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Morpholine, 4-[(1E)-2-phenylethenyl]- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 39166-25-1 Structure
  • Basic information

    1. Product Name: Morpholine, 4-[(1E)-2-phenylethenyl]-
    2. Synonyms:
    3. CAS NO:39166-25-1
    4. Molecular Formula: C12H15NO
    5. Molecular Weight: 189.257
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 39166-25-1.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Morpholine, 4-[(1E)-2-phenylethenyl]-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Morpholine, 4-[(1E)-2-phenylethenyl]-(39166-25-1)
    11. EPA Substance Registry System: Morpholine, 4-[(1E)-2-phenylethenyl]-(39166-25-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 39166-25-1(Hazardous Substances Data)

39166-25-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 39166-25-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,9,1,6 and 6 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 39166-25:
(7*3)+(6*9)+(5*1)+(4*6)+(3*6)+(2*2)+(1*5)=131
131 % 10 = 1
So 39166-25-1 is a valid CAS Registry Number.

39166-25-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-(2-phenylethenyl)-morpholine

1.2 Other means of identification

Product number -
Other names (E)-β-(N-morpholino)styrene

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:39166-25-1 SDS

39166-25-1Relevant articles and documents

Hydrogen-Bond-Promoted Metal-Free Hydroamination of Alkynes

Bahri, Janet,Monnier, Florian,Ollevier, Thierry,Taillefer, Marc,Tanbouza, Nour

supporting information, p. 2086 - 2090 (2019/11/05)

An original metal-free regio- A nd stereoselective intermolecular hydroamination of alkynes is described. Various (E)-enamines were obtained from arylacetylenes and aliphatic secondary amines in the presence of ethylene glycol as a solvent. The latter is

Regio- and Enantioselective Formal Hydroamination of Enamines for the Synthesis of 1,2-Diamines

Yu, Lu,Somfai, Peter

supporting information, p. 8551 - 8555 (2019/05/21)

The asymmetric formal hydroamination of enamines using a CuH catalyst is reported. The method provides a straightforward and efficient approach to the synthesis of chiral 1,2-dialkyl amines in good yields with high levels of enantioselectivities for a broad range of substrates, and should have significant value for the preparation of molecules bearing a 1,2-diamine motif.

The pyrrole ring η2-hapticity bridged binuclear tricarbonyl Mo(0) and W(0) complexes: catalysis of regioselective hydroamination reactions and DFT calculations

Jha, Vikesh Kumar,Mani, Ganesan,Davuluri, Yogeswara Rao,Anoop, Anakuthil

supporting information, p. 1840 - 1847 (2017/02/23)

Following the report of the ferrocene structure, metal complexes containing the heteroatom-substituted cyclopentadienyl (Cp) analogue, that is the η5 pyrrolyl ligand, have been reported. While the Cp ligand continues to be a favorite ligand in

Dynamic Covalent Chemistry of Aldehyde Enamines: BiIII- and ScIII-Catalysis of Amine–Enamine Exchange

Zhang, Yang,Xie, Sheng,Yan, Mingdi,Ramstr?m, Olof

supporting information, p. 11908 - 11912 (2017/09/07)

The dynamic exchange of enamines from secondary amines and enolizable aldehydes has been demonstrated in organic solvents. The enamine exchange with amines was efficiently catalyzed by Bi(OTf)3 and Sc(OTf)3 (2 mol %) and the equilibria (60 mm) could be attained within hours at room temperature. The formed dynamic covalent systems displayed high stabilities in basic environment with 2 % by-product formation within one week after complete equilibration. This study expands the scope of dynamic C?N bonds from imine chemistry to enamines, enabling further dynamic methodologies in exploration of this important class of structures in systems chemistry.

