24470-01-7

Basic information

• Product Name: 2-[(E)-2-(4-Chlorophenyl)vinyl]pyridine
• Synonyms: 2-[(E)-2-(4-Chlorophenyl)vinyl]pyridine
• CAS NO: 24470-01-7
• Molecular Formula: C₁₃H₁₀ClN
• Molecular Weight: 215.68
• Mol File: 24470-01-7.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 337.7±11.0 °C(Predicted)
• Appearance: /
• Density: 1.212±0.06 g/cm3(Predicted)
• PKA: 4.54±0.10(Predicted)
• CAS DataBase Reference: 2-[(E)-2-(4-Chlorophenyl)vinyl]pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(E)-2-(4-Chlorophenyl)vinyl]pyridine(24470-01-7)
• EPA Substance Registry System: 2-[(E)-2-(4-Chlorophenyl)vinyl]pyridine(24470-01-7)

Safety Data

• Hazardous Substances Data: 24470-01-7(Hazardous Substances Data)

Upstream product

• 109-06-8 α-picoline 
• 104-88-1 4-chlorobenzaldehyde 
• 38700-15-1 triphenyl-(2-pyridylmethyl)phosphonium chloride 
• 873-76-7 para-Chlorobenzyl alcohol 
• 104-83-6 1-Chloro-4-(chloromethyl)benzene 
• 1121-60-4 pyridine-2-carbaldehyde 
• 39225-17-7 diethyl 4-chlorobenzylphosphonate 
• 80221-12-1 2-(4-chloro-phenylethynyl)-pyridine 
• 104-86-9 4-chlorobenzylamine 
• 100-69-6 2-vinylpyridine 
• 1679-18-1 4-Chlorophenylboronic acid 

Downstream Products

• 93532-40-2 2-(4-chlorostyryl)pyridine N-oxide 
• 58963-35-2 1-[2-(4-chloro-phenyl)-indolizin-3-yl]-ethanone 

Relevant articles and documents

A new insight into the push-pull effect of substituents via the stilbene-like model compounds

In this paper, authors report on 1-pyridyl-2-arylethenes, 1-furyl-2-arylethylenes, 1,2-diphenylpropylenes and substituted cinnamyl anilines as stilbene-like model compounds to investigate the factors dominating the push-pull effect of substituents via usi

Xanthate-mediated synthesis of (E)-alkenes by semi-hydrogenation of alkynes using water as the hydrogen donor

Semi-hydrogenation of alkynes is one of the most widely used methods for obtaining alkenes in laboratory preparation and in industry. Transition metal catalysts have been extensively studied for this transformation, but the tolerance of functional groups, such as pyridine,-OH,-NH2,-Bpin, and halides, and the toxicity of the trace amount of transition metal catalysts are still highly challenging. In this study, we report a general and robust strategy to achieve the semi-hydrogenation of alkynes using inexpensive and commercially available xanthate as the mediator. Mechanism studies support a non-radical process and H2O acts as the hydrogen donor.

Oxidant-Controlled C-sp2/sp3-H Cross-Dehydrogenative Coupling of N-Heterocycles with Benzylamines

Oxidant controlled ionic liquid mediated cross-dehydrogenative coupling (CDC) of benzylamines with N-heterocycles having sp2 or sp3 carbon resulted in the formation of C-benzoylated or alkenylated products. Benzoylation of N-heterocycles occurs via (NH4)2S2O8 catalyzed benzoyl radical formation. An oxidative alkenylation of N-heterocycles having C-sp3 carbon (2-methylaza-arenes) occurs via deamination of benzylamine followed by C-sp3-H bond activation in high stereoselectivity. Both benzoylation and alkenylation protocols are metal-free, green, simple, efficient, and tolerate a wide variety of functional groups.