14966-36-0

Basic information

• Product Name: 1-ACETOXYACENAPHTHENE
• Synonyms: 1-acetoxyacenaphthene,tech.,95%;1,2-DIHYDROACENAPHTHYLEN-1-YL ACETATE;1-ACETOXYACENAPHTHENE;1-acenaphthenyl acetate;1-acetoxyacenaphthene, tech.;1,2-Dihydro-1-acenaphthylenol acetate
• CAS NO: 14966-36-0
• Molecular Formula: C₁₄H₁₂O₂
• Molecular Weight: 212.24
• Mol File: 14966-36-0.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 166-168°C 5mm
• Flash Point: 166-168°C/5mm
• Appearance: /
• Density: 1.21 g/cm³
• Vapor Pressure: 3.22E-05mmHg at 25°C
• Refractive Index: 1.636
• CAS DataBase Reference: 1-ACETOXYACENAPHTHENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ACETOXYACENAPHTHENE(14966-36-0)
• EPA Substance Registry System: 1-ACETOXYACENAPHTHENE(14966-36-0)

Safety Data

• Safety Statements: 23-24/25
• Hazardous Substances Data: 14966-36-0(Hazardous Substances Data)

Usage

General Description

1-Acetoxyacenaphthene, also known as 1-Acetoxyacena-9H-fluoren-9-one, is a synthetic organic chemical compound with the molecular formula C20H14O2. It is a derivative of acenaphthene, which is a polycyclic aromatic hydrocarbon. 1-Acetoxyacenaphthene is commonly used in organic synthesis and as a precursor for the preparation of various pharmaceuticals and agrochemicals. Its chemical structure includes an acetoxy group, which is a functional group composed of a methyl group bound to an oxygen atom attached to a carbon atom of an acetyl group. 1-ACETOXYACENAPHTHENE is flammable and poses potential risks to human health and the environment, so it should be handled and stored with care and in accordance with safety regulations and guidelines.

InChI:InChI=1/C14H12O2/c1-9(15)16-13-8-11-6-2-4-10-5-3-7-12(13)14(10)11/h2-7,13H,8H2,1H3/t13-/m0/s1

Upstream product

• 108-21-4 Isopropyl acetate 
• 6306-07-6 1-acenaphthenol 
• 108-05-4 vinyl acetate 
• 108-24-7 acetic anhydride 
• 2235-15-6 1(2H)-acenaphthylenone 
• 83-32-9 acenaphthene 
• 141-78-6 ethyl acetate 
• 6361-21-3 2-chloro-5-nitrobenzaldehyde 
• 2112-99-4 3-amino-4H-naphtho<1,8-de>triazine 
• 64-19-7 acetic acid 
• 876-27-7 4-chlorophenyl acetate 
• 108-22-5 Isopropenyl acetate 

Downstream Products

• 6306-07-6 1-acenaphthenol 
• 208-96-8 acenaphthylene 
• 6306-07-6 (R)-1,2-dihydroacenaphthylen-1-ol 
• 2235-15-6 1(2H)-acenaphthylenone 
• 856351-15-0 1-(2-chloro-phenyl)-acenaphthen-1-ol 
• 786722-11-0 1-(2-chloro-phenyl)-acenaphthene 
• 855883-54-4 1-(2-chloro-phenyl)-acenaphthylene 
• 58485-91-9 (6brH.10acH)-6b.7.10.10a-tetrahydro-fluoranthene 
• 20485-57-8 8-methyl-fluoranthene 

Relevant articles and documents

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Selective acetylation of primary alcohols by ethyl acetate

A KOtBu and ethyl acetate mediated efficient methodology has been developed for the acetylation of primary and secondary alcohols where ethyl acetate is the source of acetyl group. The reaction is fast, mild, efficient, and highly selective towards the primary alcohols.

Green methodology for enzymatic hydrolysis of acetates in non-aqueous media via carbonate salts

Herein we report a new approach to enantiomerically enriched acetates using a lipase-catalyzed hydrolysis in non-aqueous media by alkaline carbonate salts. The use of sodium carbonate in the enzymatic hydrolysis with Candida antarctica lipase B (CAL-B) of racemic acetates shows a large enhancement of the reactivity and selectivity of this lipase. The role of the carbonate salts, the amount and the nature of the alkaline earth metal on the efficiency of this new pathway are investigated. The enzymatic kinetic resolution of acetates 1a-9a, by enzymatic-carbonate hydrolysis under mild conditions is described. In all cases, the resulting alcohols and remaining acetates were obtained in high ee values (up to >99%) while the selectivities reached E >500.