1600-44-8Relevant articles and documents
Mn(III)-catalyzed oxidation of sulfides to sulfoxides with hydrogen peroxide
Hosseinpoor, Farideh,Golchoubian, Hamid
, p. 5195 - 5197 (2006)
Sulfides were selectively oxidized to the corresponding sulfoxides in good yields with hydrogen peroxide using a manganese(III) Schiff-base complex as a catalyst in glacial acetic acid as solvent under mild conditions.
Unexpected synthesis of an Au2In2 tetrametallatricyclic complex from α-aminophosphines and formation of Au-In-P and Ag-In-P nanomaterials
Chen, Hsiao Wei,Andy Hor,Pattacini, Roberto,Braunstein, Pierre
, p. 16242 - 16246 (2015)
Four Au-(μ-phosphinite)-In units assemble to form an unprecedented Au2In2 12-membered metallacycle which intersects at the In centres an 8-membered ring containing two In-μ-phosphinate linkages, resulting in a tricyclic structure. Thermal treatment of this complex and of its Ag(i) analog affords Au-In-P and Ag-In-P nanomaterials, respectively.
New heteropolyacids as catalysts for the selective oxidation of sulfides to sulfoxides with hydrogen peroxide
Romanelli, Gustavo P.,Vázquez, Patricia G.,Tundo, Pietro
, p. 75 - 78 (2005)
Pyridinium salts of Keggin-type molybdovanadophosphates proved to be highly active catalysts for the hydrogen peroxide oxidation of sulfides to the corresponding sulfoxide and sulfone derivatives. High conversion and high selectivity for sulfoxide were observed.
Ammonium bromide as an effective and viable catalyst in the oxidation of sulfides using nitro urea and silica sulfuric acid
Ghorbani-Choghamarani,Zamani
, p. 142 - 148 (2011)
A new catalytic method for the chemoselective oxidation of sulfides to the sulfoxides has been studied. A variety of dialkyl, alkylaryl and diaryl sulfides were subjected to the oxidation reaction by a mixture of nitro urea, derived from urea nitrate, silica sulfuric acid (SiO2-OSO3H) and catalytic amounts of ammonium bromide in CH2Cl2 at room temperature.
Dioxygen-Copper Reactivity: A Hydroperoxo-Dicopper(II) Complex
Karlin, Kenneth D.,Cruse, Richard W.,Gultneh, Yilma
, p. 599 - 600 (1987)
A hydroperoxo-dicopper(II) complex (3) can be prepared by (a) direct protonation of a peroxo-dicopper(II) complex (2), (b) oxygenation of a ligand-protonated form of the dicopper(I) precursor of (2), and (c) reaction of hydrogen peroxide with a hydroxo-bridged dicopper(II) complex (5); (3) reacts quantitatively with triphenylphosphine or tetrahydrothiophene to give (5) and oxygenated products.
Surface decorated magnetic nanoparticles with Mn-porphyrin as an effective catalyst for oxidation of sulfides
Shokoohi, Saeedeh,Rayati, Saeed
, p. 8 - 18 (2021/07/19)
Mn-porphyrin complex was anchored coordinatively to silica-coated surface of magnetic nanoparticles (SMNP). Afterward, a heterogeneous nanocatalyst (Fe3O4@SiO2-MnTCPP) has been characterized by Fourier transform infrared (FT-IR), ultraviolet-visible (UV-vis) spectroscopy, powder X-ray diffraction (XRD), scanning electron microscopy (SEM), vibrating sample magnetometry (VSM), thermogravimetric analysis (TGA), and transmission electron microscope (TEM). A thermal stability up to around 350°C was verified for prepared nanocatalyst based on thermogravimetric analysis. Finally, the catalytic performance of magnetically recoverable Mn-catalyst was exploited in the green oxidation of different sulfides with urea hydrogen peroxide (UHP) in the presence of imidazole as co-catalyst in ethanol under heterogeneous conditions. The eco-friendly property of ethanol strongly induced us to employ it as the reaction solvent in this oxidation system. Complete conversion (≥99) of sulfides to the corresponding sulfoxide or sulfones was obtained for ethyl phenyl sulfide, phenyl vinyl sulfide, diallyl sulfide, thiocyanatoethane, 2-ethyl mercaptoethanol and tetrahydrothiophene. Moreover, the recovered catalysts keep constant conversion yield up to at least three cycles.
