23956-51-6

Basic information

• Product Name: 1,2-Ethanediamine, N,N-dimethyl-N'-(phenylmethylene)-
• CAS NO: 23956-51-6
• Molecular Formula: C11H16N2
• Molecular Weight: 176.261
• Mol File: 23956-51-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 1,2-Ethanediamine, N,N-dimethyl-N'-(phenylmethylene)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Ethanediamine, N,N-dimethyl-N'-(phenylmethylene)-(23956-51-6)
• EPA Substance Registry System: 1,2-Ethanediamine, N,N-dimethyl-N'-(phenylmethylene)-(23956-51-6)

Safety Data

• Hazardous Substances Data: 23956-51-6(Hazardous Substances Data)

Upstream product

• 538-51-2 benzylidene phenylamine 
• 108-00-9 N,N-dimethylethylenediamine 
• 1749-16-2 N'-(benzylideneamino)-N,N-diethylethan-1-amine 
• 100-52-7 benzaldehyde 

Downstream Products

• 141956-26-5 2-phenyl-3-[2-(N,N-dimethylamino)ethyl]-1,3-thiazolidin-4-one 
• 15855-37-5 N,N-diethyl-N'-benzylethylenediamine 
• 100-52-7 benzaldehyde 
• 90-02-8 salicylaldehyde 
• 1749-16-2 N'-(benzylideneamino)-N,N-diethylethan-1-amine 
• 690661-82-6 C₁₁H₁₆Cl₂N₂Pt 
• 681457-39-6 Pt(C₆H₅)(CH₃)2NC₂H₄NCHC₆H₄P(C₆H₅)3 
• 681457-35-2 Pt(C₆H₅)(CH₃)2NC₂H₄NCHC₆H₄ 
• 70509-18-1 N-(Diphenylmethylen)-N'-(phenylmethylen)-1,1-ethandiamin 
• 70509-15-8 1-Benzylthio-N-(phenylmethylen)-ethanamin 
• 70509-14-7 1-Ethylthio-N-(phenylmethylen)-ethanamin 
• 70509-10-3 1-phenyl-3-ethoxy-2-aza-1-butene 
• 70509-12-5 1-phenyl-3-methoxy-2-aza-1-butene 
• 70509-11-4 1-phenyl-2-aza-1,3-butadiene 

Relevant articles and documents

New Schiff base cationic surfactants as corrosion inhibitors for carbon steel in acidic medium: Weight loss, electrochemical and SEM characterization techniques

Two new Schiff base cationic surfactants were synthesized and their chemical structures confirmed using FTIR spectroscopy. The tensioactive and thermodynamic characteristics of their solutions were determined using surface tension/log concentration plots.

Organomagnesium-catalyzed isomerization of terminal alkynes to allenes and internal alkynes

Organomagnesium complexes 2 were synthesized from N,N-dialkylamineimine ligands 1 and dibenzylmagnesium by benzylation of the imine moiety. 3-Aryl-1-propynes reacted with 2 to form the corresponding tetraalkynyl complexes, which acted as catalysts for the transformation of these terminal alkynes into allenes and further to internal alkynes under mild conditions. To the best of our knowledge, this example is the first of an organomagnesium-catalyzed isomerization of alkynes. Notably, the reactions proceeded through temporally separated autotandem catalysis, thus allowing the isolation of the allene or internal alkyne species in good yields. Mechanistic experiments suggested that the catalytically active tetraalkynyl complexes consist of a tautomeric mixture of alkynyl-, allenyl-, and propargylmagnesium species.

Base-free copper-catalyzed aerobic oxidation of benzylic alcohols with N-benzylidene-N,N-dimethylthane-1,2-diamine and TEMPO

Selective oxidation of alcohols using N-benzylidene-N,N-dimethylthane-1,2- diamine, CuBr2 and TEMPO as the catalytic system was developed. Catalyzed by this simple catalytic system in the absence of any external base, various benzylic alcohols