Welcome to LookChem.com Sign In|Join Free

Cas Database

101-43-9

101-43-9

Identification

Synonyms:Methacrylicacid, cyclohexyl ester (6CI,7CI,8CI);Cyclohexanol, methacrylate (6CI);Acryester CH;Blemmer CHMA;Light Ester CH;NSC 20968;SR 208;2-Propenoic acid,2-methyl-, cyclohexyl ester;

Post Buying Request Now

Safety information and MSDS view more

  • Pictogram(s):IrritantXi

  • Hazard Codes:Xi,Xn

  • Signal Word:Warning

  • Hazard Statement:H315 Causes skin irritationH319 Causes serious eye irritation H335 May cause respiratory irritation

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Temp during storage must be kept low to minimize formation of peroxides and other oxidation products. ... Storage temp below 30°C are recommended for the polyfunctional methacrylates. ... The methacrylate monomers should not be stored for longer than one year. Shorter storage times are recommended for the aminomethacrylates, ie, three months, and the polyfunctional methacrylates, ie, six months. Many of these cmpd are sensitive to UV light and should, therefore, be stored in the dark. The methacrylic esters may be stored in mild steel, stainless steel, or aluminum. /Methacrylic acid & derivatives/

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price view more

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:TRC
  • Product Description:Cyclohexyl2-Methylprop-2-enoate
  • Packaging:50mg
  • Price:$ 75
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:TCI Chemical
  • Product Description:Cyclohexyl Methacrylate (stabilized with MEHQ) >98.0%(GC)
  • Packaging:25mL
  • Price:$ 27
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:TCI Chemical
  • Product Description:Cyclohexyl Methacrylate (stabilized with MEHQ) >98.0%(GC)
  • Packaging:500mL
  • Price:$ 90
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Cyclohexyl methacrylate ≥97%, contains ~60 ppm monomethyl ether hydroquinone as inhibitor
  • Packaging:250ml
  • Price:$ 209
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Cyclohexyl methacrylate ≥97%, contains ~60 ppm monomethyl ether hydroquinone as inhibitor
  • Packaging:100ml
  • Price:$ 102
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:Cyclohexyl methacrylate
  • Packaging:250 g
  • Price:$ 100
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:Cyclohexyl methacrylate
  • Packaging:5 kg
  • Price:$ 800
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:Cyclohexyl methacrylate
  • Packaging:2 kg
  • Price:$ 400
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:Cyclohexyl methacrylate
  • Packaging:500 g
  • Price:$ 150
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Biosynth Carbosynth
  • Product Description:Cyclohexyl methacrylate
  • Packaging:1 kg
  • Price:$ 250
  • Delivery:In stock
  • Buy Now

Relevant articles and documentsAll total 9 Articles be found

-

Tong,Kenyon

, p. 1355 (1946)

-

Ligand-assisted rate acceleration in lanthanum

Hatano, Manabu,Furuya, Yoshiro,Shimmura, Takumi,Moriyama, Katsuhiko,Kamiya, Sho,Maki, Toshikatsu,Ishihara, Kazuaki

supporting information; experimental part, p. 426 - 429 (2011/04/15)

The transesterification of an equimolar mixture of carboxylic esters and primary (1°), secondary (2°), and tertiary (3°) alcohols in hydrocarbon solvents was promoted with high efficiency by a lanthanum(III) complex, which was prepared in situ from lanthanum (III) isopropoxide (1 mol %) and 2-(2-methoxyethoxy)ethanol (2 mol %). The present La(III) catalyst was highly effective for the chemoselective transesterification in the presence of competitive 1°-and 2°-amines. Remarkably, esters were obtained in good to excellent yields as colorless materials without an inconvenient workup procedure.

Process for the conversion of aldehydes to esters

-

Page/Page column 4, (2010/01/31)

A process for the conversion of aldehydes to esters, specifically acrolein or methacrolein to methyl acrylate or methyl methacrylate, respectively. Essentially in the absence of water, an aldehyde is contacted with an oxidizing agent to form an intermediate and then the intermediate is contacted with a diol or an alcohol to form an ester or diester. Preferably, the oxidizing agent is also a chlorinating agent. Specifically, acrolein or methacrolein is contacted with an oxidizing/chlorinating agent, such as t-butyl hypochlorite, and the chlorinated compound is contacted with an alcohol, such as methanol, to form methyl acrylate or methyl methacrylate, respectively. Generally, the order of addition is for the oxidizing agent to be added to the aldehyde, specifically for t-butyl hypochlorite to be added to acrolein or methacrolein, and for the diol or alcohol to be added to the intermediate, specifically for the methanol to be added to the reaction product of acrolein or methacrolein and t-butyl hypochlorite. The process of the present invention can be carried out in the absence or in the presence of solvent. Generally, better methyl acrylate or methyl methacrylate yields are obtained at lower reaction temperatures.

