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DIMETHYL(PENTAFLUOROPHENYL)SILANE, also known as pentafluorophenylsilane or pentamethyldisilane, is a chemical compound characterized by its molecular formula C8H9F5Si. It is a clear, colorless liquid with a pungent odor and is recognized for its high flammability. DIMETHYL(PENTAFLUOROPHENYL)SILANE is a versatile entity in the field of chemistry, serving various roles in different industries.

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  • 13888-77-2 Structure
  • Basic information

    1. Product Name: DIMETHYL(PENTAFLUOROPHENYL)SILANE
    2. Synonyms: DIMETHYL(PENTAFLUOROPHENYL)SILANE;(pentafluorophenyl)dimethylsilane;2,3,4,5,6-Pentafluoro-1-dimethylsilylbenzene;Dimethyl-pentafluorophenylsilane,(Pentafluorophenyl)dimethylsilane;(Dimethylsilyl)perfluorobenzene;(Dimethyl)(perfluorophenyl)silane, (Dimethyl)(pentafluorophenyl)silane;DiMethyl(perfluorophenyl)silane;(Dimethyl)(pentafluorophenyl)silane, (Dimethylsilyl)pentafluorobenzene
    3. CAS NO:13888-77-2
    4. Molecular Formula: C8H7F5Si
    5. Molecular Weight: 226.22
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 13888-77-2.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 61-62 °C20 mm Hg(lit.)
    3. Flash Point: 105 °F
    4. Appearance: /
    5. Density: 1.295 g/mL at 25 °C(lit.)
    6. Vapor Pressure: 2.66mmHg at 25°C
    7. Refractive Index: n20/D 1.431(lit.)
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: DIMETHYL(PENTAFLUOROPHENYL)SILANE(CAS DataBase Reference)
    11. NIST Chemistry Reference: DIMETHYL(PENTAFLUOROPHENYL)SILANE(13888-77-2)
    12. EPA Substance Registry System: DIMETHYL(PENTAFLUOROPHENYL)SILANE(13888-77-2)
  • Safety Data

    1. Hazard Codes: Xi,F
    2. Statements: 10-36/37/38
    3. Safety Statements: 26-36
    4. RIDADR: UN 1993 3/PG 3
    5. WGK Germany: 3
    6. RTECS:
    7. F: 10-21
    8. HazardClass: 3.2
    9. PackingGroup: III
    10. Hazardous Substances Data: 13888-77-2(Hazardous Substances Data)

13888-77-2 Usage

Uses

Used in Organic Synthesis:
DIMETHYL(PENTAFLUOROPHENYL)SILANE is used as a reagent in organic synthesis for its ability to facilitate specific chemical reactions, contributing to the formation of desired products in the synthesis process.
Used in Silicon-Containing Polymers and Materials Production:
It is utilized as a precursor in the production of silicon-containing polymers and materials, where its unique properties enhance the characteristics of the final products.
Used as a Crosslinking Agent in Silicone Rubber Synthesis:
DIMETHYL(PENTAFLUOROPHENYL)SILANE is used as a crosslinking agent in the synthesis of silicone rubber, playing a crucial role in determining the rubber's physical properties such as elasticity and durability.
Used as a Protective Agent for Metal Surfaces:
DIMETHYL(PENTAFLUOROPHENYL)SILANE serves as a protective agent for metal surfaces, providing a layer that can prevent corrosion or other forms of degradation, thus extending the life of metal components.
Used in Pharmaceutical Industry:
DIMETHYL(PENTAFLUOROPHENYL)SILANE finds application in the pharmaceutical industry, potentially contributing to the development of new drugs or the improvement of drug delivery systems.
Used in Semiconductor Industry:
It is also utilized in the semiconductor industry, where its properties may be harnessed in the manufacturing of electronic components or in processes that require precise material properties.
It is crucial to handle DIMETHYL(PENTAFLUOROPHENYL)SILANE with care due to its reactive nature with water and air, and its potential to cause irritation to the skin, eyes, and respiratory system. Proper safety measures should be taken to mitigate any risks associated with its use.

Check Digit Verification of cas no

The CAS Registry Mumber 13888-77-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,8,8 and 8 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 13888-77:
(7*1)+(6*3)+(5*8)+(4*8)+(3*8)+(2*7)+(1*7)=142
142 % 10 = 2
So 13888-77-2 is a valid CAS Registry Number.
InChI:InChI=1/C8H7F5Si/c1-14(2)8-6(12)4(10)3(9)5(11)7(8)13/h14H,1-2H3

13888-77-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name Dimethylpentafluorophenylsilane

1.2 Other means of identification

Product number -
Other names DIMETHYL(PENTAFLUOROPHENYL)SILANE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13888-77-2 SDS

13888-77-2Relevant articles and documents

Synthesis of hydrosilanes: Via Lewis-base-catalysed reduction of alkoxy silanes with NaBH4

Aoyagi, Keiya,Ohmori, Yu,Inomata, Koya,Matsumoto, Kazuhiro,Shimada, Shigeru,Sato, Kazuhiko,Nakajima, Yumiko

supporting information, p. 5859 - 5862 (2019/05/27)

Hydrosilanes were synthesized by reduction of alkoxy silanes with BH3 in the presence of hexamethylphosphoric triamide (HMPA) as a Lewis-base catalyst. The reaction was also achieved using an inexpensive and easily handled hydride source NaBH4, which reacted with EtBr as a sacrificial reagent to form BH3in situ.

Si-based benzylic 1,4-rearrangement/cyclization reaction

Trost, Barry M.,Bertogg, Andreas

supporting information; experimental part, p. 511 - 513 (2009/07/10)

(Chemical Equation Presented) The trans-selective hydrosilylation of ynones (1) yields ss-silylated enones (2) that undergo a benzylic 1,4-rearrangement/cyclization reaction in the presence of base, yielding 2,5-dihydro-1,2-oxasiloles (3).

Peculiarities in the cleavage by methyllithium of unsymmetrical disilanes

Hevesi,Dehon

, p. 8031 - 8032 (2007/10/02)

The title reactions did not produce the more stable silyl anions from the disilanes studied, they either occurred by attack at the more electrophilic silicon atom, or led to unexpected products.

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