19917-00-1

Basic information

• Product Name: trimethyl[(1-phenylprop-2-en-1-yl)oxy]silane
• CAS NO: 19917-00-1
• Molecular Formula: C₁₂H₁₈OSi
• Molecular Weight: 206.3562
• Mol File: 19917-00-1.mol

Chemical Properties

• Boiling Point: 237.2°C at 760 mmHg
• Flash Point: 92°C
• Density: 0.912g/cm³
• Vapor Pressure: 0.0697mmHg at 25°C
• Refractive Index: 1.482
• CAS DataBase Reference: trimethyl[(1-phenylprop-2-en-1-yl)oxy]silane(CAS DataBase Reference)
• NIST Chemistry Reference: trimethyl[(1-phenylprop-2-en-1-yl)oxy]silane(19917-00-1)
• EPA Substance Registry System: trimethyl[(1-phenylprop-2-en-1-yl)oxy]silane(19917-00-1)

Safety Data

• Hazardous Substances Data: 19917-00-1(Hazardous Substances Data)

Usage

Uses

Used in Adhesives and Sealants Industry:
Trimethyl[(1-phenylprop-2-en-1-yl)oxy]silane is used as a silane coupling agent for improving the adhesion of organic materials to inorganic substrates in the production of adhesives and sealants. Its ability to bond these materials effectively contributes to the enhanced performance and durability of the final products.
Used in Coatings Industry:
In the coatings industry, trimethyl[(1-phenylprop-2-en-1-yl)oxy]silane serves as a silane coupling agent that boosts the adhesion of coatings to various surfaces, ensuring a strong bond and long-lasting protection. Its incorporation into coatings also contributes to improved water and UV resistance properties, making it suitable for applications where durability and resistance to environmental factors are crucial.
Used in Composite Materials:
Trimethyl[(1-phenylprop-2-en-1-yl)oxy]silane is used as a component in composite materials to improve their overall performance and durability. Its role as a silane coupling agent allows for better integration of different material components, leading to enhanced mechanical properties and resistance to various environmental stresses.
Used in Plastics and Rubber Industry:
Trimethyl[(1-phenylprop-2-en-1-yl)oxy]silane is utilized in the plastics and rubber industry as a silane coupling agent to improve the bonding between organic polymers and inorganic fillers. This results in enhanced mechanical properties, such as strength and flexibility, as well as improved resistance to wear and tear.
Used in Construction Materials:
In the construction materials industry, trimethyl[(1-phenylprop-2-en-1-yl)oxy]silane is employed as a silane coupling agent to improve the adhesion of construction materials to various surfaces, ensuring a strong and durable bond. Its use in this industry contributes to the creation of more robust and long-lasting construction materials that can withstand the test of time and environmental conditions.

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 100-52-7 benzaldehyde 
• 10519-96-7 potassium trimethylsilonate 
• 95932-32-4 tert-butyl (E)-cinnamyl carbonate 
• 593-60-2 Vinyl bromide 
• 123159-55-7 <2-(trimethylsilyl)ethyl>tris(2-methylphenyl)phosphonium iodide 

Downstream Products

• 1083-30-3 dihydrochalcone 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 112741-53-4 (3R,5S,6R)-4-(benzyloxycarbonyl)-5,6-diphenyl-3-(2'-oxo-2'-phenylethyl)-2,3,5,6-tetrahydro-4H-1,4-oxazin-2-one 
• 100516-57-2 (3S,5S,6R)-4-(benzyloxycarbonyl)-5,6-diphenyl-3-(2'-oxo-2'-phenylethyl)-2,3,5,6-tetrahydro-4H-1,4-oxazin-2-one 
• 66323-99-7 trimethyl[(Z)-(1-phenyl-1-propenyl)oxy]silane 
• 71268-59-2 (E)-1-phenyl-1-(trimethylsiloxy)propene 
• 57294-86-7 (E)-cinnamyl azide 
• 3412-44-0 (1E)-1,3-diphenylpropene 
• 62056-38-6 (E)-1-phenyl-3-p-tolylpropene 
• 18916-11-5 (E)-1-methyl-2-(3-phenyl-2-propen-1-yl)benzene 
• 20442-73-3 (1E)-3-(4-methoxyphenyl)-1-phenylpropene 
• 20442-73-3 (Z)-1-methoxy-4-(3-phenyl-2-propen-1-yl)benzene 
• 149045-39-6 1-methoxy-2-[(2E)-3-phenyl-2-propen-1-yl]benzene 
• 485844-19-7 1-fluoro-4-[(2E)-3-phenyl-2-propen-1-yl]benzene 

Relevant articles and documents

Iron-Catalyzed Grignard Cross-Couplings with Allylic Methyl Ethers or Allylic Trimethylsilyl Ethers

We have found that cross-coupling between aryl Grignard reagents and allylic methyl ethers proceeded well in the presence of a catalytic amounts of Fe(acac) 3 to afford the corresponding allylic substitution products in good yields. Under the same conditions, allylic trimethylsilyl ethers also reacted with Grignard reagents to give the corresponding cross-coupling products.

Iridium-catalyzed enantioselective synthesis of allylic alcohols: Silanolates as hydroxide equivalents

(Chemical Equation Presented) Masked hydroxide: A highly regio- and enantioselective Ir-catalyzed allylic etherification of acyclic, achiral allylic carbonates can be achieved by using potassium silanolates as nucleophiles. The use of these hydroxide equi

Wittig rearrangement of lithiated allyl aryl ethers: A mechanistic study

At -75°C, α-lithiated allyl phenyl ether undergoes mainly the [1,2] Wittig rearrangement to afford, after acidic hydrolysis, 1-phenyl-2-propen-1-ol as the main product. A second metalation taking place at one of the ortho positions is the sole competing s

Electrochemical regeneration of chromium(II). Alkenylation of carbonyl compounds

Electrochemical alkenylation of aldehydes using an Al sacrificial anode in the presence of Cr(II)/Ni(II) catalysts afforded the corresponding allyl alcohol derivatives in good to moderate yields.

Ni/Cr/Al multi-metal redox-mediated alkenylation of aldehydes

Alkenylation of aldehydes mediated by a catalytic amount of Cr(II)/Ni(0), using aluminium as an electron source, was performed to afford the corresponding allyl alcohol derivatives in good to moderate yields.

TRIS(2-METHYLPHENYL)PHOSPHORANE, A MODIFIED SEYFERTH-WITTIG REAGENT FOR THE STEREOSELECTIVE SYNTHESES OF Z-ALLYLTRIMETHYLSILANES

The Wittig reactions between title β-silylphosphorus ylide and aliphatic aldehydes give selectively Z-allyltrimethylsilanes with minimal formation of vinylation products.