25036-01-5

Basic information

• Product Name: POLYACENAPHTHYLENE
• Synonyms: ACENAPHTHYLENE RESIN;POLYACENAPHTHYLENE;acenaphthylene homopolymer
• CAS NO: 25036-01-5
• Molecular Formula: CH313CH(NH2)CO2H
• Molecular Weight: 152.2
• EINECS: 205-917-1
• Product Categories: Alphabetical Listings;Amino Acids;AStable Isotopes;Stable Isotopes;Hydrophobic Polymers;Styrenes;Substituted and Modified Styrenes;Hydrophobic Polymers;Materials Science;Polymer Science;Polymers;Substituted and Modified Styrenes
• Mol File: 25036-01-5.mol

Chemical Properties

• Melting Point: 291 °C (dec.)(lit.)
• Boiling Point: 298.9°C at 760 mmHg
• Flash Point: 137.2°C
• Appearance: Yellow/powder
• Density: 1.187g/cm³
• Vapor Pressure: 0.0022mmHg at 25°C
• Refractive Index: 1.731
• CAS DataBase Reference: POLYACENAPHTHYLENE(CAS DataBase Reference)
• NIST Chemistry Reference: POLYACENAPHTHYLENE(25036-01-5)
• EPA Substance Registry System: POLYACENAPHTHYLENE(25036-01-5)

Safety Data

• Hazard Codes: Xi:Irritant
• Statements: R36/37/38:
• Safety Statements: 24/25
• WGK Germany: 3
• Hazardous Substances Data: 25036-01-5(Hazardous Substances Data)

Usage

Chemical Properties

yellow powder

InChI:InChI=1/C12H8/c1-3-9-4-2-6-11-8-7-10(5-1)12(9)11/h1-8H

Upstream product

• 128-08-5 N-Bromosuccinimide 
• 127-08-2 potassium acetate 
• 83-32-9 acenaphthene 
• 64-19-7 acetic acid 
• 94-36-0 dibenzoyl peroxide 
• 13936-05-5 5-ethylacenaphthene 
• 14209-08-6 1,2-dibromoacenaphthene 
• 141-52-6 sodium ethanolate 
• 10047-18-4 5-acetylacenaphthene 
• 6306-07-6 1-acenaphthenol 
• 14620-98-5 acenaphthylene 
• 14966-36-0 1-acetoxyacenaphthene 
• 10183-87-6 1-(1,2,6,7,8,8a-hexahydro-acenaphthylen-5-yl)-ethanone 
• 25226-58-8 trans-1,2-dibromo-1,2-dihydroacenaphthylene 

Downstream Products

• 14973-11-6 1:2-Cyclopropanacenaphthen-3'-carbonsaeure 
• 13093-44-2 7,12-diphenyl-(6br,12ac)-6b,7,12,12a-tetrahydro-7ξ,12ξ-epoxido-benzo[k]fluoranthene 
• 16391-62-1 (7,12-diphenyl)benzofluoranthene 
• 58485-91-9 (6brH.10acH)-6b.7.10.10a-tetrahydro-fluoranthene 
• 110195-27-2 7-phenyl-6b,7,10,10a-tetrahydro-fluoranthene 
• 14209-08-6 1,2-dibromoacenaphthene 
• 214-63-1 Zethren 
• 65726-91-2 1-chloroacenaphthylene 
• 35468-33-8 trans-1,2-dichloroacenaphthene 
• 6840-31-9 naphthocyclopropane 
• 24648-02-0 9-phenyl-6b,9a-dihydro-acenaphtho[1,2-d]isoxazole 
• 19380-19-9 8-methyl-9c-phenyl-(6br,9ac)-6b,8,9,9a-tetrahydro-acenaphtho[1,2-d]isoxazole 
• 19380-20-2 8-phenyl-9ξ-propyl-(6br,9ac)-6b,8,9,9a-tetrahydro-acenaphtho[1,2-d]isoxazole 
• 54080-26-1 9-(2,4,6-trimethyl-phenyl)-(6br,9ac)-6b,9a-dihydro-acenaphtho[1,2-d]isoxazole 

Relevant articles and documents

Direct Evidence on the Mechanism of Methane Conversion under Non-oxidative Conditions over Iron-modified Silica: The Role of Propargyl Radicals Unveiled