An Efficient One–pot Procedure for the Direct Preparation of 4,5-Dihydroisoxazoles from Amides

Slagbrand, Tove,Kervefors, Gabriella,Tinnis, Fredrik,Adolfsson, Hans

, p. 1990 - 1995 (2017/06/09)

A Mo(CO)6 (molybdenumhexacarbonyl) catalyzed reductive functionalization of amides to afford 5-amino substituted 4,5-dihydroisoxazoles is presented. The reduction of amides generates reactive enamines, which upon the addition of hydroximinoyl chlorides and base undergoes a 1,3-dipolar cycloaddition reaction that gives access to the desired heterocyclic compounds. The transformation of amides is highly chemoselective and tolerates functional groups such as nitro, nitriles, esters, and ketones. Furthermore, a versatile scope of 4,5-dihydroisoxazoles derived from a variety of hydroximinoyl chlorides and amides is demonstrated. (Figure presented.).

Facile preparation of pyrimidinediones and thioacrylamides: Via reductive functionalization of amides

Trillo, Paz,Slagbrand, Tove,Tinnis, Fredrik,Adolfsson, Hans

, p. 9159 - 9162 (2017/08/17)

The development of an efficient protocol for the reductive functionalization of amides into pyrimidinediones and amino-substituted thioacrylamides is presented. Enamines are generated in a highly chemoselective amide hydrosilylation reaction catalyzed by

1,3-Dipolar cycloaddition reactivities of perfluorinated aryl azides with enamines and strained dipolarophiles

Xie, Sheng,Lopez, Steven A.,Ramstr?m, Olof,Yan, Mingdi,Houk

supporting information, p. 2958 - 2966 (2015/03/18)

The reactivities of enamines and predistorted (strained) dipolarophiles toward perfluoroaryl azides (PFAAs) were explored experimentally and computationally. Kinetic analyses indicate that PFAAs undergo (3 + 2) cycloadditions with enamines up to 4 orders of magnitude faster than phenyl azide reacts with these dipolarophiles. DFT calculations were used to identify the origin of this rate acceleration. Orbital interactions between the cycloaddends are larger due to the relatively low-lying LUMO of PFAAs. The triazolines resulting from PFAA-enamine cycloadditions rearrange to amidines at room temperature, while (3 + 2) cycloadditions of enamines and phenyl azide yield stable, isolable triazolines. The 1,3-dipolar cycloadditions of norbornene and DIBAC also show increased reactivity toward PFAAs over phenyl azide but are slower than enamine-azide cycloadditions.

Efficient and selective synthesis of e-vinylamines via tungsten(0)-catalyzed hydroamination of terminal alkynes

Kocicka, Paulina,Czelusniak, Izabela,Szymaska-Buzar, Teresa

supporting information, p. 3319 - 3324 (2015/01/09)

The hydroamination of terminal alkynes (RC≡CH=phenylacetylene, 4-methylphenylacetylene, 4-fluorophenylacetylene, 1-hexyne, methyl 2-propynyl ether, prop-2-yn-1-ol) with secondary amines (piperidine, pyrrolidine, morpholine, piperazine, methylpiperazine, 4

Catalytic reductive dehydration of tertiary amides to enamines under hydrosilylation conditions

Volkov, Alexey,Tinnis, Fredrik,Adolfsson, Hans

supporting information, p. 680 - 683 (2014/03/21)

Tertiary amides are efficiently reduced to their corresponding enamines under hydrosilylation conditions, using a transition-metal-free catalytic protocol based on t-BuOK (5 mol %) and (MeO)3SiH or (EtO) 3SiH as the reducing agent. The enamines were formed with high selectivity in good-to-excellent yields.

Inverse electron demand hetero-Diels-Alder reaction in preparing 1,4-benzodioxin from o-quinone and enamine

Zhang, Jinsong,Taylor, Chris,Bowman, Erich,Savage-Low, Leo,Lodewyk, Michael W.,Hanne, Larry,Wu, Guang

supporting information, p. 6298 - 6302 (2013/11/06)

A process for synthesizing 1,4-benzodioxin, through oxidation of a phenol to an o-quinone followed by treatment with an enamine, has been developed. Adduct stereochemistry is found to be retained via this one-pot reaction. The method uses hypervalent iodine reagent under mild conditions and is compatible with a wide scope of phenols and enamines.

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