1095419-50-3Relevant articles and documents
CATALYSTS AND METHODS FOR FORMING ALKENYL AND ALKYL SUBSTITUTED ARENES
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Paragraph 0155, (2018/03/25)
Embodiments of the present disclosure provide for Rh(I) catalysts, methods of making alkenyl substituted arenes (e.g., allyl arene, vinyl arene, and the like), methods of making alkyl substituted arenes, and the like.
Highly enantioselective and anti -diastereoselective catalytic intermolecular glyoxylate-ene reactions: Effect of the geometrical isomers of alkenes
Zhang, Xiang,Wang, Min,Ding, Ran,Xu, Yun-He,Loh, Teck-Peng
supporting information, p. 2736 - 2739 (2015/06/16)
An efficient method for the synthesis of homoallylic alcohols with high enantioselectivities and anti-diastereoselectivities via an In(III)-catalyzed intermolecular glyoxylate-ene reaction has been developed. The geometrical isomers of alkenes were shown to have different reactivities. Only the isomers of the alkenes having a proton β-cis to the substituent reacted in this catalytic system.
Hydrogen peroxide oxidation of polysubstituted pyrylium salts: Formation of enol esters and furans
Balaban, Teodor Silviu,Hiegemann, Monika
, p. 9827 - 9840 (2007/10/02)
2,4,6-Trialkylsubstituted pyrylium salts 1 have been known to afford 2-acyl-3,5-dialkyl-furans 2 in moderate yields (30 - 45%). Oxidation of these salts in buffer solutions (pH = 3-4.5) increased the yields of acylfurans to 75%. In contrast, tetra- and pe