Radical-mediated gas-phase reactions play an important role in the conversion of methane under non-oxidative conditions into olefins and aromatics over iron-modified silica catalysts. Herein, we use operando photoelectron photoion coincidence spectroscopy to disentangle the elusive C2+ radical intermediates participating in the complex gas-phase reaction network. Our experiments pinpoint different C2-C5 radical species that allow for a stepwise growth of the hydrocarbon chains. Propargyl radicals (H2C?C≡C?H) are identified as essential precursors for the formation of aromatics, which then contribute to the formation of heavier hydrocarbon products via hydrogen abstraction–acetylene addition routes (HACA mechanism). These results provide comprehensive mechanistic insights that are relevant for the development of methane valorization processes.

Mechanisms of Heptane Degradation and Product Formation in Microwave Discharge

Abstract: A mechanism for the degradation of n-heptane and the formation of the products of its plasma-chemical transformation by microwave discharge treatment has been proposed. Chemical reactions resulting in reactive species, namely free radicals that form lower hydrocarbons and polyaromatic structures are presented. The product composition of the gas, liquid, and solid phases has been studied using gas chromatography–mass spectrometry analysis of the precipitate obtained by evaporation of the liquid phase after the treatment of n-heptane.

2,3-Dihydro-1H-naphtho[1,8-cd]borinine as a Potent Precursor for Open-Shell Singlet B-Heterocycles

The reaction of naphthalene-1,8-diylbis[(trimethylsilyl)methanide] and dimethyl arylboronates afforded the corresponding 2,3-dihydro-1H-naphtho[1,8-cd]borinine as single diastereomers. Single-electron oxidation of the boron-containing heterocycles provided acenaphthylene through the generation boron-containing cyclic singlet biradicals.

RECORDING MATERIAL AND OPTICAL INFORMATION RECORDING MEDIUM

A recording material includes a dye-bonded polymer compound which contains a polymer compound to which a one-photon absorption dye is bonded, and a glass transition temperature of the recording material is higher than 200° C. An optical information recording medium includes a recording layer and an intermediate layer adjacent to the recording layer, and the recording layer contains the above-described recording material.

Synthesis of novel fluoranthene-based conformationally constrained α-amino acid derivatives and polycyclic aromatics via the diels-alder reaction

Conformationally constrained cyclic α-amino acid moieties have been fused to the fluoranthene system. Aminoindanecarboxylic acid (Aic) and 1,2,3,4-tetrahydroisoquinolinecarboxylic acid (Tic) derivatives were synthesized by an alkylation sequence, whereas a aminotetralincarboxylic acid (Atc) derivative was assembled using the Diels-Alder reaction as a key step. These α-amino acid derivatives are considered as constrained analogues of phenylalanine (Phe) and play an important role in the design and synthesis of bioactive peptides and some fluorescence chemosensor molecules. Moreover, this strategy has been extended to polycyclic aromatics via the Diels-Alder reaction and subsequent aromatization with DDQ. Georg Thieme Verlag Stuttgart New York.

Probing mechanisms of aryl-aryl bond cleavages under flash vacuum pyrolysis conditions

Several biaryls have been subjected to flash vacuum pyrolysis (FVP) at 1100°C and 0.8-0.9hPa. Product compositions are reported for the FVP of 9-phenylanthracene (1), 2-bromobiphenyl (5), biphenyl (8), 1,10- diphenylanthracene (12), 9-(2-naphthyl)anthracene (17), and 9,9′- bianthracenyl (20). The experimental results have been used to evaluate four possible mechanistic pathways for the cleavage of aryl-aryl bonds under these conditions: (1) the 'explosion' of substituted phenyl radicals; (2) hydrogen atom attachment to an ipso-carbon atom of the biaryl followed by C-C bond cleavage; (3) direct homolysis; and (4) loss of a fragment as an aryne. None of these mechanisms by itself successfully accommodates all of the experimental facts. The data suggest that aryl-aryl bond cleavages under FVP conditions involve at least two different mechanistic pathways and that the relative contributions of the competing pathways probably vary from one biaryl to the next.

