25939-13-3

Basic information

• Product Name: N-(4-Nitrophenyl)benzenecarbohydrazonoylchloride
• Synonyms: N-(4-Nitrophenyl)benzenecarbohydrazonoylchloride;Benzoyl chloride (p-nitrophenyl)hydrazone;1-(4-Nitrophenyl)-2-(α-chlorobenzylidene)hydrazine;1-(Chlorophenylmethylene)-2-(4-nitrophenyl)hydrazine;1-(α-Chlorobenzylidene)-2-(4-nitrophenyl)hydrazine
• CAS NO: 25939-13-3
• Molecular Formula: C₁₃H₁₀ClN₃O₂
• Molecular Weight: 275.6904
• Mol File: 25939-13-3.mol
• Article Data: 7

Chemical Properties

• Melting Point: 191-191.5 °C
• Boiling Point: 423.6°Cat760mmHg
• Flash Point: 210°C
• Appearance: /
• Density: 1.31g/cm³
• Vapor Pressure: 2.2E-07mmHg at 25°C
• Refractive Index: 1.623
• PKA: 13.73±0.10(Predicted)
• CAS DataBase Reference: N-(4-Nitrophenyl)benzenecarbohydrazonoylchloride(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-Nitrophenyl)benzenecarbohydrazonoylchloride(25939-13-3)
• EPA Substance Registry System: N-(4-Nitrophenyl)benzenecarbohydrazonoylchloride(25939-13-3)

Safety Data

• Hazardous Substances Data: 25939-13-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron, 52, p. 661, 1996 DOI: 10.1016/0040-4020(95)00916-7

InChI:InChI=1/C13H10ClN3O2/c14-13(10-4-2-1-3-5-10)16-15-11-6-8-12(9-7-11)17(18)19/h1-9,15H/b16-13-

Upstream product

• 908094-04-2 phenyldiazomethane 
• 100-05-0 4-nitrobenzenediazonium chloride 
• 67-56-1 methanol 
• 98-88-4 benzoyl chloride 
• 100-16-3 4-nitrophenylhydrazone 
• 33786-33-3 anti-benzaldehyde (4'-nitrophenyl)hydrazone 
• 1088-95-5 1-benzoyl-2-(p-nitrophenyl)hydrazine 

Downstream Products

• 37628-12-9 4-ethoxy-5-methyl-1-(4-nitro-phenyl)-3-phenyl-1,4,5,6-tetrahydro-[1,2,4]diazaphosphinine 4-oxide 
• 104057-87-6 N-[1-Imidazol-1-yl-1-phenyl-meth-(E)-ylidene]-N'-(4-nitro-phenyl)-hydrazine 
• 142397-15-7 3-(4-Nitro-phenyl)-1-phenyl-3,3a-dihydro-[1,2,4]triazolo[4,3-a]quinoline 
• 98826-17-6 10-chloro-3,11b-diphenyl-1-(4-nitrophenyl)-5,6,7,11b-tetrahydro-1H-s-triazolo<4,3-d><1,4>benzodiazepin-6-one 
• 13788-77-7 1-(4-nitrophenyl)-3-phenyl-1H-pyrazole 
• 128694-04-2 5-ethoxy-4-(p-nitrophenyl)-2-phenyl-6,6,7,7-tetramethyl-1,3,4-triazabicyclo<3.2.0>hept-2-ene 
• 26631-44-7 1-p-nitrophenyl-3-phenyl-5-cyano-4,5-dihydro-2-pyrazoline 
• 162274-90-0 5,5,7a-trimethyl-1-(4-nitrophenyl)-3-phenyl-5,6-dihydro-7aH-oxazolo<2,3-c><1,2,4>triazole 
• 115591-24-7 5-methyl-1-(4-nitrophenyl)-3-phenyl-1H-1,2,4-triazole 

Relevant articles and documents

TRIAZINE MEDIATED LIVING RADICAL CONTROLLED POLYMERIZATION

The disclosure provides modular triazine-based unimolecular initiator compounds useful in controlled radical polymerizations of vinyl-containing monomers.

Synthesis of new thienopyridine derivatives by [3+2]- and [2+2]-cycloaddition reactions

The reaction of 6,7-dihydrothieno[3,2-c]pyridine derivatives with 1,3-dipoles, such as a nitrile oxides or nitrile imines, gave novel fused heterocycles. The Staudinger reaction of the starting material was also studied. This reaction was stereoselective

1,3-Dipolar Cycloadditions of 2-Ethoxy- and 2-(Ethylthio)-1-azetines with Nitrile Oxides, Nitrile Ylides and Nitrilimines: An Unexpected 1,2,4-Triazole Formation.

2-Ethoxy- and 2-(ethylthio)-1-azetines readily undergo 1,3-dipolar cycloadditions with nitrile oxides and nitrile ylides to give stable 4,5-bicyclic cycloadducts.With nitrilimines, however, the expected 1,3-dipolar cycloadducts and/or unexpected ring-open