540-49-8Relevant articles and documents
Metal ions do not play a direct role in the formation of carbon-carbon triple bonds during reduction of trihaloalkyls by CrII or V II
Levy, Ophir,Bino, Avi
supporting information, p. 15944 - 15947 (2013/02/23)
Carbyne radicals: Reactions of trihaloalkyl compounds with Cr2+ or V2+ in aqueous solutions yield alkynes and other products. Stepwise halogen abstractions from the trihaloalkyls form alkyl carbyne triradicals in solution. These radicals undergo coupling reactions, producing triply bonded alkyne molecules (see scheme). This process is not metal-assisted and does not occur in the coordination sphere of the metal ions.
Liquid-phase oxidation of bromovinyl compounds with molecular oxygen
Bayatyan,Bayatyan,Saakyan
, p. 1849 - 1852 (2008/02/08)
Liquid-phase oxidation of bromovinyl compounds with the aim to obtain the corresponding α-bromo acids was studied.