13940-22-2Relevant articles and documents
Photocatalytic reduction of Se(VI) in aqueous solutions in UV/TiO2 system: Importance of optimum ratio of reactants on TiO2 surface
Tan, Timothy T.Y.,Beydoun, Donia,Amal, Rose
, p. 73 - 85 (2003)
This study investigates the effect of pH, initial concentrations of formic acid and selenate (Se(VI)) ions on the UV/TiO2 reduction of Se(VI) ions. The adsorption of Se(VI) and formate ions onto TiO2 surface was essential before the
Acidity, basicity, and gas-phase ion chemistry of hydrogen selenide by ion cyclotron resonance spectroscopy
Dixon, David A.,Holtz, David,Beauchamp
, p. 960 - 963 (1972)
Reaction pathways, product distributions, and rate constants have been determined for the gas-phase ion-molecule reactions of H2Se by ion cyclotron resonance spectroscopy. Hydrogen selenide fragment ions condense with neutral H2Se, e
About selenidostannates. I: Synthesis, structure, and properties of [Sn2Se6]4-, [Sn4Se10]4-, and [Sn3Se7]2-
Fehlker, Andreas,Blachnik, Roger
, p. 411 - 418 (2008/10/08)
The selenidostannates [(C4H9)2NH2]4Sn 2Se6·H2O (I), [(C4H9)2NH2]4Sn 4Se10·2H2O (II) und [(C3H7)3NH]2-Sn3Se 7 (III) were prepared by hydrothermal syntheses from the elements and the amines. I crystallizes in the monoclinic spacegroup P21/n (a = 1262.9(3) pm, b = 1851.3(4) pm, c = 2305.2(4) pm, β = 104.13(3)° and Z = 4). The [Sn2Se6]4- anion consists of two edge-sharing tetrahedra. II crystallizes in the orthorhombic spacegroup Pna21 (a = 2080.3(4) pm, b = 1308.2(3) pm, c = 2263.5(5) pm and Z = 4). The anion is formed from four SnSe4 tetrahedra which are joined by common corners to the adamantane cage [Sn4Se10]4-. III crystallizes in the orthorhombic spacegroup Pbcn (a = 1371.1(3) pm, b = 2285.4(5) pm, c = 2194.7(4) pm and Z = 8). The anion is a chain, built from edge-sharing [Sn3Se5Se4/2]2- units, in which two corner sharing tetrahedra are connected to a trigonal bipyramid by an edge of one and a corner of the other tetrahedron. The results of the TG/DSC measurements and of temperature dependent X-ray diffractograms reveal that I and II decompose at first by release of minor quantities of triethylammonium to compounds with layer structure and larger cell dimensions. At still higher temperature the rest of triethylammonium and H2Se is evolved, leaving SnSe2 and Se in the bulk. The former decomposes partially at the highest temperature to SnSe. In the measurements of III the complex intermediate compound was not observed. III decomposes directly to SnSe2. Wiley-VCH Verlag GmbH, 2001.
Synthesis and Vibrational Spectroscopic Investigation of [H3B-Se-Se-BH3](2-) and [H3B-mu.2-Se(B2H5)](1-) Crystal Structure and Theoretical Investigation of the Molecular Structure of [H3B-mu.2-Se(B2H5)](1-)
Binder, H.,Duttlinger, I.,Loos, H.,Locke, K.,Pfitzner, A.,et al.
, (2008/10/08)
M2[H3B-Se-Se-BH3] 1 is produced by the reaction between elemental selenium and MBH4 (1:1) in triglyme (diglyme), under dehydrogenation. 1 reactswith an excess of B2H6 to give M[H3B-μ2-Se(B2H5)] 2 which is also fo rmed in the reaction of THF*BH3 with 1. These reactions proceed under cleavage of the Se-Se bond and hydrogen evolution. [(C6H5)4P]Br reacts with Na*2 to form [(C6H5)4P]*2 which crystallizes in the tetragonal space grou I4-(No.82) An X-ray structure determination failed because of disordering of the cation and anion. (11)B, (77)Se NMR shifts and (1)J((11)B(1)H) coupling constants as well as IR- and Raman spectroscopic investigations convey further structural informations. Structural data of 2 have been calculated by SCF methods. The anion of 2 may be viewed either as anadduct of Se with B3H8(1-), or as a bridge substituted selena derivativ e of B2H6.
