34422-57-6

Basic information

• Product Name: tris(pentafluorophenyl)bismuth
• Synonyms: tris(pentafluorophenyl)bismuth
• CAS NO: 34422-57-6
• Molecular Weight: 710.154
• Mol File: 34422-57-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: tris(pentafluorophenyl)bismuth(CAS DataBase Reference)
• NIST Chemistry Reference: tris(pentafluorophenyl)bismuth(34422-57-6)
• EPA Substance Registry System: tris(pentafluorophenyl)bismuth(34422-57-6)

Safety Data

• Hazardous Substances Data: 34422-57-6(Hazardous Substances Data)

Usage

General Description

Tris(pentafluorophenyl)bismuth is a chemical compound with the formula Bi(C6F5)3. It is a coordination complex that consists of a bismuth atom bonded to three pentafluorophenyl ligands. tris(pentafluorophenyl)bismuth is commonly used as a catalyst in organic synthesis due to its ability to promote a variety of chemical reactions. It has been found to be effective in a range of transformations including carbon-carbon bond formation, reduction reactions, and asymmetric catalysis. Tris(pentafluorophenyl)bismuth is an air-stable white solid that is soluble in organic solvents, making it a convenient and versatile reagent for synthetic applications. Additionally, it has been studied for its potential in the development of new materials and as a contrast agent in medical imaging.

Upstream product

• 74-96-4 ethyl bromide 
• 344-04-7 bromopentafluorobenzene 
• 7787-60-2 bismuth(III) chloride 
• 7439-95-4 magnesium 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 7440-69-9 bismuth 
• 30123-12-7 silver(I)pentafluorobenzene 
• 7787-58-8 bismuth(III) bromide 

Downstream Products

• 101565-24-6 perfluoro-2-methyl-3-phenyl-2-pentene 
• 7440-69-9 bismuth 
• 363-72-4 Pentafluorobenzene 
• 434-90-2 decafluorobiphenyl 
• 196407-05-3 Bi(C₆F₅)3Cl₂ 
• 1259-34-3 tris(pentafluorophenyl)arsine 
• 973-17-1 bis(pentafluorophenyl)mercury(II) 
• 31569-56-9 tris-(pentafluoro phenyl) indane 
• 1065-49-2 perfluoro(tetraphenyl)tin 
• 1043-50-1 pentafluorophenyl sulfide 
• 7787-61-3 bismuth(III) fluoride 
• 118798-75-7 tris(pentafluorophenyl)bismuth difluoride 
• 38091-68-8 Pentafluorophenyliodine tetrafluoride 
• 3512-11-6 perfluoro(4-phenylpyridine) 

Relevant articles and documents

The preparations and properties of tris(perfluoroorgano)bismuth compounds Bi(Rf)3 (Rf=CF3, C2F5, n-C3F7, n-C4F9, n-C6F13, n-C8H17, C6F5)

Tris(perfluoroorgano)bismuth compounds Bi(Rf)3 (Rf=CF3, C2F5, n-C3F7, n-C4F9, n-C6H13, n-C8H17, C6F5) are easily prepared in high yields from the reactions of perfluoroorganocadmium complexes with BiCl3 or BiBr3 in aprotic solvents.T

Silver compounds in synthetic chemistry. 1. A facile preparative route for pentafluorophenylsilver, AgC6F5 and its use as an oxidative pentafluorophenyl group transfer reagent in reactions with group 12 to 16 elements

AgC6F5 is directly and quantitatively formed from room temperature reactions of AgF and Me3SiC6F5 in N-donor solvents, particularly EtCN. Solutions of AgC6F5 prepared by this method exhibit excellent oxidative properties in reactions with a variety of groups 12 to 16 elements giving the corresponding pentafluorophenyl element compounds in moderate to excellent yields. AgC6F5·EtCN crystallises with monoclinic symmetry (C2/c, Z = 8, a = 2301.4(5)pm, b = 1078.8(4)pm, c = 948.0(2)pm, β = 113.19(1)°) and exhibits chains of silver atoms with bridging C6F5 groups.

Structures of Pentaarylbismuth Compounds

Pentaarylbismuth compounds were synthesized by the known reaction Ar3BiX2 + 2 Ar'Li ---> 2 LiX + BiAr3Ar'2.Whenever possible they were characterized by single-crystal X-ray structure determination.In two cases almost ideal square-pyramidal geometry was found, in a third case there were two different molecules in the unit cell, both again with square-pyramidal geometry.None of these novel bismuth pentaaryls exhibit the deep coloration and the dichroism of Bi(C6H5)5. - Key Words: Bismuth organic compounds / Fluorinated aromatic rings / Square pyramidal bismuth