100-40-3

Basic information

• Product Name: 4-Vinyl-1-cyclohexene
• Synonyms: 4-ethenyl-Cyclohexene;4-vinyl-1-cyclohexen;4-vinyl-cyclohexen;Butadiene dimer;butadienedimer;Cyclohexene, 4-vinyl-;cyclohexene,4-ethenyl-;Cyclohexenylethylene
• CAS NO: 100-40-3
• Molecular Formula: C₈H₁₂
• Molecular Weight: 108.18
• EINECS: 202-848-9
• Product Categories: Industrial/Fine Chemicals;Monomers;Polymer Science;Vinyl Halides, Amines, Amides, and Other Vinyl Monomers;Alpha Sort;Alphabetic;Chemical Class;Hydrocarbons;NeatsGasoline, Diesel,&Petroleum;OlefinsVolatiles/ Semivolatiles;Substance classes;T-ZAnalytical Standards;V
• Mol File: 100-40-3.mol

Chemical Properties

• Melting Point: -101 °C
• Boiling Point: 126-127 °C(lit.)
• Flash Point: 68 °F
• Appearance: Off-white to beige-brownish/Powder
• Density: 0.832 g/mL at 25 °C(lit.)
• Vapor Density: 3.76 (vs air)
• Vapor Pressure: 10.2 mm Hg ( 25 °C)
• Refractive Index: n20/D 1.463(lit.)
• Storage Temp.: 2-8°C
• Water Solubility: 50mg/L(25 oC)
• BRN: 1901553
• CAS DataBase Reference: 4-Vinyl-1-cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Vinyl-1-cyclohexene(100-40-3)
• EPA Substance Registry System: 4-Vinyl-1-cyclohexene(100-40-3)

Safety Data

• Hazard Codes: F,Xn
• Statements: 11-38-40-65-62-52/53
• Safety Statements: 16-33-36/37-62
• RIDADR: UN 1993 3/PG 2
• WGK Germany: 2
• RTECS: GW6650000
• F: 10-23
• HazardClass: 3.1
• PackingGroup: II
• Hazardous Substances Data: 100-40-3(Hazardous Substances Data)

Usage

Uses

Used in Polymer Production:
4-Vinyl-1-cyclohexene is used as a monomer in the production of polymers such as polyethylene and polystyrene. Its ability to undergo polymerization reactions contributes to the formation of these versatile materials, which are widely used in the manufacturing of plastic products.
Used in Chemical Synthesis:
4-Vinyl-1-cyclohexene is also utilized in the synthesis of other chemicals, showcasing its role as an intermediate in various chemical processes. Its reactivity and functional groups make it a valuable component in the creation of a range of chemical products.
Used in Flavoring and Fragrance Industry:
4-Vinyl-1-cyclohexene is employed as a flavoring and fragrance agent in the food and beverage industry. Its distinctive aromatic properties allow it to enhance the sensory experience of various consumable products, adding to their appeal.
Used in Manufacturing of Adhesives, Coatings, and Inks:
4-Vinyl-1-cyclohexene is also used in the production of adhesives, coatings, and inks, where its chemical properties contribute to the performance and quality of these materials. Its presence in these products helps to improve their adhesive, protective, and decorative capabilities.
Safety Precautions:
Due to its potential to cause irritation to the skin, eyes, and respiratory tract, it is crucial to handle 4-Vinyl-1-cyclohexene with proper safety measures. Workers should be trained in the safe handling and use of this chemical to minimize exposure and associated health risks.

