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116128-29-1

Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)

    Cas No: 116128-29-1

  • USD $ 1.9-2.9 / Gram

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  • 116128-29-1 Structure

  • Basic information

    1. Product Name: Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)
    2. Synonyms: Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II);(R)-Ru(OAc)2(T-BINAP);Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-tolbinap];Ru(OAc)2[(R)-tolbinap];-binaphthyl]ruthenium(II),Ru(OAc)2[(R)-tolbinap]
    3. CAS NO:116128-29-1
    4. Molecular Formula: C52H46O4P2Ru
    5. Molecular Weight: 899.952642
    6. EINECS: N/A
    7. Product Categories: Ru
    8. Mol File: 116128-29-1.mol

  • Chemical Properties

    1. Melting Point: >100°C
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: brown/Powder
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: 2-8°C
    8. Solubility: N/A
    9. Sensitive: air sensitive
    10. CAS DataBase Reference: Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)(CAS DataBase Reference)
    11. NIST Chemistry Reference: Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)(116128-29-1)
    12. EPA Substance Registry System: Diacetato[(R)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl]ruthenium(II)(116128-29-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany: 3
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 116128-29-1(Hazardous Substances Data)

116128-29-1 Usage

Uses

Ru(OAc)2[(S)-tolbinap] is used as a catalyst.

Check Digit Verification of cas no

The CAS Registry Mumber 116128-29-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,6,1,2 and 8 respectively; the second part has 2 digits, 2 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 116128-29:
(8*1)+(7*1)+(6*6)+(5*1)+(4*2)+(3*8)+(2*2)+(1*9)=101
101 % 10 = 1
So 116128-29-1 is a valid CAS Registry Number.

116128-29-1 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail

  • TCI America

  • (R0168)  Ru(OAc)2[(R)-tolbinap]  

  • 116128-29-1

  • 200mg

  • 430.00CNY

  • Detail

  • TCI America

  • (R0168)  Ru(OAc)2[(R)-tolbinap]  

  • 116128-29-1

  • 1g

  • 1,590.00CNY

  • Detail

  • Aldrich

  • (692239)  (R)-Ru(OAc)2(T-BINAP)  

  • 116128-29-1

  • 692239-100MG

  • 286.65CNY

  • Detail

  • Aldrich

  • (692239)  (R)-Ru(OAc)2(T-BINAP)  

  • 116128-29-1

  • 692239-500MG

  • 1,102.14CNY

  • Detail

116128-29-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Ruthenium(2+) acetate 1,1'-binaphthalene-2,2'-diylbis[bis(4-methy lphenyl)phosphine] (1:2:1)

1.2 Other means of identification

Product number -
Other names Ru(OAc)2((R)-Tol-BINAP)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:116128-29-1 SDS

116128-29-1Downstream Products

116128-29-1Relevant articles and documents

METHOD FOR PRODUCING A RUTHENIUM COMPLEX

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Page/Page column 6, (2010/04/23)

Provided is a method for producing a ruthenium complex comprises the step of reacting a ruthenium compound represented by general formula (1): [in-line-formulae][RuX(L)(PP)]X ??(1),[/in-line-formulae] wherein Ru represents a ruthenium atom; X represents a halogen atom; L represents an arene; and PP represents an optically active bisphosphine, with a carboxylate salt represented by general formula (2): [in-line-formulae]R1CO2M ??(2),[/in-line-formulae] wherein M represents a monovalent cation; and R1 represents a group selected from the group consisting of alkyl groups, haloalkyl groups, phenyl groups optionally having a substituent(s), 1-aminoalkyl groups and 1-amino-1-phenylalkyl groups, to produce a ruthenium complex represented by general formula (3): [in-line-formulae]Ru(OCOR1)2(PP) ??(3),[/in-line-formulae] wherein R1 represents the group selected from the group consisting of alkyl groups, haloalkyl groups, phenyl groups optionally having a substituent(s), 1-aminoalkyl groups and 1-amino-1-phenylalkyl groups; and PP represents the optically active bisphosphine.

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