161841-12-9

Basic information

• Product Name: 4-(6-ACRYLOXY-HEX-1-YL-OXY)PHENOL
• Synonyms: 4-(6-ACRYLOXY-HEX-1-YL-OXY)PHENOL;4-((6-(Acryloyloxy)hexyl)oxy)phenol;4-(6-Acryloyloxy-n-hex-1-yloxy)phenol;4-[(6-Acryloxy)hexyloxy]phenol;4-[6-(Acryloyloxy)hexyloxy]pheno;6-(4-Hydroxyphenoxy)hexyl acrylate;2-Propenoic acid,6-(4-hydroxyphenoxy)hexyl ester;4-(6-Acryloyloxyhex-1-yloxy)phenol
• CAS NO: 161841-12-9
• Molecular Formula: C15H20O4
• Molecular Weight: 264.3169
• Product Categories: Other
• Mol File: 161841-12-9.mol
• Article Data: 15

Chemical Properties

• Melting Point: 55℃ (water )
• Boiling Point: 407.6 °C at 760 mmHg
• Flash Point: 147 °C
• Appearance: /
• Density: 1.09 g/cm³
• PKA: 10.33±0.15(Predicted)
• CAS DataBase Reference: 4-(6-ACRYLOXY-HEX-1-YL-OXY)PHENOL(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(6-ACRYLOXY-HEX-1-YL-OXY)PHENOL(161841-12-9)
• EPA Substance Registry System: 4-(6-ACRYLOXY-HEX-1-YL-OXY)PHENOL(161841-12-9)

Safety Data

• Hazardous Substances Data: 161841-12-9(Hazardous Substances Data)

Usage

Chemical Properties

off-white powder

Uses

6-(4-Hydroxyphenoxy)hexyl acrylate is used in organic synthesis and pharmaceutical intermediates.

Preparation

The preparation of 6-(4-Hydroxyphenoxy)hexyl acrylate is as follows:10 g (47.56 mmol) of 4-(6-hydroxyhexyloxy)phenol, 50 ml (551.7 mmol)Methyl acrylate, 0.36g (3.75mmol)Methanesulfonic acid was added to the reaction flask, heated to 40 ° C, reacted for 3 hours, and distilled under reduced pressure.The reaction solution was added to water and stirred with methyl tert-butyl ether.The organic layer was collected, concentrated to dryness, and then filtered with ethyl t-butyl ether and n-heptane.After drying, 12.0 g of an off-white solid was obtained in a yield of 95.5%.The content is ≥98.5%.

Upstream product

• 2009-83-8 6-chloro-1-hexanol 
• 123-31-9 hydroquinone 
• 79-10-7 acrylic acid 
• 140-88-5 ethyl acrylate 
• 142627-91-6 4-(6-hydroxyhexyloxy)phenol 
• 292638-85-8 acrylic acid methyl ester 
• 814-68-6 acryloyl chloride 
• 133123-02-1 acrylic acid 6-chlorohexyl ester 
• 53936-79-1 4-benzyloxyphenyl 2-tetrahydropyranyl ether 
• 103-16-2 4-Benzyloxyphenol 
• 161841-11-8 C₂₀H₂₈O₅ 
• 161841-10-7 C₁₇H₂₆O₄ 
• 53936-56-4 4-(tetrahydro-2H-2-pyranyloxy)phenol 

Relevant articles and documents

METHOD FOR PRODUCING 2-HYDRAZINOBENZOTHIAZOLE DERIVATIVE

The present invention provides a novel method for producing a 2-hydrazinobenzothiazole derivative. The present invention also provides a method for producing a compound by using the 2-hydrazinobenzothiazole derivative obtained by the production method, and a composition that contains the compound. The present invention also provides a polymerizable composition that is useful in producing film-shaped polymers and contains the compound obtained by the production method. The invention of the present application provides a method for producing a compound represented by general formula (I-C), the method including a step of reacting a compound represented by general formula (I-B) with a compound represented by general formula (I-A) in the presence of at least one compound selected from the group consisting of metal amides, metal hydrides, metal alkoxides, and organic alkali metals. A compound derived from the compound produced by the production method, and a composition that contains the compound are also provided.

Method for producing 2-hydrazinobenzothiazole derivative also providing a polymerizable composition which is useful for producing a film-like polymer

The present invention provides a novel method for producing a 2-hydrazinobenzothiazole derivative. The present invention also provides a method for producing a compound using the 2-hydrazinobenzothiazole derivative obtained by the production method, and a composition containing the compound. The present invention also provides a polymerizable composition which is useful for producing a film-like polymer and contains the compound obtained by the production method. The present invention provides a method for producing a compound represented by general formula (I-C), which comprises a step for reacting a compound represented by general formula (I-B) and a compound represented by general formula (I-A) in the presence of at least one compound selected from the group consisting of metal amides, metal hydrides, metal alkoxides and organic alkali metals; the present invention also relates to a compound derived from the compound produced by the production method and a composition containing the compound.

POLYMERIZABLE COMPOUND AND OPTICALLY ANISOTROPIC BODY

In light of requests to reduce or reverse the wavelength dispersion of the birefringence of a phase-retardation film in order to increase the viewing angle of a liquid crystal display, the present invention provides a polymerizable compound that reduces, for example, the likelihood of crystals precipitating in a polymerizable composition including the polymerizable compound and enables the polymerizable composition to have high preservation stability and a polymerizable composition including the polymerizable compound which reduces the likelihood of inconsistencies being formed in a film-like polymer produced by polymerizing the polymerizable composition. Another object of the present invention is to provide a polymer produced by polymerizing the polymerizable composition and an optically anisotropic body including the polymer.