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Cas Database

101-13-3

101-13-3

Identification

Synonyms:Aniline,3,3'-azoxydi- (8CI); Benzenamine, 3,3'-azoxybis- (9CI); 3,3'-Azoxydianiline;3,3'-Diaminoazoxybenzene; NSC 7131; m,m'-Azoxybisaniline

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Safety information and MSDS view more

  • Signal Word:no data available

  • Hazard Statement:no data available

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

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Relevant articles and documentsAll total 3 Articles be found

-

Busch,Schulz

, p. 1465 (1929)

-

Palladium Nanoparticles on Silica Nanospheres for Switchable Reductive Coupling of Nitroarenes

Lakshminarayana, Bhairi,Manna, Arun Kumar,Satyanarayana,Subrahmanyam, Ch.

, p. 2309 - 2321 (2020/02/18)

Abstract: In this study, we synthesized a robust and sustainable Pd/SiO2 nanospheres catalyst. Further, its catalytic activity was demonstrated for the direct reductive coupling of nitroarenes under mild conditions. While the reaction with Pd nanoparticles on other supporting materials such as modified carbon materials and TiO2, under similar conditions, resulted formation of amines exclusively. Therefore, it was confirmed that the SiO2 was found to be the best supporting material towards the selective reductive coupling of nitroarenes. Also, the catalyst could be recycled up to five cycles with a marginal loss of product yield ( 2% yield). Graphic Abstract: [Figure not available: see fulltext.].

Process route upstream and downstream products

Process route

3-nitro-aniline
99-09-2

3-nitro-aniline

3,3'-diaminoazobenzene

3,3'-diaminoazobenzene

3,3'-diaminoazoxybenzene
101-13-3

3,3'-diaminoazoxybenzene

Conditions
Conditions Yield
With hydrazine hydrate; Pd/C; In ethanol; water; at 80 ℃; for 10h; chemoselective reaction;
90.6 %Chromat.
3-nitro-aniline
99-09-2

3-nitro-aniline

3,3'-diaminoazoxybenzene
101-13-3

3,3'-diaminoazoxybenzene

Conditions
Conditions Yield
3-nitro-aniline
99-09-2

3-nitro-aniline

3,3'-diaminoazoxybenzene
101-13-3

3,3'-diaminoazoxybenzene

Conditions
Conditions Yield
With potassium hydroxide; In methanol; toluene; for 0.5h; Heating;
70%
With sodium tetrahydroborate; Pd/SiO2; In ethanol; at 20 ℃;
20%
With potassium hydroxide; Lindlar's catalyst; hydrazine;
With sodium hydroxide; water; zinc; man laugt den Niederschlag mit siedendem Alkohol aus;
With sodium amalgam; ethanol;
With acetic acid; zinc; man laesst das entstandene Hydroxyl-amino-anilin mit Natronlauge laengere Zeit stehen;
With potassium hydroxide; Lindlar's catalyst; hydrazine;
With sodium acetate; Reduktion an einer Nickel-Kathode;
With alkaline aqueous sodium arsenite;
D-glucose
50-99-7

D-glucose

3-nitro-aniline
99-09-2

3-nitro-aniline

3,3'-diaminoazoxybenzene
101-13-3

3,3'-diaminoazoxybenzene

Conditions
Conditions Yield
With sodium hydroxide;
3-nitro-aniline
99-09-2

3-nitro-aniline

3,3'-diaminoazobenzene
21371-44-8,140661-36-5

3,3'-diaminoazobenzene

3,3'-diaminoazoxybenzene
101-13-3

3,3'-diaminoazoxybenzene

Conditions
Conditions Yield
With alkaline tin oxide; water;
With alkaline tin oxide;
3,3'-dinitro azoxybenzene
1230-85-9,71298-01-6

3,3'-dinitro azoxybenzene

3,3'-diaminoazoxybenzene
101-13-3

3,3'-diaminoazoxybenzene

Conditions
Conditions Yield
With diethyl ether; platinum; Hydrogenation;
meta-dinitrobenzene
99-65-0

meta-dinitrobenzene

triethanolamine
102-71-6,64114-46-1

triethanolamine

3,3'-diaminoazobenzene
21371-44-8,140661-36-5

3,3'-diaminoazobenzene

3,3'-diaminoazoxybenzene
101-13-3

3,3'-diaminoazoxybenzene

Conditions
Conditions Yield
meta-dinitrobenzene
99-65-0

meta-dinitrobenzene

2,2'-iminobis[ethanol]
111-42-2

2,2'-iminobis[ethanol]

3,3'-diaminoazobenzene
21371-44-8,140661-36-5

3,3'-diaminoazobenzene

3,3'-diaminoazoxybenzene
101-13-3

3,3'-diaminoazoxybenzene

Conditions
Conditions Yield
3-nitro-aniline
99-09-2

3-nitro-aniline

3,3'-diaminoazoxybenzene
101-13-3

3,3'-diaminoazoxybenzene

Conditions
Conditions Yield
3-nitro-aniline
99-09-2

3-nitro-aniline

3,3'-diaminoazoxybenzene
101-13-3

3,3'-diaminoazoxybenzene

Conditions
Conditions Yield

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