1644-11-7

Basic information

• Product Name: 2-(PERFLUOROPROPOXY)PERFLUOROPROPYL TRIFLUOROVINYL ETHER
• Synonyms: perfluoropropoxyperfluoropropyltrifluorovinylether;2-(PERFLUOROPROPOXY)PERFLUOROPROPYL TRIFLUOROVINYL ETHER;PERFLUORO(5-METHYL-3,6-DIOXANON-1-ENE);1,1,1,2,3,3-hexafluoro-2-(heptafluoropropoxy)-3-[(trifluorovinyl)oxy]propane;2-(Perfluoropropoxy)perfluoropropyl trifluorovinyl;2-(PERFLUOROPROPOXY)PERFLUOROPROPYL TRIFLUOROVINYL ETHER 98+%;2-(Heptafluoropropoxy)hexafluoropropyl Trifluorovinyl Ether;1,1,1,2,2,3,3-Heptafluoro-3-({1,1,1,2,3,3-hexafluoro-3-[(trifluoroethenyl)oxy]prop-2-yl}oxy)propane, 2-(Heptafluoropropoxy)hexafluoropropyl trifluorovinyl ether
• CAS NO: 1644-11-7
• Molecular Formula: C₈F₁₆O₂
• Molecular Weight: 432.06
• EINECS: 216-703-2
• Mol File: 1644-11-7.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 104 °C
• Flash Point: 52℃
• Appearance: /
• Density: 1.69
• Vapor Pressure: 47-60hPa at 20-25℃
• Storage Temp.: Refrigerator
• CAS DataBase Reference: 2-(PERFLUOROPROPOXY)PERFLUOROPROPYL TRIFLUOROVINYL ETHER(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(PERFLUOROPROPOXY)PERFLUOROPROPYL TRIFLUOROVINYL ETHER(1644-11-7)
• EPA Substance Registry System: 2-(PERFLUOROPROPOXY)PERFLUOROPROPYL TRIFLUOROVINYL ETHER(1644-11-7)

Safety Data

• Hazard Codes: Xi
• HazardClass: IRRITANT
• Hazardous Substances Data: 1644-11-7(Hazardous Substances Data)

Usage

Description

2-(Perfluoropropoxy)perfluoropropyl trifluorovinyl ether is a fluorinated compound with the chemical formula C6F13O2. It is a colorless liquid at room temperature, characterized by its high thermal and chemical stability, as well as its resistance to solvents and harsh environmental conditions. This unique combination of properties makes it a valuable monomer in the production of fluoropolymer coatings and films.

Uses

Used in Aerospace Industry:
2-(Perfluoropropoxy)perfluoropropyl trifluorovinyl ether is used as a monomer for the production of fluoropolymer coatings and films in the aerospace industry. Its high thermal and chemical stability, along with its resistance to harsh environmental conditions, make it suitable for applications where materials are exposed to extreme temperatures and corrosive environments.
Used in Automotive Industry:
In the automotive industry, 2-(Perfluoropropoxy)perfluoropropyl trifluorovinyl ether is utilized as a monomer for creating fluoropolymer coatings and films. Its properties of high thermal stability and resistance to solvents contribute to the durability and longevity of automotive components, enhancing their performance and reliability.
Used in Electronics Industry:
2-(Perfluoropropoxy)perfluoropropyl trifluorovinyl ether is employed as a monomer in the electronics industry for the production of fluoropolymer coatings and films. Its ability to withstand high temperatures and resist chemical reactions makes it ideal for use in electronic components that require protection from environmental factors and thermal stress.
Used in Specialty Chemicals Production:
As a specialty chemical, 2-(Perfluoropropoxy)perfluoropropyl trifluorovinyl ether is used in the production of high-performance materials. Its unique properties allow for the creation of materials with exceptional thermal and chemical stability, making them suitable for a variety of applications across different industries.
Used as a Processing Aid:
2-(Perfluoropropoxy)perfluoropropyl trifluorovinyl ether also serves as a processing aid in the manufacturing of other fluorinated products. Its ability to improve the production process and enhance the properties of the final product makes it a valuable component in the synthesis of various fluorinated compounds.

