling; Reflux;	97%

bromochlorobenzene (106-39-8) + 4-dibenzofurylboronic acid (100124-06-9) → 4-(4-chlorophenyl)dibenzo[b,d]furan

Conditions	Yield
With potassium carbonate In water; toluene at 90℃; for 2h; Suzuki-Miyaura Coupling; chemoselective reaction;	97%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran at 80℃; for 15h; Inert atmosphere;	80%

benzoic acid phenyl ester (93-99-2) + 4-dibenzofurylboronic acid (100124-06-9) → dibenzo[b,d]furan-4-yl(phenyl)methanone (99329-30-3)

Conditions	Yield
With [1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(ll) dichloride; water; potassium carbonate In tetrahydrofuran at 23℃; for 18h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere;	97%

4-dibenzofurylboronic acid (100124-06-9) + (6aR,10aR)-1-hydroxy-6,6,9-trimethyl-6a,7,10,10a-tetrahydro-6H-benzo[c]chromen-3-yl trifluoromethanesulfonate → (6aR,10aR)-3-(dibenzo[b,d]furan-4-yl)-6,6,9-trimethyl-6a,7,10,10a-tetrahydro-6H-benzo[c]chromen-1-ol

Conditions	Yield
With palladium diacetate; caesium carbonate; tricyclohexylphosphine In tetrahydrofuran; water; toluene at 80℃; Suzuki-Miyaura Coupling; Schlenk technique;	97%

[3-(bromo-phenyl)-thiazol-4-yl]-methanol (885280-57-9) + 4-dibenzofurylboronic acid (100124-06-9) → [2-(3-dibenzofuran-4-yl-phenyl)-thiazol-4-yl]methanol (1012315-89-7)

Conditions	Yield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water at 90℃; for 8h;	96%

4-dibenzofurylboronic acid (100124-06-9) + 1-bromo-4-(trimethylsilyl)benzene (6999-03-7) → (4-dibenzofuran-4-yl-phenyl)-trimethyl-silane (796072-24-7)

Conditions	Yield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 80℃; for 4h;	96%
Stage #1: 4-dibenzofurylboronic acid; 1-bromo-4-(trimethylsilyl)benzene With potassium carbonate In ethanol; water; toluene for 0.0833333h; Stage #2: tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 80℃; for 4h;	96%
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene at 80℃; for 4h;	96%

4-dibenzofurylboronic acid (100124-06-9) + para-bromoacetophenone (99-90-1) → 1-[4-(dibenzo[b,d]furan-4-yl)phenyl]ethanone (756484-37-4)

Conditions	Yield
With sodium phosphate; palladium on activated charcoal In water; isopropyl alcohol at 80℃; for 1h; Suzuki-Miyaura coupling reaction;	96%
With sodium phosphate dodecahydrate; palladium 10% on activated carbon In water; isopropyl alcohol at 80℃; for 1h; hetero-Suzuki-Miyaura cross-coupling; Inert atmosphere;	96%
With [Pd(N-(3-chloro-2-quinoxalinyl)-N'-(2,6-diisopropylphenyl)imidazolium)(PPh3)Cl2]; potassium carbonate In water at 70℃; for 3h; Catalytic behavior; Suzuki-Miyaura Coupling;	88%
With disodium[(N,N’-bis(2-hydroxy-5-sulfonatobenzyl)-1,2-diphenyl-1,2-diaminoethano)palladate(II)]; caesium carbonate In water at 80℃; for 1h; Suzuki-Miyaura Coupling;

4-dibenzofurylboronic acid (100124-06-9) + 3-bromo-5,5-dimethlycyclohex-2-en-1-one (13271-49-3) → 3-dibenzofuran-4-yl-5,5-dimethyl-cyclohex-2-enone (1056882-10-0)

Conditions	Yield
With potassium carbonate In ethanol; water at 110℃; for 0.0833333h; Suzuki coupling; Microwave irradiation;	96%
	96%

4-dibenzofurylboronic acid (100124-06-9) + dihydrogen peroxide (7722-84-1) → 4-hydroxydibenzofuran (19261-06-4)

Conditions	Yield
With ammonium bicarbonate In water at 20℃; for 2h; Schlenk technique;	96%

