70509-11-4Relevant articles and documents
Bifunctional ruthenium(II) PCP pincer complexes and their catalytic activity in acceptorless dehydrogenative reactions
Musa, Sanaa,Fronton, Sveta,Vaccaro, Luigi,Gelman, Dmitri
, p. 3069 - 3073 (2013/07/05)
New air-stable ruthenium complex 1, bearing the dibenzobarrelene-based cooperating ligand, was synthesized in 96% yield and fully characterized. The examination of its coordination chemistry revealed that the ruthenium center in 1 is slightly distorted from octahedral geometry, and 31P NMR is consistent with the formation of trans-spanned pincer complexes bearing strongly bent dibenzobarrelene-based ligands. The catalytic activity of the new complex was examined in acceptorless dehydrogenation of alcohols and acceptorless dehydrogenative coupling of alcohols with amines.
Retrodienic Reactions. Part 15. Synthesis and Flash Thermolysis of Diels-Alder Imino-adducts: Isolation and Reactivity of 2-Aza-1,3-dienes
Malecot, Yves-Michel,Ripoll, Jean-Louis,Thuillier, Andre
, p. 959 - 993 (2007/10/02)
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