Synthesis and characterization of magnetic Fe3O4@Creatinine@Zr nanoparticles as novel catalyst for the synthesis of 5-substituted 1H-tetrazoles in water and the selective oxidation of sulfides with classical and ultrasonic methods
Ghadermazi, Mohammad,Moeini, Nazanin,Molaei, Somayeh
, (2021/12/03)
Tetrazoles and sulfoxide compounds have a wide range of applications in industries and are of great expectation to be environmentally friendly and cost-effective. This paper reports the introduction of zirconium supported on Fe3O4 na
Selective synthesis of sulfoxides and sulfonesviacontrollable oxidation of sulfides withN-fluorobenzenesulfonimide
Cao, Zhong-Yan,Li, Xiaolong,Lu, Hao,Wang, Panpan,Wang, Shengqiang,Xu, Xiaobo,Yan, Leyu,Yang, A-Xiu
supporting information, p. 8691 - 8695 (2021/10/22)
A practical and mild method for the switchable synthesis of sulfoxides or sulfonesviaselective oxidation of sulfides using cheapN-fluorobenzenesulfonimide (NFSI) as the oxidant has been developed. These highly chemoselective transformations were simply achieved by varying the NFSI loading with H2O as the green solvent and oxygen source without any additives. The good functional group tolerance makes the strategy valuable.
Copper based on diaminonaphthalene-coated magnetic nanoparticles as robust catalysts for catalytic oxidation reactions and C-S cross-coupling reactions
Yarmohammadi, Nasrin,Ghadermazi, Mohammad,Mozafari, Roya
, p. 9366 - 9380 (2021/03/16)
In this work, the immobilization of copper(ii) on the surface of 1,8-diaminonaphthalene (DAN)-coated magnetic nanoparticles provides a highly active catalyst for the oxidation reaction of sulfides to sulfoxides and the oxidative coupling of thiols to disulfides using hydrogen peroxide (H2O2). This catalyst was also applied for the one-pot synthesis of symmetrical sulfidesviathe reaction of aryl halides with thiourea as the sulfur source in the presence of NaOH instead of former strongly basic and harsh reaction conditions. Under optimum conditions, the synthesis yields of sulfoxides, symmetrical sulfides, and disulfides were about 99%, 95%, and 96% respectively with highest selectivity. The heterogeneous copper-based catalyst has advantages such as the easy recyclability of the catalyst, the easy separation of the product and the less wastage of products during the separation of the catalyst. This heterogeneous nanocatalyst was characterized by FESEM, FT-IR, VSM, XRD, EDX, ICP and TGA. Furthermore, the recycled catalyst can be reused for several runs and is economically effective.
Trisaminomethane–cobalt complex supported on Fe3O4 magnetic nanoparticles as an efficient recoverable nanocatalyst for oxidation of sulfides and C–S coupling reactions
Ashraf, Muhammad Aqeel,Liu, Zhenling,Peng, Wan-Xi
, (2019/11/16)
In this work, trisaminomethane–cobalt complex immobilized onto the surface of Fe3O4 magnetic nanoparticles was successfully prepared via a simple and inexpensive procedure. The prepared nanocatalyst was considered a robust and clean nanoreactor catalyst for the oxidation and synthesis of sulfides under green conditions. This ecofriendly heterogeneous catalyst was characterized by Fourier transform infrared spectroscopy, X-ray diffractometry, energy-dispersive X-ray spectroscopy, inductively coupled plasma-atomic emission spectroscopy, thermogravimetric analysis, vibrating sample magnetometry, X-ray mapping, scanning electron microscopy, and transmission electron microscopy techniques. Use of green medium, easy separation and workup, excellent reusability of the nanocatalyst, and short reaction time are some outstanding advantages of this method.