InChI:InChI=1/C8H12/c1-2-8-6-4-3-5-7-8/h2-4,8H,1,5-7H2/t8-/m1/s1

Upstream product

• 1708-29-8 2,5-dihydrofuran 
• 106-99-0 buta-1,3-diene 
• 1552-12-1 1,5-cis,cis-cyclooctadiene 
• 74454-29-8 1-phenylethyl acetate 
• 110-89-4 piperidine 
• 2494-10-2 1-piperidinomethanol 
• 100-69-6 2-vinylpyridine 
• 3975-85-7 3,5,5-Trimethylpyrazolin 
• 3104-91-4 9-Nortwistbrendan 
• 96-10-6 diethylaluminium chloride 
• 7550-45-0 titanium tetrachloride 
• 71-43-2 benzene 
• 109-89-7 diethylamine 
• 14296-80-1 1,2-dimethylenecyclobutane 

Downstream Products

• 17864-93-6 dichloro-(2-cyclohex-3-enyl-ethyl)-methyl-silane 
• 106-86-5 1,2-Epoxy-4-vinylcyclohexane 
• 5089-25-8 chloro-(2-cyclohex-3-enyl-ethyl)-dimethyl-silane 
• 17985-25-0 ethyl-dichloro-(2-cyclohex-3-enyl-ethyl)-silane 
• 6337-45-7 thioacetic acid S-(2-cyclohex-3-enyl-ethyl ester) 
• 106-87-6 4-vinylcyclohexene dioxide 
• 1678-91-7 ethyl-cyclohexane 
• 100-41-4 ethylbenzene 
• 3742-42-5 4-ethylcyclohexene 
• 18240-10-3 (+/-)-2-(3-cyclohexenyl)ethanol 
• 1123-84-8 2,5-dichlorostyrene 
• 857827-93-1 1-(1-hydroxy-ethyl)-cyclohexane-1,2,3-triol 
• 31646-64-7 (+/-)-1ξ-vinyl-cyclohexanediol-(3r.4t) 
• 51962-63-1 4-(1,2-dichloroethyl)-1,2-dichlorocyclohexane 

Related news

Kinetic study of dichlorocyclopropanation of 4-Vinyl-1-cyclohexene (cas 100-40-3) by a novel multisite phase transfer catalyst07/20/2019

In this work, the dichlorocyclopropanation of 4-vinyl-1-cyclohexene catalyzed by a new novel phase transfer catalyst was carried out in an alkaline solution/chloroform two-phase medium. This new synthesized phase transfer catalyst, 1,4-bis(triethylmethylammonium)benzene dichloride (DC-X), which ...detailed

Greener and efficient epoxidation of 4-Vinyl-1-cyclohexene (cas 100-40-3) with polystyrene 2-(aminomethyl)pyridine supported Mo(VI) catalyst in batch and continuous reactors07/21/2019

Polystyrene 2-(aminomethyl)pyridine supported Mo(VI) complex, i.e. Ps.AMP.Mo catalyst has been successfully prepared and characterised. The catalytic performance of the Ps.AMP.Mo catalyst in epoxidation of 4-vinyl-1-cyclohexene (4-VCH) with tert-butyl hydroperoxide (TBHP) as an oxidant has been ...detailed

Relevant articles and documents

Catalysis of Diels-Alder Reactions by Zeolites

The Diels-Alder cyclodimerization of buta-1,3-diene to 4-vinylcyclohexene was found to be catalysed by non-acidic zeolites, especially large-pore zeolites such as Na-ZSM-20, Na-β, and Na-Y, and also by carbon molecular sieves.

Dehydrogenative Vacuum Pyrolysis: a Novel Synthetic Technique. Conversion of Cyclo-octa-1,5-diene into Styrene and Related Reactions

Vacuum pyrolysis in the presence of palladium on charcoal of the 3,3-dioxide (1) of 3-thiabicyclo-heptane-6,7-dicarboxylic anhydride gave, without undesirable disproportionation, phthalic anhydride, also obtained from cis-2,3-divinylsuccinic anhydride (2) and cis-1,2,3,6-tetrahydrophthalic anhydride (5), while cyclo-octa-1,5-diene (7) and the disulphone (6) each gave styrene.

