371-77-7

Basic information

• Product Name: Methanamine, 1,1,1-trifluoro-N-(trifluoromethyl)-
• CAS NO: 371-77-7
• Molecular Formula: C2HF6N
• Molecular Weight: 153.027
• Mol File: 371-77-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Methanamine, 1,1,1-trifluoro-N-(trifluoromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanamine, 1,1,1-trifluoro-N-(trifluoromethyl)-(371-77-7)
• EPA Substance Registry System: Methanamine, 1,1,1-trifluoro-N-(trifluoromethyl)-(371-77-7)

Safety Data

• Hazardous Substances Data: 371-77-7(Hazardous Substances Data)

Upstream product

• 108-89-4 picoline 
• 2154-71-4 bis-trifluoromethyl-aminooxyl 
• 100-44-7 benzyl chloride 
• 431-94-7 N-chlorobistrifluoromethylamine 
• 1165952-91-9 cyclohexa-1,3-diene 
• 758-43-0 N-bromobis(trifluoromethyl)amine 
• 5764-87-4 N-Jod-bis(trifluormethyl)-amin 
• 1768-32-7 sulfur bis(trifluoromethyl)amide chloride 
• 100-66-3 methoxybenzene 
• 359-63-7 N,N-bis(trifluoromethyl)hydroxylamine 
• 10026-13-8 phosphorus pentachloride 
• 74770-43-7 perfluoro(2,5-dimethyl-4-oxa-3,5-diazahex-2-ene) 
• 73513-59-4 cis-hexafluoroazomethane 
• 371-56-2 N,N'-bis(trifluoromethyl)-diazene-N-oxide 

Downstream Products

• 71000-82-3 cyanate 
• 16984-48-8 fluoride 
• 3812-32-6 carbonate^(2-) 
• 124-38-9 carbon dioxide 
• 420-05-3 cyanic acid 
• 7664-39-3 hydrogen fluoride 

Relevant articles and documents

A New Method for the Synthesis of Perfluorooxaziridines. Preparation of Perfluoro-cis-2,3-dialkyloxaziridines

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PERFLUOROALKYL DERIVATIVES OF NITROGEN. PART LIII. REACTION OF PERFLUORO(2,5-DIMETHYL-4-OXA-3,5-DIAZAHEX-2-ENE) WITH FLUORO-OLEFINS

Thermal decomposition of the title compound at 140 deg C gives mainly nitrogen, hexafluoroacetone and tetrakistrifluoromethylhydrazine while reaction with tetrafluoroethylene and chlorotrifluoroethylene affords equimolar mixtures of the 1:1 adducts (CF3)2C=NCF2CFXON(CF3)2 and (CF3)2C=NOCFXCF2N(CF3)2 (X=F and Cl) in highly yield via four-centre addition or a radical-cage process.

FLUORINATIONS WITH COMPLEX METAL FLUORIDES. PART 6. FLUORINATION OF PYRIDINE AND RELATED COMPOUNDS WITH CAESIUM TETRAFLUOROCOBALTATE(III)

Pyridine has been fluorinated over caesium tetrafluorocobaltate(III) (CsCo(III)F4) at 300-400 deg C to give a mixture of undecafluoro-N-methyl-pyrrolidine, bis(trifluoromethyl)amine, pentafluoropyridine and several polyfluoropyridines; the product composition depend to some extent on the geometry of the reactor.The fluorinations of pentafluoropyridine, piperidine and undecafluoropiperidine were also investigated.