Relevant articles and documents
All total 3 Articles be found
-
Busch,Schulz
, p. 1465 (1929)
-
Palladium Nanoparticles on Silica Nanospheres for Switchable Reductive Coupling of Nitroarenes
Lakshminarayana, Bhairi,Manna, Arun Kumar,Satyanarayana,Subrahmanyam, Ch.
, p. 2309 - 2321 (2020/02/18)
Abstract: In this study, we synthesized a robust and sustainable Pd/SiO2 nanospheres catalyst. Further, its catalytic activity was demonstrated for the direct reductive coupling of nitroarenes under mild conditions. While the reaction with Pd nanoparticles on other supporting materials such as modified carbon materials and TiO2, under similar conditions, resulted formation of amines exclusively. Therefore, it was confirmed that the SiO2 was found to be the best supporting material towards the selective reductive coupling of nitroarenes. Also, the catalyst could be recycled up to five cycles with a marginal loss of product yield ( 2% yield). Graphic Abstract: [Figure not available: see fulltext.].