Upstream product

• 132-64-9 dibenzofuran 
• 5419-55-6 Triisopropyl borate 
• 89827-45-2 4-bromodibenzofuran 
• 7732-18-5 water 
• 958458-89-4 1-bromo-2-fluoro-3-iodobenzene 
• 5720-06-9 2-Methoxyphenylboronic acid 
• 6990-27-8 bromobis(dimethylamino)borane 
• 28049-80-1 bis(diisopropylamino)chloroborane 
• 6562-41-0 chloro-bis(dimethylamino)borane 
• 121-43-7 Trimethyl borate 

Downstream Products

• 1027019-64-2 3-dibenzofuran-4-yl-2-methoxy-benzaldehyde 
• 743453-07-8 N-(dibenzofuran-4-yl)-N-phenyl-amine 
• 99329-30-3 dibenzo[b,d]furan-4-yl(phenyl)methanone 
• 626605-16-1 3-{1-[3-(tert-butyldiphenylsilanyloxy)-propyl]-1H-pyrrolo[2,3-b]pyridin-3-yl}-4-dibenzofuran-4-yl-pyrrole-2,5-dione 
• 19261-06-4 4-hydroxydibenzofuran 
• 1012315-89-7 [2-(3-dibenzofuran-4-yl-phenyl)-thiazol-4-yl]methanol 
• 934292-87-2 tert-butyl 5-(benzyloxy)-2-(dibenzo[b,d]furan-4-yl)benzoate 
• 92185-79-0 4-(2-methoxyphenyl)dibenzofuran 
• 74104-10-2 4-phenyldibenzo[b,d]furan 

Relevant articles and documents

Deep blue organic light-emitting devices enabled by bipolar phenanthro[9,10-d]imidazole derivatives

Two blue fluorescent phenanthroimidazole derivatives (PhImFD and PhImTD) with a D-π-A structure are synthesized by attaching a hole-transporting dibenzofuran or dibenzothiophene and an electron-transporting phenanthroimidazole moiety and characterized. The nonplanar twisted structures reduce molecular aggregation, which endows both of the compounds with good thermal properties, and film-forming abilities as well as high quantum yields in CH2Cl2 and in the solid state. Non-doped organic light emitting diodes (OLEDs) are fabricated by employing the compounds PhImFD and PhImTD as emitters and exhibited promising performances. The devices show a deep blue emission with Commission Internationale de l'Eclairage (CIE) coordinates of (0.15, 0.11) for PhImFD and (0.15, 0.10) for PhImTD. PhImFD and PhImTD, with the desired bipolar-dominant characteristics, render devices with a low driving voltage of 3.6 V. The energy levels of the materials were found to be related to the donor units in the compounds with different substituents. Device B, using PhImTD as the emitting layer (EML), with well fitting energy levels and increased electron transport ability, possesses favorable efficiencies of 1.34 cd m-2 for CE, 0.82 lm W-1 for PE and 1.63% for EQE. PhImFD and PhImTD are utilized as blue emitters and the host for a yellow emitter, PO-01, to fabricate white organic light-emitting diodes (WOLEDs) that give a forward-viewing maximum CE of 8.12 cd m-2 and CIE coordinates of (0.339, 0.330). The results demonstrated not only that the phenanthroimidazole unit is an excellent building block to construct deep blue emission materials, but also that chemical structure modification by the introduction of a suitable electron-donor substituent could influence the performance of devices.

Copper-Catalyzed Monoorganylation of Trialkyl Borates with Functionalized Organozinc Pivalates

Organozinc pivalates, a recently developed air- and moisture-stable organozinc species, were found for the first time as excellent organometallic species in the monoorganylation of trialkyl borates whereby boronic acids were prepared in high yields. The significant advantage of organozinc pivalates over another previously employed organometallic reagents, e. g., organolithium reagents, Grignard reagents and organozinc halides, is that the generation of multiorganylation byproducts such as borinic acids and trialkylboranes were completely suppressed. Additionally, the in situ generated boronates could be directly arranged into Suzuki-Miyaura type cross-coupling reactions to produce biaryls in high yields.

