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18052-27-2

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18052-27-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 18052-27-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,0,5 and 2 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 18052-27:
(7*1)+(6*8)+(5*0)+(4*5)+(3*2)+(2*2)+(1*7)=92
92 % 10 = 2
So 18052-27-2 is a valid CAS Registry Number.

18052-27-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-butyl-dimethyl-phenoxysilane

1.2 Other means of identification

Product number -
Other names Phenol,DMTBS

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:18052-27-2 SDS

18052-27-2Relevant articles and documents

Functionalization at Will of Rim-Differentiated Pillar[5]arenes

Demay-Drouhard, Paul,Du, Ke,Samanta, Kushal,Wan, Xintong,Yang, Weiwei,Srinivasan, Rajavel,Sue, Andrew C.-H.,Zuilhof, Han

, p. 3976 - 3980 (2019)

The development of an efficient synthetic route toward rim-differentiated C5-symmetric pillar[5]arenes (P[5]s), whose two rims are decorated with different chemical functionalities, opens up successive transformations of this macrocyclic scaffo

Synthesis of Bidentate Nitrogen Ligands by Rh-Catalyzed C-H Annulation and Their Application to Pd-Catalyzed Aerobic C-H Alkenylation

Kim, Hyun Tae,Kang, Eunsu,Kim, Minkyu,Joo, Jung Min

supporting information, p. 3657 - 3662 (2021/05/10)

A new class of bidentate ligands was prepared by a modular approach involving Rh-catalyzed C-H annulation reactions. The resulting conformationally constrained ligands enabled the Pd-catalyzed C-H alkenylation at electron-rich and sterically less hindered positions of electron-rich arenes while promoting the facile oxidation of Pd(0) intermediates by oxygen. This newly introduced ligand class is complementary to the ligands developed for Pd-catalyzed oxidative reactions and may find broad application in transition-metal-catalyzed reactions.

Ligand-Promoted Non-Directed C?H Cyanation of Arenes

Liu, Luo-Yan,Yeung, Kap-Sun,Yu, Jin-Quan

supporting information, p. 2199 - 2202 (2019/01/24)

This article reports the first example of a 2-pyridone accelerated non-directed C?H cyanation with an arene as the limiting reagent. This protocol is compatible with a broad scope of arenes, including advanced intermediates, drug molecules, and natural products. A kinetic isotope experiment (kH/kD=4.40) indicates that the C?H bond cleavage is the rate-limiting step. Also, the reaction is readily scalable, further showcasing the synthetic utility of this method.

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