14794-99-1

Basic information

• Product Name: TIN (II) METHOXIDE
• Synonyms: TIN (II) METHOXIDE;tetramethoxytin;Tin(Ⅱ) Methoxide
• CAS NO: 14794-99-1
• Molecular Formula: C₂H₆O₂Sn
• Molecular Weight: 180.78
• Mol File: 14794-99-1.mol

Chemical Properties

• Melting Point: 242-243°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /Powder
• Density: g/cm³
• Sensitive: Moisture Sensitive
• CAS DataBase Reference: TIN (II) METHOXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: TIN (II) METHOXIDE(14794-99-1)
• EPA Substance Registry System: TIN (II) METHOXIDE(14794-99-1)

Safety Data

• RIDADR: UN3180
• TSCA: No
• HazardClass: 4.1
• PackingGroup: II
• Hazardous Substances Data: 14794-99-1(Hazardous Substances Data)

Usage

Uses

Used in Organic Chemical Reactions:
Tin (II) methoxide is used as a catalyst for various organic chemical reactions, particularly in the synthesis of polymers and other organic compounds. Its catalytic activity facilitates the formation of desired products, improving the efficiency and selectivity of these reactions.
Used in the Production of Coatings, Adhesives, and Sealants:
Tin (II) methoxide is utilized in the manufacturing process of coatings, adhesives, and sealants. Its presence in these products contributes to their adhesive and binding properties, enhancing their performance and durability.
Used in Nanotechnology:
Tin (II) methoxide has potential applications in the field of nanotechnology, specifically for the preparation of tin oxide nanoparticles. These nanoparticles have a wide range of uses, including in electronics, optics, and sensing applications.
Safety Precautions:
Due to its highly flammable nature, tin (II) methoxide should be handled with care in a well-ventilated environment to minimize the risk of fire or explosion. Proper safety measures, such as wearing protective gear and following safety protocols, are essential when working with this compound.

InChI:InChI=1/2CH3O.Sn/c2*1-2;/h2*1H3;/q2*-1;+2/rC2H6O2Sn/c1-3-5-4-2/h1-2H3

Upstream product

• 67-56-1 methanol 
• 7440-31-5 tin 
• 7440-23-5 sodium 
• 124-41-4 sodium methylate 
• 1067-21-6 triethylmethoxystannane 
• 875217-50-8 dimethoxystannane 

Downstream Products

• 22541-90-8 tin(II) 
• 73296-25-0 bis(O,O'-diphenyl dithiophosphato)tin(II) 
• 14254-05-8 tin(II) n-butoxide 
• 638-39-1 tin(II) acetate 

Relevant articles and documents

Rational Syntheses and Serendipity: Complexes [LSnPtCl2(SMe2)]2, [{LSnPtCl(SMe2)}2SnCl2], [(LSn)3(PtCl2)(PtClSnCl){LSn(Cl)OH}], and [O(SnCl)2(SnL)2] with L=MeN(CH2CMe2O)2

Syntheses and molecular structures of the dimeric tin–platinum complex [LSnPtCl2(SMe2)]2 (2), the tin–platinum clusters [{LSnPtCl(SMe2)}2SnCl2)] (3) and [(LSn)3(PtCl2)(PtClSnCl)(LSnOHCl)] (6) (L=MeN(CH2CMe2O?)2), and of the unprecedented tin(II) aminoalkoxide–tin oxide chloride complex [O(SnCl)2?(SnL)2] (5) are reported. The compounds were characterized by NMR spectroscopy (1H, 13C, 119Sn, 195Pt), 119Sn M?ssbauer spectroscopy (1–3, 6), electrospray ionization mass spectrometry, elemental analyses, and single-crystal X-ray diffraction analyses (2?CH2Cl2, 3?2 C4H8O, 5, 6?3CH2Cl2). The tin(II) aminoalkoxide [MeN(CH2CMe2O)2Sn]2 (1) behaves like a neutral ligand, inserts into a Pt?Cl bond, or is involved in rearrangement reactions with the different behavior occurring even within one compound (3, 6). DFT calculations show that the tin–platinum compounds behave like electronic chameleons.

Anodic dissolution of tin in alcohols

Tin(II) alcoholates Sn(OR)2 are formed upon the anodic galvanostatic dissolution of tin in alcohols in an undivided cell in the presence of minimum amounts of NaOAc as an electrolyte. Tin(II) alcoholates are easily hydrolyzed in air to form oxy

A study on the carboxylation of glycerol to glycerol carbonate with carbon dioxide: The role of the catalyst, solvent and reaction conditions

Glycerol was reacted with CO2 (5 MPa) at 450 K in presence of Sn-catalysts (n-Bu2Sn(OMe)2 1, n-Bu2SnO 2 or Sn(OMe)2 3), using either glycerol or tetraethylene glycol dimethyl ether (tedmg) as reaction medium. 1 was much more active than 2. 1 was demonstrated to convert into n-Bu2Sn(glycerol-2H) 4 upon reaction with glycerol and elimination of MeOH. Monomeric 4 is proposed to be the active species in catalysis. It converted into a polymeric material with time with consequent reduction of its catalytic activity. Also, after the first catalytic cycle 4 was converted into an oligomeric material that did not contain glycerol. This also caused the reduction of the catalytic activity. 3 was able to uptake CO2 but was not able to promote the carboxylation of glycerol. 1 and 2 also promoted the trans-esterification of dimethylcarbonate (DMC) with glycerol to afford glycerol carbonate, but at a lower rate than the direct carboxylation of glycerol. This fact seems to rule out that the carboxylation of glycerol may proceed through the preliminary formation of DMC and its subsequent trans-esterification.

A new method for synthesizing dialkoxytin(II) and mono and diaryloxytin(II) compounds

The reactions of bis(β-diketonato)tin(II), such as bis(2, 4-pentanedionato)tin(II), Sn(acac)2, bis(1-ethoxy-1, 3-butanedionato)tin(II), Sn(etac)2, and bis(1-methoxy-1, 3-butanedionato)-tin(II), Sn(mtac)2, with sodium alkoxide (NaOR, R = CH3, C2H5) in alcohol/benzene at room temperature have been found to give the corresponding dialkoxytin(II) compounds. Sn(acac)2 reacted also with o-substituted phenols [O-X-C6H4OH; X = CH3CO, CH3OC(O), CH3O, Cl, (CH3)3C] in a molar ratio of 1:2 at 90°C to afford the corresponding monosubstituted tin(II) compound, [Sn(OC6H4-X)(acac)], but the reaction with C6H5OH produced only the diphenoxide, Sn(OC6H5)2.