74783-31-6

Upstream product

• 1095419-50-3 3-phenylpent-2-ene 
• 54542-07-3 1-phenyl-propan-1-one-O-methyl-oxime 
• 93-55-0 1-phenyl-propan-1-one 

Downstream Products

• 93-99-2 benzoic acid phenyl ester 
• 92-52-4 biphenyl 
• 100-41-4 ethylbenzene 
• 93-89-0 benzoic acid ethyl ester 
• 93-55-0 1-phenyl-propan-1-one 
• 65-85-0 benzoic acid 

Relevant academic research and scientific papers

Ketone-derived Peroxides. Part I. Synthetic Methods.

Study of the reactivity of peroxides derivable from ketones by reaction with hydrogen peroxide has required reexamination of preparative methods.Conditions for obtaining five known peroxides from cyclohexanone and the new 1-(1-hydroxycyclohexyldioxy)-1-(1-hydroperoxycyclohexyldioxy)cyclohexane (10) are carefully defined.An improved general method for obtaining cyclic diperoxides (3,3,6,6-tetrasubstituted 1,2,4,5-tetraoxans) (6) has been developed and used to obtain new diperoxides from dibenzyl ketone, di-(4-methylbenzyl) ketone and 2,2-dimethylcyclohexanone whereas indan-2-one and 5,7-dihydro-6H-dibenzocyclohepten-6-one yield the corresponding triperoxides (1,2,4,5,7,8-hexoxonans) (7) and 1,5-diphenylpentan-3-one yields bis-(1-hydroperoxy-1-phenethyl-3-phenylpropyl) peroxide (5k).Ozonolysis of appropriate alkenes has been used to obtain new cyclic diperoxides formally related to 4'-methylacetophenone, propiophenone and deoxybenzoin.

Formation of Ketone Diperoxides from Ozonation of O-Methyloximes

The ozonation of the O-methyloximes has been investigated.Besides the corresponding ketones, ketone diperoxides, and N-methoxyamides were produced.The stereochemistry of the ketone diperoxides was studied by the NMR technique.