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13963-57-0

13963-57-0

Identification

  • Product Name:Aluminum,tris(2,4-pentanedionato-kO2,kO4)-, (OC-6-11)-

  • CAS Number: 13963-57-0

  • EINECS:237-741-6

  • Molecular Weight:324.31

  • Molecular Formula: C15H21AlO6

  • HS Code:29420000

  • Mol File:13963-57-0.mol

Synonyms:Tris(acetylacetonate) aluminum(III);Aluminum 2,4-pentanedionate;Aluminum triacetylacetonate;Aluminum tris(acetylacetonate);CCRIS 3463;NSC 4650;

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Safety information and MSDS view more

  • Pictogram(s):ToxicT

  • Hazard Codes:T

  • Signal Word:Danger

  • Hazard Statement:H301 Toxic if swallowedH319 Causes serious eye irritation

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

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  • Manufacture/Brand:TCI Chemical
  • Product Description:Tris(2,4-pentanedionato)aluminum(III) >99.0%(T)
  • Packaging:500g
  • Price:$ 112
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:Tris(2,4-pentanedionato)aluminum(III) >99.0%(T)
  • Packaging:25g
  • Price:$ 14
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  • Manufacture/Brand:TCI Chemical
  • Product Description:Tris(2,4-pentanedionato)aluminum(III) >99.0%(T)
  • Packaging:100g
  • Price:$ 29
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  • Manufacture/Brand:Strem Chemicals
  • Product Description:Aluminum acetylacetonate, 99%
  • Packaging:100g
  • Price:$ 37
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  • Manufacture/Brand:Strem Chemicals
  • Product Description:Aluminum acetylacetonate, 99%
  • Packaging:500g
  • Price:$ 100
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Aluminum acetylacetonate purified by sublimation, 99.999% trace metals basis
  • Packaging:25g
  • Price:$ 160
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Aluminium acetylacetonate for synthesis
  • Packaging:50 kg
  • Price:$ 9410
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Aluminium acetylacetonate for synthesis. CAS 13963-57-0, pH 8 (3 g/l, H O, 20 °C)., for synthesis
  • Packaging:8010599050
  • Price:$ 9090
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Aluminium acetylacetonate for synthesis
  • Packaging:25 kg
  • Price:$ 4760
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Aluminium acetylacetonate for synthesis. CAS 13963-57-0, pH 8 (3 g/l, H O, 20 °C)., for synthesis
  • Packaging:8010599025
  • Price:$ 4600
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Relevant articles and documentsAll total 4 Articles be found

Formation, nature of activity, and hydrogenation catalysis by nickel bis(acetylacetonate)-lithium tetrahydroaluminate systems

Belykh,Titova,Rokhin,Shmidt

, p. 1911 - 1918 (2010)

A new approach to synthesis of nickel catalysts under the action of lithium tetrahydroaluminate was proposed which allows preparation of high-performance nanosized catalytic systems with well-reproducible properties. The major stages of formation and the

Low field magnetoconductance studies in aggregated Al nano-clusters

Dhara,Panigrahi,Magudapathy,Nair

, p. 284 - 287 (2001)

Nano-aggregates of Al have been formed by 70 keV He+ irradiation on spin cast films of aluminum acetyl acetonate. Three fold increase in conductivity was observed for a fluence range of 1×1016-5×1017 ions/cm2. Electrical transport of the charge carriers was observed to follow Mott's variable range hopping (VRH) mechanism in 3D nano-aggregates of Al in the temperature regime of 110-300 K. Low field (≤1 T) magnetoresistance (MR) studies in these samples showed change in sign of MR from positive for a sample with low zero field resistance [R(H = 0)] to negative for samples with high R(H = 0) owing to quantum interference phenomena of hopping paths.

Acid-Mediated Synthesis of Ordered Mesoporous Aluminosilicates: The Challenge and the Promise

Krishna, Nunna V.,Selvam, Parasuraman

, p. 1604 - 1612 (2017/02/10)

A new intrinsic hydrolysis method was employed, for the first-time, to synthesize well-ordered H-AlSBA-15 with trivalent aluminium exclusively in the tetrahedral framework structure of SBA-15. Unlike other methods, which involve incorporation of aluminium ions in both the framework (Br?nsted) and non-framework (Lewis) sites of the silicate matrix, the intrinsic hydrolysis method isomorphously substitutes aluminium ions in the tetrahedral network even at high aluminium content. This unique approach relies mainly on the hydrolysis rates of the inorganic (silicon and aluminium) precursors used for the preparation in such a way that the condensation occurs simultaneously so as to overcome the usually encountered difficulties in stabilizing aluminium ions in the silicate matrix. In this way, we could successfully synthesize high quality Br?nsted acidic H-AlSBA-15, hitherto not reported. The synthesized materials were systematically characterized by various analytical, spectroscopic, and imaging techniques, including XRD, Brunauer–Emmett–Teller (BET) surface area measurements, TEM, SEM,29Si and27Al magic angle spinning NMR spectroscopy, X-ray fluorescence (XRF), and NH3temperature-programmed desorption (TPD). The characterization results reveal the presence of a highly porous structure (with narrow pores) and tetrahedrally coordinated trivalent aluminium in the silicate matrix with more medium to strong Br?nsted acid sites. The resulting high quality catalysts exhibit excellent activity for tert-butylation of phenol with high selectivity towards para-tert-butyl phenol and 2,4-di-tert-butyl phenol.