Upstream product

• 98-88-4 benzoyl chloride 
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• 76145-89-6 N-(2-Amino-phenyl)-2,3,3,3-tetrafluoro-2-(1,1,2,3,3,3-hexafluoro-2-heptafluoropropyloxy-propoxy)-propionamide 
• 76145-88-5 2'-perfluoropropoxy-2-perfluoropropoxyperfluoropropanoic acid ethyl ester 
• 25080-17-5 6-trifluoromethyl-5-oxa-perfluoroheptyliodide 
• 428-59-1 Hexafluoropropene oxide 
• 111-96-6 diethylene glycol dimethyl ether 
• 54542-82-4 Trimethyl-[1,1,2,2,3,3,4,4-octafluoro-4-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethoxy)-butyl]-silane 

Downstream Products

• 2062-98-8 perfluoro(2-propoxypropionyl) fluoride 
• 1623-05-8 perfluoro(propyl vinyl ether) 
• 67118-55-2 potassium 2,3,3,3-tetrafluoro-2-(perfluoropropoxy)propanoate 
• 3330-15-2 heptafluoropropyl 1,2,2,2-tetrafluoroethyl ether 
• 405-42-5 2',2'-difluorostyrene 
• 1609100-95-9 1-(1,1,2-trifluoro-2-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)ethoxy)-4-((1,1,2-trifluoro-2-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)ethoxy)methyl)benzene 
• 1608467-79-3 (4-(1,1,2-trifluoro-2-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)ethoxy)phenyl)methanol 
• 128931-15-7 1-(1,1,2-trifluoro-2-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)ethoxy)-4-vinylbenzene 
• 1609114-89-7 methyl 4-(1,1,2-trifluoro-2-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)ethoxy)benzoate 
• 1609114-88-6 1-(4-(1,1,2-trifluoro-2-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)ethoxy)phenyl)ethanone 
• 1609114-85-3 4-(1,1,2-trifluoro-2-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)ethoxy)benzaldehyde 
• 1609114-84-2 1-ethynyl-3-(1,1,2-trifluoro-2-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)ethoxy)benzene 
• 1609114-83-1 2-hydroxyethyl 4-(1,1,2-trifluoro-2-(1,1,2,3,3,3-hexafluoro-2-(perfluoropropoxy)propoxy)ethoxy)benzoate 

Relevant articles and documents

Reaction of 1,1,2-trifluoro-2-hexafluoro-2′-(heptafluoropropoxy)-propoxyethylene with amines or alcohols

Reaction between 1,1,2-trifluoro-2-hexafluoro-2′-(heptafluoropropoxy)-propoxyethylene and secondary amines (dimethylamine, diethylamine, dibutylamine, pyrrolidine, piperidine, morpholine) leads either to perfluoro-2-propoxy-3(1H′)-ethoxy-2″-alkoxypropanes - the addition products to the double bond - or to an N,N-dialkylamide of α-substituted fluoroacetic acid depending on the solvent used and the following work-up of the crude product. With primary amines (propylamine, butylamine, monoethanolamine), fluorine-containing imines or N-alkylamides of the α-substituted fluoroacetic acid (as a mixture of diastereomers) were obtained. The use of diethanolamine produces 2-{fluoro-2[hexafluoro-2′-(heptafluoropropoxy)-propoxy]-methyl}-4,5,7,8- tetrahydro-[1.6.3]dioxasozine. Reaction of 1,1,2-trifluoro-2′-hexafluoro-2′-(heptafluoropropoxy)- propoxyethylene with alcohols (methanol, ethanol, β,β,β-trifluoroethanol, 2-methoxyethanol, 2-ethoxyethanol, iso-propanol, butanol and pentafluorophenol) in the presence of KOH in tetrahydrofuran (sulfolane, DMSO, acetonitrile) or sodium alkoxide in an alcoholic medium yields only the corresponding ethers as a mixture of diastereomers. Treatment of ethyleneglycol, glycerine, pentaerythritol, triethanolamine, 2-(2-hydroxyethylsulphanyl) ethanol, 4-(2-hydroxyethyl) phenol with 1,1,2-trifluoro-2′-(heptafluoropropoxy)-2-hexafluoropropoxyethylene provides the addition products to all OH groups if the reaction is carried out in DMSO, sulfolane or acetonitrile. However, the use of THF as the solvent leads to the formation of α-substituted tetrahydrofuran together with the formation of ethers. The initial perfluoro(propoxypropoxy) olefin can be hydrolyzed in the alkaline media to give fluoro-[hexafluoro-2-(heptafluoropropoxy)propoxy]acetic acid.

A fluorinated alkyl vinyl ether of preparation method

The invention discloses a fluoroalkylvinyl ether preparation method. The method comprises the following steps: carrying out a film forming reaction on perfluoroalkyloxypropionyl fluoride by a salt forming agent under the action of an aprotic alcohol ether catalyst at 20-80DEG C, and carrying out a decarboxylation reaction at 110-150DEG C to prepare corresponding fluoroalkylvinyl ether. The preparation method has the advantages of high raw material conversion rate, simple process, no need of a solvent, and the like.

Polyfluorinated ethers: IV.* By-products in the synthesis of polyfluorinated alkyl vinyl ethers in a solvating solvent

By-products formed in the synthesis of perfluoro(propyl vinyl ether), perfluoro(2-propoxypropyl vinyl ether), and methyl perfluoro(4-vinyloxybutanoate) in a solvating solvent have been studied. 1998 MAHK "Hayka/Interperiodica".