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19856-23-6

Articles about 19856-23-6Total 3 be found

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Efficient and Bio-inspired Conversion of Cellulose to Formic Acid Catalyzed by Metalloporphyrins in Alkaline Solution
A bio-inspired approach for efficient conversion of cellulose to formic acid (FA) was developed in an aqueous alkaline medium. Metalloporphyrins mimicking cytochrome P450 exhibit efficiently and selectively catalytic performance in catalytic conversion of cellulose. High yield of FA about 63.7% was obtained by using sulfonated iron(III) porphyrin as the catalyst and O2 as the oxidant. Iron(III)-peroxo species, TSPPFeIIIOO?, was involved to cleave the C-C bonds of gluconic acid to FA in this catalytic system. This approach used relatively high concentration of cellulose and ppm concentration of catalyst. This work may provide a bio-inspired route to efficient conversion of cellulose to FA.
Liu, Qiang,Zhou, Doudou,Li, Zongxiang,Luo, Weiping,Guo, Cancheng
supporting information
p. 1063 - 1068
(2017/07/24)

PROCESS TO PREPARE LEVULINIC ACID
The invention describes processes to prepare levulinic acid, formic acid and/or hydroxymethyl furfural from various biomass materials.
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Paragraph 0531

(2014/12/12)

GLYCEROL LEVULINATE KETALS AND THEIR USE
The present disclosure relates to the preparation of ketal compounds from glycerol and levulinic acid and esters, and uses thereof.
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Page/Page column 42-43

(2008/06/13)

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Chemical Properties

Boiling Point: 242.9 °C at 760 mmHg
Flash Point:115 °C
Density: 1.129g/cm3
Vapor Pressure: 0.018Pa at 135℃
PSA: 57.20000
LogP: -0.89450

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