Aromatic compound and organoelectroluminescent device comprising the compound

The present invention relates to an aromatic compound and an organic electroluminescent device including the same. The aromatic compound is represented by chemical formula 1, and the organic electroluminescent device is excellent in driving voltage, luminous efficiency and lifetime characteristics.

Compound, electronic element and electronic device

The invention provides a compound, an electronic component and an electronic device, and relates to the technical field of organic materials, wherein the compound is represented by a formula I, X1, X2and X3 are the same or different and are respectively and independently selected from carbon and nitrogen, X1, X2 and X3 are not carbon at the same time, L is selected from a single bond, arylene, heteroarylene, aryl alkylene and heteroaryl alkylene, Ar1 is selected from alkyl, cycloalkyl, aryl, heteroaryl, alkoxy, alkylamino, arylamino and arylalkylamino, and Ar2 and Ar3 are the same or different and are respectively and independently selected from cycloalkyl, aryl, heteroaryl, alkoxy, alkylamino, arylamino and arylalkylamino. The compound provided by the invention can reduce the working voltage of an electronic component, improve the luminous efficiency of the electronic component and prolong the service life of a device.

Synthesis method of dibenzofuran/thiophene-4-boric acid

The invention discloses a synthesis method of dibenzofuran/thiophene-4-boric acid, and belongs to the field of heterocyclic boric acid synthesis in organic chemistry. The synthesis method comprises the following steps: adding dibenzofuran or dibenzothioph

Terpyridine derivative and preparation method and application thereof as well as device

The invention belongs to the field of application science and technology of organic photoelectric materials, and particularly relates to a terpyridine derivative and a preparation method and application thereof as well as a device. The derivative provided by the invention is characterized by being mainly based on a terpyridine core, peripherally using a carbazole derivative and the like to regulate appropriate electron donating ability, and transforming different bridging groups through a D-A structure design to regulate the appropriate distribution of highest occupied molecular orbital (HOMO)and lowest unoccupied molecular orbital (LUMO); the derivative is mainly applied to TADF guest materials, host materials and carrier transport materials.

Fused cyclic compound and organoelectroluminescent device comprising the compound

PURPOSE: A condensed cyclic compound is provided to drive an organic electroluminescent device at low voltage and to improve brightness and economic efficiency. CONSTITUTION: A condensed cyclic compound is denoted by chemical formula 1. An organic electroluminescence device comprises an anode, a cathode, and a layer containing the condensed cyclic compounds, placed between the anode and the cathode. A light emitting layer between the anode and the cathode contains the condensed cyclic compounds. The organic electroluminescent device further comprises one or more layers selected among a hole injection layer, a hole transport layer, an electron blocking layer, a hole blocking layer, an electron transport layer, and an electron injection layer.

A iridium complex and its organic light-emitting device (by machine translation)

The invention discloses a metal iridium complex and its organic light-emitting device, relates to organic photoelectric material technical field. We will have the kind of cabeen structure of guanidine groups and bases as the auxiliary ligand is introduced

A pyrimidine derivatives and application thereof (by machine translation)

The invention discloses a pyrimidine derivative and its application, the pyrimidine derivatives having the following -like type (I) indicated by the structure; wherein said R1 , R2 , R3 Are selected from the carbon atom number is 1 - 60 alkyl, substituted and non-substituted aromatic heterocyclic radical, and substituted and non-substituted aromatic ring in base of any one group. The invention through the pyrimidine derivatives key chemical structure and the like is improved, and the pyrimidine derivatives as material is applied to the electro-luminescent layer in the organic electroluminescent device, compared with the prior art can effectively solve the organic electroluminescent device in blue light material of poor stability, low efficiency and the like. (by machine translation)

NOVEL TRIAZINE COMPOUND, AND ORGANIC ELECTRONIC ELEMENT AND PLANT-GROWING LIGHTING THAT USE THE SAME

PROBLEM TO BE SOLVED: To provide a triazine compound which has a high triplet energy level and excellent heat resistance, and can be used as an organic electronic element material realizing an element with high efficiency, low voltage and a long life. SOLUTION: In the triazine compound, as represented by the general formula [1] in the figure, a triazine backbone moiety is linked to a dibenzofuran or dibenzothiophene backbone moiety via a biphenyl backbone moiety, where X is an oxygen atom or sulfur atom. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPO&INPIT