1088-95-5

Basic information

• Product Name: Benzoic acid 2-(p-nitrophenyl)hydrazide
• Synonyms: Benzoic acid 2-(p-nitrophenyl)hydrazide;N'-(p-Nitrophenyl)benzhydrazide;N'-(4-Nitrophenyl)benzohydrazide
• CAS NO: 1088-95-5
• Molecular Formula: C₁₃H₁₁N₃O₃
• Molecular Weight: 257.24474
• Mol File: 1088-95-5.mol

Chemical Properties

• Melting Point: 193-194 °C(Solv: ethanol (64-17-5))
• Boiling Point: 394.2 °C at 760 mmHg
• Flash Point: 192.2 °C
• Appearance: /
• Density: 1.361 g/cm³
• Vapor Pressure: 2.02E-06mmHg at 25°C
• Refractive Index: 1.674
• PKA: 11.39±0.23(Predicted)
• CAS DataBase Reference: Benzoic acid 2-(p-nitrophenyl)hydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid 2-(p-nitrophenyl)hydrazide(1088-95-5)
• EPA Substance Registry System: Benzoic acid 2-(p-nitrophenyl)hydrazide(1088-95-5)

Safety Data

• Hazardous Substances Data: 1088-95-5(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 6, p. 841, 1965 DOI: 10.1016/S0040-4039(00)90028-5

InChI:InChI=1/C13H11N3O3/c17-13(10-4-2-1-3-5-10)15-14-11-6-8-12(9-7-11)16(18)19/h1-9,14H,(H,15,17)

Upstream product

• 13443-96-4 N-benzoyl-N'-(4-nitrophenyl)diazene 
• 65-85-0 benzoic acid 
• 636-99-7 4-nitrophenylhydrazine hydrochloride 
• 13443-96-4 C₁₃H₉N₃O₃ 
• 4231-62-3 1-benzoyl-1H-benzotriazole 
• 100-16-3 4-nitrophenylhydrazone 
• 861568-85-6 N-(4-nitro-phenyl)-N-nitroso-benzamidrazone 
• 7732-18-5 water 
• 98-88-4 benzoyl chloride 
• 106690-01-1 4a-Morpholin-4-yl-1-(4-nitro-phenyl)-3-phenyl-1,4a,5,6,7,7a-hexahydro-cyclopenta[1,3,4]oxadiazine 
• 7148-07-4 1-pyrrolidinocyclopent-1-ene 
• 93-97-0 benzoic acid anhydride 

Downstream Products

• 1374227-54-9 N'-(4-methoxyphenyl)-N'-(4-nitrophenyl)benzohydrazide 
• 27182-33-8 3-(4-nitro-phenyl)-5-phenyl-3H-[1,3,4]oxadiazol-2-one 
• 1418304-15-0 9b-methyl-3-(4-nitrophenyl)-1-phenyl-1,5,6,9b-tetrahydrothieno[3,2-c][1,2,4]triazolo[4,3-a]pyridine 
• 1418304-16-1 9b-cyclohexyl-3-(4-nitrophenyl)-1-phenyl-1,5,6,9b-tetrahydrothieno[3,2-c][1,2,4]triazolo[4,3-a]pyridine 
• 4106-21-2 3-methyl-1-(4-nitrophenyl)-1H-indazole 
• 64765-98-6 3-ethoxy-2-(4-nitro-phenyl)-5-phenyl-4-oxa-1,2-diaza-bicyclo[3.2.0]hept-6-ene-6,7-dicarboxylic acid diethyl ester 
• 64766-03-6 3t-[2-ethoxy-3-(4-nitro-phenyl)-5-phenyl-2,3-dihydro-[1,3,4]oxadiazol-2-yl]-acrylic acid ethyl ester 
• 63401-99-0 1,3-Bis[4-(2-benzoylhydrazino)phenyl]thiourea 
• 63402-04-0 1-[4-(2-Benzoylhydrazino)phenyl]-3-phenylthiourea 
• 128694-08-6 5-(ethylthio)-4-(p-nitrophenyl)-2-phenyl-6,6,7,7-tetramethyl-1,3,4-triazabicyclo<3.2.0>hept-2-ene 
• 128694-04-2 5-ethoxy-4-(p-nitrophenyl)-2-phenyl-6,6,7,7-tetramethyl-1,3,4-triazabicyclo<3.2.0>hept-2-ene 
• 128694-01-9 5-(2,3-dimethylbut-1-ene-3-yl)-1-(4-nitrophenyl)-3-phenyl-1,2,4-triazole 
• 25939-13-3 N-(p-nitrophenyl)benzohydrazonoyl chloride 
• 13443-96-4 N-benzoyl-N'-(4-nitrophenyl)diazene 

Relevant articles and documents

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Copper(ii)-catalyzed coupling reaction: An efficient and regioselective approach to N′,N′-diaryl acylhydrazines

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Reduction of Ag(I) by 1-acyl-2-arylhydrazines: Mechanism of photographic infectious development

The photographic process of 'infectious development' in which 1-acyl-2-arylhydrazines reduce Ag(I) has been studied using analogues. 1-Acyl-2-aryldiazenes, resulting from oxidation of 1-acyl-2-arylhydrazines, are hydrolysed to anions of aryldiazenes (ArN = NH), which undergo further oxidation with loss of nitrogen to yield aryl radicals. The aryl radicals cause 'feedback inhibition' which is prevented by the addition of benzhydrol.

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