Precursor effect on the property and catalytic behavior of Fe-TS-1 in butadiene epoxidation

The effect of iron precursor on the property and catalytic behavior of iron modified titanium silicalite molecular sieve (Fe-TS-1) catalysts in butadiene selective epoxidation has been studied. Three Fe-TS-1 catalysts were prepared, using iron nitrate, iron chloride and iron sulfate as precursors, which played an important role in adjusting the textural properties and chemical states of TS-1. Of the prepared Fe-TS-1 catalysts, those modified by iron nitrate (FN-TS-1) exhibited a significant enhanced performance in butadiene selective epoxidation compared to those derived from iron sulfate (FS-TS-1) or iron chloride (FC-TS-1) precursors. To obtain a deep understanding of their structure-performance relationship, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Temperature programmed desorption of NH3 (NH3-TPD), Diffuse reflectance UV–Vis spectra (DR UV–Vis), Fourier transformed infrared spectra (FT-IR) and thermal gravimetric analysis (TGA) were conducted to characterize Fe-TS-1 catalysts. Experimental results indicated that textural structures and acid sites of modified catalysts as well as the type of Fe species influenced by the precursors were all responsible for the activity and product distribution.

Nickel(0) and palladium(0) complexes with 1,3,5-triaza-7-phosphaadamantane. Catalysis of buta-1,3-diene oligomerization or telomerization in an aqueous biphasic system

New homoleptic nickel(0) and palladium(0) complexes with a water-soluble ligand, 1,3,5-triaza-7-phosphaadamantane, were prepared and characterized by 1H, 13C, and 31P NMR spectra. The complexes, together with the known ana

The positive role of cadmium in TS-1 catalyst for butadiene epoxidation

A series of Cd modified titanium silicalite 1 catalysts with different Cd content (xCd-TS-1, x = 1-15) were successfully prepared by ultrasound impregnation. Epoxidation of butadiene over these catalysts were investigated using hydrogen peroxide as oxidant, which indicated that Cd greatly improve the catalytic performance of TS-1 and the selectivity of epoxide. Various characterization methods including quantum chemical calculation were employed to explore the specific roles of Cd in promoting TS-1 catalytic activity. Theoretical calculation consistently suggested TiO bond were weakened owing to the introduction of Cd, which resulted in the structure of Cd-TS-1 becoming more relaxant. As a consequence, it is favorable to methanol solvent and H 2O2 interacting with the Ti active site to form five-member transition state during reaction. It was observed that catalysts modified with 1-5 wt% Cd presented both high catalytic activity and good reusability. The highest yield of 0.63 mol/L of vinyloxirane (VO) was obtained, while turnover number (TON, determined as the molar VO obtained per molar Ti atom) could reach to 1466.

Chelating Diphosphite Complexes of Nickel(0) and Platinum(0): Their Remarkable Stability and Hydrocyanation Activity

The synthesis, stability and hydrocyanation catalytic activity of nickel(0) complexes af the diphosphite 1 derived from 2,2'-biphenol are described; the X-ray crystal structures of the legand 1 and its platinum(0) complexes 2b are reported.

Synthesis of p-(Cyclohexene-3-yl-ethyl)phenol and Characteristics of its Phosphatization with Phosphorous Trichloride

Cycloalkenylation of phenol with 4-vinylcyclohexene was studied in the presence of zeolite-Y catalyst, saturated by orthophosphoric acid on the batch unit. Phenol and 4-vinylcyclohexene were used as initial products for the realization of cycloalkenylatio

Polyethylene-entrapped Nickel(0) Diene Cyclo-oligomerization Catalysts

The use of precipitates of polyethylene as a matrix quantitatively to entrap and recover selective homogeneous Ni(0) diene cyclo-oligomerization catalysts complexed by ligands composed of ethylene oligomers containing dialkylphosphito and diarylphosphito

Epoxidation of butadiene over nickel modified TS-1 catalyst

Nickel modified Titanium silicalite 1 (TS-1) catalysts provided an environmentally benign and effective method for butadiene epoxidation. Certain loading of modified Ni in our system significantly promoted TS-1 catalytic activity. The product vinyloxirane

Small Rings. Part 32. The Gas Phase Kinetics, Mechanism, and Energy Hypersurface for the Thermolyses of syn- and anti-Tricyclo2,5>-octane

The title reactions have been studied at low pressure (1-10 Torr) and in the temperature ranges 390-419 2,5/octane(syn-TCO)> and 412-445 K (anti-TCO).The major products from both compounds were cis,cis and cis,trans-cyclo-o