677-22-5

Basic information

• Product Name: TERT-BUTYLMAGNESIUM CHLORIDE
• Synonyms: tert-Butylmagnesium chloride, 1M in MeTHF;tert-Butylmagnesium chloride [1.0 M solution in THF];tert-Butylmagnesium chloride, 1,7M solution in diethyl ether, AcroSeal§3;tert-Butylmagnesium chloride, 1.7M solution in THF, AcroSeal;tert-Butylmagnesium chloride, 1.7M solution in diethyl ether, AcroSeal;tert-ButylMagnesiuM chloride ,1.0 M in tetrahydrofuran;tert-butylMagnesiuM;(1,1-Dimethylethyl)magnesium chloride
• CAS NO: 677-22-5
• Molecular Formula: C₄H₉ClMg
• Molecular Weight: 116.87
• EINECS: 211-638-6
• Product Categories: Grignard Reagent;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents
• Mol File: 677-22-5.mol
• Article Data: 15

Chemical Properties

• Melting Point: -108℃ (Tetrahydrofuran)
• Boiling Point: 34 °F
• Flash Point: 34 °F
• Appearance: Clear brown to dark brown/Liquid
• Density: 0.931 g/mL at 25 °C
• Storage Temp.: 2-8°C
• Water Solubility: Miscible with alcohol and water.
• Sensitive: Air & Moisture Sensitive
• BRN: 3535403
• CAS DataBase Reference: TERT-BUTYLMAGNESIUM CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: TERT-BUTYLMAGNESIUM CHLORIDE(677-22-5)
• EPA Substance Registry System: TERT-BUTYLMAGNESIUM CHLORIDE(677-22-5)

Safety Data

• Hazard Codes: F+,C,F
• Statements: 12-14/15-19-22-34-66-67-15-11-14-37-17-40
• Safety Statements: 9-16-26-29-33-36/37/39-43-45
• RIDADR: UN 3399 4.3/PG 1
• WGK Germany: 1
• F: 1-3-10
• HazardClass: 4.3
• PackingGroup: I
• Hazardous Substances Data: 677-22-5(Hazardous Substances Data)

Usage

Chemical Properties

clear faint grey to grey, grey-brown or light

Uses

tert-Butylmagnesium chloride is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides.

InChI:InChI=1/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1/rC4H9Mg.ClH/c1-4(2,3)5;/h1-3H3;1H/q+1;/p-1

Upstream product

• 507-20-0 tertiary butyl chloride 
• 7439-95-4 magnesium 
• 86901-19-1 9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium 
• 141-57-1 n-propyltrichlorosilane 

Downstream Products

• 462-18-0 tridecan-7-one 
• 91-01-0 1,1-Diphenylmethanol 
• 40132-64-7 (E)-(4,4-dimethylpent-1-en-1-yl)benzene 
• 32363-47-6 (4-(tert-butyl)phenyl)(mesityl)methanone 
• 938-16-9 2,2-dimethylpropiophenone 
• 30314-46-6 1-(3,4-dimethoxyphenyl)-2,2-dimethylpropan-1-one 
• 75-84-3 2,2-dimethyl-propanol-1 
• 79885-46-4 2-isopropoxypropionic acid 
• 115-11-7 isobutene 
• 132350-97-1 4,4-dimethyl-1-phenyl-pent-1-yn-3-ol 
• 75-64-9 tert-butylamine 
• 18335-33-6 1-phenyl-4,4-dimethyl-3-pentanol 
• 19775-91-8 (E)-4,4-dimethyl-1-phenylpent-1-en-3-ol 
• 594-82-1 tetramethyl-2,2,3,3 butane 

Relevant articles and documents

COMPLEXES OF IMIDAZOLE LIGANDS

Metal imidazolate complexes are described where imidazoles ligands functionalized with bulky groups and their anionic counterpart, i.e., imidazolates are described. Compounds comprising one or more such polyalkylated imidazolate anions coordinated to a metal or more than one metal, selected from the group consisting of alkali metals, transition metals, lanthanide metals, actinide metals, main group metals, including the chalcogenides, are contemplated. Alternatively, multiple different imidazole anions, in addition to other different anions, can be coordinated to metals to make new complexes. The synthesis of novel compounds and their use to form thin metal containing films is also contemplated.

METHOD OF MANUFACTURING AN AMINOARYL-CONTAINING ORGANOSILICON COMPOUND AND METHOD OF MANUFACTURING AN INTERMEDIATE PRODUCT OF THE AFOREMENTIONED COMPOUND

To provide an aminoaryl-containing organosilicon compound with high efficiency, after protecting amino groups of a haloaniline compound with a specific compound, to form a Grignard reagent and to deprotect the aforementioned groups by reacting the Grignard reagent with a silicon compound.