5395-04-0 Usage
Description
1,1'-Carbonyldipiperidine, also known as a urea derivative, is an organic compound with the chemical formula C10H20N2O. It is characterized by its faintly yellow crystalline appearance and is commonly used as a reactant in the synthesis of various chemical compounds. Its structure, which includes two piperidine rings connected by a carbonyl group, allows it to participate in a wide range of chemical reactions and applications across different industries.
Uses
Used in Chemical Synthesis:
1,1'-Carbonyldipiperidine is used as a reactant for the synthesis of various compounds, including bis(guanidine) ligands, diaminocarbeneand Fischer-carbene complexes of palladium and nickel, neodymium and europium complexes with amides and cyclic aminoxides, bis(pentamethylene)urea complexes of lanthanide nitrates, and tetra(amino)methanes.
Used in Catalyst and Ligand Design:
1,1'-Carbonyldipiperidine is used as a ligand for tuning the reactivity of copper(I) dioxygen complexes. Its unique structure allows it to modulate the electronic and steric properties of the catalyst, enhancing its performance in various chemical reactions.
Used in Luminescence Studies:
In the field of materials science, 1,1'-Carbonyldipiperidine is used in the development of europium complexes for luminescence studies. Its ability to form stable complexes with europium ions makes it a valuable component in the design of luminescent materials with potential applications in sensing, imaging, and lighting technologies.
Used in Pharmaceutical Industry:
1,1'-Carbonyldipiperidine is also utilized in the pharmaceutical industry as an intermediate for the synthesis of various drugs and drug candidates. Its versatile chemical properties enable it to be incorporated into a wide range of molecular structures, making it a valuable building block in drug discovery and development.
Check Digit Verification of cas no
The CAS Registry Mumber 5395-04-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,3,9 and 5 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 5395-04:
(6*5)+(5*3)+(4*9)+(3*5)+(2*0)+(1*4)=100
100 % 10 = 0
So 5395-04-0 is a valid CAS Registry Number.
InChI:InChI=1/C11H20N2O/c14-11(12-7-3-1-4-8-12)13-9-5-2-6-10-13/h1-10H2
5395-04-0Relevant articles and documents
OXIDATIVE CARBONYLATION OF PIPERIDINE IN THE PRESENCE OF PALLADIUM(II)-COPPER(II) CATALYTIC SYSTEM.
Sheludyakov,Golodov
, p. 251 - 253 (1984)
A kinetic study on oxidative carbonylation of piperidine to give 1,1 prime -carbonyldipiperidine in the presence of Pd(II) and Cu(II) complexes at 40 degree C has been investigated.
CARBONATE DERIVATIVE PRODUCTION METHOD
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Paragraph 0153-0154; 0163-0164, (2020/04/09)
The objective of the present invention is to provide a method for producing a carbonate derivative in a safe and efficient manner. The method for producing a carbonate derivative according to the present invention is characterized in comprising irradiating light on a composition containing a C1-4 halogenated hydrocarbon having one or more kinds of halogen atoms selected from the group consisting of a chlorine atom, a bromine atom and an iodine atom, a nucleophilic functional group-containing compound and the specific base in the presence of oxygen.
CaI2-Catalyzed direct transformation of: N -Alloc-, N -Troc-, and N -Cbz-protected amines to asymmetrical ureas
Tran, Van Hieu,Kim, Hee-Kwon
, p. 14093 - 14101 (2019/09/18)
A novel and facile CaI2-catalyzed direct synthesis of asymmetrical ureas from N-Alloc-, N-Troc-, and N-Cbz-protected amines is developed. In this study, the efficient reaction of Alloc-, Troc-, and Cbz-carbamates with amines in the presence of catalytic CaI2 successfully generated various asymmetrical ureas. This catalytic synthetic procedure provided the desired ureas via reactions of these protected aromatic and aliphatic amines with various amines in high yields without side products. This suggests that novel direct synthesis of ureas from Alloc-, Troc-, and Cbz-carbamates can be a promising approach for the synthesis of useful ureas.