PROCESS FOR THE PREPARATION OF METAL ACETYLACETONATES

-

Page 9-10, (2008/06/13)

The present invention provides an improved, economical and environmmentally benign process for metal complexes of acetylacetone having the general formula, M(acac)n wherein M is a metal cation selected from the group consisting of Fe, Co, Ni, Cu, Zn, Al, Ca, Mg, Mo, Ru, Re, U, Th, Ce, Na, K, Rb, Cs, V, Cr, and Mn etc., n is an integer which corresponds to the electrovalence of M, are obtained by reacting the corresponding metal hydroxide, metal hydrated oxide or metal oxide with a stoichiometric amount of acetylacetone and separating the product.

Process route upstream and downstream products

Process route

lithium aluminium tetrahydride
16853-85-3

lithium aluminium tetrahydride

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

aluminium hydride

aluminium hydride

nickel
7440-02-0

nickel

aluminium acetylacetonate
13963-57-0

aluminium acetylacetonate

lithium pentane-2,4-dionate
18115-70-3

lithium pentane-2,4-dionate

Conditions
Conditions Yield
In tetrahydrofuran; benzene; byproducts: H2; various product ratios at various reactant ratios; not isolated, detected by GLC, UV, IR;
acetyl chloride
75-36-5

acetyl chloride

aluminium acetylacetonate
13963-57-0

aluminium acetylacetonate

acetylacetone
123-54-6,81235-32-7

acetylacetone

Conditions
Conditions Yield
aluminum hydroxide

aluminum hydroxide

acetylacetone
123-54-6,81235-32-7

acetylacetone

aluminium acetylacetonate
13963-57-0

aluminium acetylacetonate

Conditions
Conditions Yield
at 0 - 50 ℃; for 0.75h;
91%
tris(o-chlorophenoxo)aluminium(III)

tris(o-chlorophenoxo)aluminium(III)

aluminium acetylacetonate
13963-57-0

aluminium acetylacetonate

Conditions
Conditions Yield
With acetylacetone; In benzene; stirring Al complex and diketone (molar ratio 1/6, slight excess) with stirring, 6h; aaddn. of petroleum ether; pptn.; recrystn. (benzene/acetone); elem. anal.;
aluminium(III) sulfate hexadecahydrate

aluminium(III) sulfate hexadecahydrate

acetylacetone
123-54-6,81235-32-7

acetylacetone

aluminium acetylacetonate
13963-57-0

aluminium acetylacetonate

Conditions
Conditions Yield
acetylacetone; With ammonia; In water;
aluminium(III) sulfate hexadecahydrate; In water;
acetylacetone
123-54-6,81235-32-7

acetylacetone

aluminium acetylacetonate
13963-57-0

aluminium acetylacetonate

Conditions
Conditions Yield
With chloroform;
With ammonia; water;
aluminium trichloride
7446-70-0

aluminium trichloride

acetylacetone
123-54-6,81235-32-7

acetylacetone

aluminium acetylacetonate
13963-57-0

aluminium acetylacetonate

Conditions
Conditions Yield
In water; in acidic medium;
copper bis(tetraisopropoxyaluminate)
70504-66-4,45188-39-4

copper bis(tetraisopropoxyaluminate)

acetylacetone
123-54-6,81235-32-7

acetylacetone

aluminium acetylacetonate
13963-57-0

aluminium acetylacetonate

copper(II) acetylacetonate
13395-16-9

copper(II) acetylacetonate

Conditions
Conditions Yield
In benzene; byproducts: i-propanol; the i-propoxy-complex and acetylacetone (1:8 molar ratio) were refluxedin benzene for 10 h (isopropanol was removed azeotropically out between72-80°C along with benzene); removing the solvent; elem. anal.;
acetylacetone
123-54-6,81235-32-7

acetylacetone

aluminium acetylacetonate
13963-57-0

aluminium acetylacetonate

Conditions
Conditions Yield
aluminium acetylacetonate
13963-57-0

aluminium acetylacetonate

Conditions
Conditions Yield
Zur Darstellung;
Herstellung;

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