Organocatalytic oxidative dehydrogenation of dihydroarenes by dioxygen using 2,3-dichloro-5,6-dicyano-benzoquinone (DDQ) and NaNO2

The oxidative dehydrogenation of dihydroarenes catalyzed by 2,3-dichloro-5,6-dicyano-benzoquinone(DDQ) and NaNO2 with dioxygen is reported. The combination of DDQ and NaNO2 showed high efficiency and high selectivity, compared with other benzoquinones and anthraquinones, e.g., >99% conversion of 9,10-dihydroanthracene with 99% selectivity for anthracene can be obtained at 120 °C under 1.3 MPa O2 for 8 h. Excellent results were achieved in the oxidative dehydrogenation of variety of dihydroarenes.

Zirconium tetrachloride catalysed synthesis of symmetric and unsymmetric ethers from secondary benzylic alcohols

Secondary benzylic alcohols are coupled in the presence of zirconium tetrachloride to afford the corresponding symmetrical ethers in good yields. Unsymmetric ethers are obtained with good selectivity by condensation of two different secondary benzylic alcohols under the action of the same catalyst.

Role of temperature and hydrochloric acid on the formation of chlorinated hydrocarbons and polycyclic aromatic hydrocarbons during combustion of paraffin powder, polymers, and newspaper

Formation of chlorinated hydrocarbons and polycyclic aromatic hydrocarbons (PAHs) were determined using a laboratory-scale incinerator when combusting materials at different temperatures, different concentrations of hydrochloric acid (HCl), and when combusting various types of polymers/newspaper. Polychlorobenzenes (PCBz), polychlorophenols (PCPhs), polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs) and their toxic equivalency (TEQ) and PAHs were highlighted and reported. Our results imply maximum formation of chlorinated hydrocarbons at 400°C in the following order; PCBz≥PCPhs?PCDFs>PCDDs>TEQ on a parts-per-billion level. Similarly, a maximum concentration of chlorinated hydrocarbons was noticed with an HCl concentration at 1000 ppm with the presence of paraffin powder in the following order; PAHs>PCBz≥PCPhs?PCDFs>PCDDs>TEQ an a parts-per-billion level. PAHs were not measured at different temperatures. Elevated PAHs were noticed with different HCl concentrations and paraffin powder combustion (range: 27-32 μg/g). While, different polymers and newspaper combusted, nylon and acrylonitrile butadiene styrene (ABS) produced the maximum hydrogen cyanide (HCN) concentration, concentrations of PCDD/FS, dioxin-like polychlorinated biphenyls (DL-PCBs), and TEQ were in a decreasing order: polyvinylchloride (PVC)newspaperpolyethyleneterephthalate (PET) polyethylene (PE) polypropylene (PP) ABS = blank. Precursors of PCBs were in a decreasing order: PPnylonPEnewspaperABSPVCblankPET. Precursors of PCDD/Fs were in a decreasing order: newspaper PP= nylonPEABSPVC= blankPET. BTX formation was in a decreasing order; PEnylonnewspaperABSPP. PAHs formation were elevated with parts-per-million levels in the decreasing order of PPnylonPE newspaperblankABS PETPVC.

Emission factors and importance of PCDD/Fs, PCBs, PCNs, PAHs and PM 10 from the domestic burning of coal and wood in the U.K.

This paper presents emission factors (EFs) derived for a range of persistent organic pollutants (POPs) when coal and wood were subject to controlled burning experiments, designed to simulate domestic burning for space heating. A wide range of POPs were emitted, with emissions from coal being higher than those from wood. Highest EFs were obtained for particulate matter, PM10, (～ 10 g/kg fuel) and polycyclic aromatic hydrocarbons (～ 100 mg/ kg fuel for ΣPAHs). For chlorinated compounds, EFs were highest for polychlorinated biphenyls (PCBs), with polychlorinated naphthalenes (PCNs), dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) being less abundant. EFs were on the order of 1000 ng/kg fuel for ΣPCBs, 100s ng/ kg fuel for ΣPCNs and 100 ng/kg fuel for ΣPCDD/Fs. The study confirmed that mono- to trichlorinated dibenzofurans, Cl1,2,3DFs, were strong indicators of low temperature combustion processes, such as the domestic burning of coal and wood. It is concluded that numerous PCB and PCN congeners are routinely formed during the combustion of solid fuels. However, their combined emissions from the domestic burning of coal and wood would contribute only a few percent to annual U.K. emission estimates. Emissions of PAHs and PM 10 were major contributors to U.K. national emission inventories. Major emissions were found from the domestic burning for Cl1,2,3DFs, while the contribution of PCDD/F-ΣTEQ to total U.K. emissions was minor.