Process route upstream and downstream products

Process route

2-methylpropenal
78-85-3,25120-30-3

2-methylpropenal

cyclohexanol
108-93-0

cyclohexanol

cyclohexyl methacrylate
101-43-9

cyclohexyl methacrylate

Conditions
Conditions Yield
2-methylpropenal; With tert-butylhypochlorite; In tetrachloromethane; at 20 - 50 ℃; for 5.5 - 6.5h;
cyclohexanol; In tetrachloromethane; at 0 - 20 ℃; for 2h;
poly(methacrylic acid)
79-41-4,25087-26-7,50867-57-7

poly(methacrylic acid)

cyclohexanol
108-93-0

cyclohexanol

cyclohexyl methacrylate
101-43-9

cyclohexyl methacrylate

Conditions
Conditions Yield
toluene-4-sulfonic acid; In water; at 120 ℃; for 24h;
86%
10H-phenothiazine
92-84-2

10H-phenothiazine

cyclohexyl methacrylate
101-43-9

cyclohexyl methacrylate

Conditions
Conditions Yield
With lithium hydroxide; In cyclohexanol;
2-methyllactic acid
594-61-6

2-methyllactic acid

cyclohexanol
108-93-0

cyclohexanol

cyclohexyl methacrylate
101-43-9

cyclohexyl methacrylate

Conditions
Conditions Yield
calcinated cesium nitrate on silica; at 350 ℃; Gas phase;
58.4%
cyclohexyl methacrylate
101-43-9

cyclohexyl methacrylate

Conditions
Conditions Yield
cyclohexanol
108-93-0

cyclohexanol

cyclohexyl methacrylate
101-43-9

cyclohexyl methacrylate

Conditions
Conditions Yield
With lanthanum(III) isopropoxide; 2-(2-methoxyethoxy)ethyl alcohol; In hexane; chemoselective reaction; Reflux;
95%
With C2H3O3(1-)*C37H78N(1+); In hexane; at 90 ℃; for 2h; Molecular sieve;
93%
With sodium methylate;
With di(n-butyl)tin oxide; C21H42NO8;
With di(n-butyl)tin oxide; 4-methoxy-2,2,6,6-tetramethylpiperidin-1-oxyl radical;
With toluene-4-sulfonic acid; hydroquinone; benzene; zuletzt bei 130-140grad;
With sulfuric acid; hydroquinone;
n-perfluorohexyl iodide
355-43-1

n-perfluorohexyl iodide

cyclohexyl methacrylate
101-43-9

cyclohexyl methacrylate

4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-hydroxy-2-methylnonanoic acid cyclohexyl ester

4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-hydroxy-2-methylnonanoic acid cyclohexyl ester

Conditions
Conditions Yield
With pyrrolidine; Diphenylacetaldehyde; oxygen; In ethanol; water; at 20 ℃; for 16h; under 760.051 Torr; Inert atmosphere; Irradiation;
34%
cyclohexyl methacrylate
101-43-9

cyclohexyl methacrylate

cyclohexyl 2-methyl-3-nitroacrylate

cyclohexyl 2-methyl-3-nitroacrylate

cyclohexyl 2-methyl-3-nitroacrylate
1310686-73-7

cyclohexyl 2-methyl-3-nitroacrylate

cyclohexyl 2-hydroxy-2-methyl-3-nitropropanoate
1310686-67-9

cyclohexyl 2-hydroxy-2-methyl-3-nitropropanoate

Conditions
Conditions Yield
With tetranitromethane; triethylamine; In 1,4-dioxane; at 70 ℃; for 4h;
36%
cyclohexyl methacrylate
101-43-9

cyclohexyl methacrylate

2-Hydroperoxy-2-methyl-propionic acid cyclohexyl ester

2-Hydroperoxy-2-methyl-propionic acid cyclohexyl ester

Conditions
Conditions Yield
With triethylsilane; oxygen; [5,10,15,20-tetrakis(2,6-dichlorophenyl)porphinato]cobalt(II); In dichloromethane; isopropyl alcohol; at 28 ℃; for 2h; under 760 Torr;
80%
piperidine
110-89-4

piperidine

cyclohexyl methacrylate
101-43-9

cyclohexyl methacrylate

C<sub>15</sub>H<sub>27</sub>NO<sub>2</sub>

C15H27NO2

Conditions
Conditions Yield
In toluene; at 65 ℃; for 36h;
72.8%

Global suppliers and manufacturers

Global( 102) Suppliers
  • Company Name
  • Business Type
  • Contact Tel
  • Emails
  • Main Products
  • Country
  • Simagchem Corporation
  • Business Type:Manufacturers
  • Contact Tel:+86-592-2680277
  • Emails:sale@simagchem.com
  • Main Products:110
  • Country:China (Mainland)
  • Chemwill Asia Co., Ltd.
  • Business Type:Manufacturers
  • Contact Tel:021-51086038
  • Emails:sales@chemwill.com
  • Main Products:56
  • Country:China (Mainland)
  • Shaanxi BLOOM TECH Co.,Ltd
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-29-86470566
  • Emails:sales@bloomtechz.com
  • Main Products:79
  • Country:China (Mainland)
  • Shanghai Upbio Tech Co.,Ltd
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-21-52196435
  • Emails:upbiocn@hotmail.com
  • Main Products:89
  • Country:China (Mainland)
close
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 101-43-9
Post Buying Request Now
close
Remarks: The blank with*must be completed