142891-22-3Relevant articles and documents
Process for the preparation of α-chloromethylene-triorganylphosphorane derivatives
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, (2008/06/13)
A process for the preparation of α-chloromethylene-triorganylphosphorane derivatives I (radicals R areC-organic substituents and A stands forCNorCO-B where B is aC-organic orO-organic radical which is inert under chlorination conditions) by chlorination of phosphoranes II with chlorine, wherein the chlorination is carried out in the presence of a mineral base as hydrogen chloride acceptor and the chlorine and base are fed to the reaction mixture concurrently but separately at the rates at which they are consumed. The reaction products I are important intermediates for plant protectants.
Process for the preparation of chlorine-substituted olefins
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, (2008/06/13)
Chlorine-substituted olefins I STR1 (R1 =organic radical; R2 =--CN, --CO--R3, --CO--S--R3, --CO--O--R3 --CO--N(R4,R5); R3 =organic radical; R4, R5/sup