1749-29-7Relevant articles and documents
Neutral Fe(iv) alkylidenes, including some that bind dinitrogen
Lindley, Brian M.,Jacobs, Brian P.,MacMillan, Samantha N.,Wolczanski, Peter T.
, p. 3891 - 3894 (2016)
Neutral, formally Fe(iv) alkylidene species are sought as plausible olefin metathesis catalysts, and the synthesis of several is described herein. The complexes are prepared via nucleophilic attack (Nu = MeLi, PhCH2K, 2-picolyllithium, Me2PCH2Li, MePhPCH2Li, Ph2PCH2Li) at the imine of cationic [mer-{κ-C,N,C-(C6H4-yl)-2-CH=N(2-C6H4-C(iPr)=)}Fe(PMe3)3][B(3,5-CF3-C6H3)4]. In contrast, MeMgCl and mesityllithium displaced and deprotonated bound PMe3, respectively. Structural details are provided for mer-{κ-C,N,C-(C6H4-yl)-2-CH(Bn)N(2-C6H4-C(iPr)=)}Fe{trans-(PMe3)2}N2 and {κ-C,N,C,P-(C6H4-yl)-2-CH(CH2PMe2)N(2-C6H4-C(iPr)=)}Fe(PMe3)2.
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Konishi et al.
, p. 2281 (1971)
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REACTION OF 2-PICOLYLLITHIUM AND 6-METHYL-2-PICOLYLLITHIUM WITH VINYL(tert-BUTYL)ACETYLENE
Cherkasov, L. N.
, p. 1181 - 1182 (1982)
The possibility of obtaining pyridylallene hydrocarbons with normal structure with a branched grouping in the side chain on the basis of vinyl(alkyl)acetylene hydrocarbons with iso structures and, respectively, 2-picolyl and 2,6-lutidyllithium is demonstrated.
Synthesis, structure and coordination of the ambiphilic ligand (2-picolyl)BCy2
Vergnaud, Jerome,Ayed, Tahra,Hussein, Khansaa,Vendier, Laure,Grellier, Mary,Bouhadir, Ghenwa,Barthelat, Jean-Claude,Sabo-Etienne, Sylviane,Bourissou, Didier
, p. 2370 - 2372 (2008/02/04)
The new pyridine-borane compound (2-picolyl)BCy2, readily prepared from 2-picolyllithium and ClBCy2, adopts a head-to-tail dimeric structure in the solid state as indicated by X-ray diffraction analysis and according to NMR and DFT studies, the dimeric form equilibrates in solution with a strained monomeric structure; the ambiphilic behavior of the new compound is illustrated by its bridging coordination to the (p-cymene)RuCl2 unit. The Royal Society of Chemistry.