6832-17-3

Basic information

• Product Name: Ethanone, 2-diazo-1-(4-methoxyphenyl)-
• CAS NO: 6832-17-3
• Molecular Formula: C9H8N2O2
• Molecular Weight: 176.175
• Mol File: 6832-17-3.mol
• Article Data: 30

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-diazo-1-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-diazo-1-(4-methoxyphenyl)-(6832-17-3)
• EPA Substance Registry System: Ethanone, 2-diazo-1-(4-methoxyphenyl)-(6832-17-3)

Safety Data

• Hazardous Substances Data: 6832-17-3(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 100-07-2 4-methoxy-benzoyl chloride 
• 23722-34-1 2-hydrazono-1-(4-methoxyphenyl)ethanone 
• 34933-41-0 sodium salt of p-methoxybenzoylacetaldehyde 
• 72818-30-5 Anisoyl-4-tolylsulfon 
• 31706-15-7 3-(4-methoxy-phenyl)-3-oxo-propionaldehyde 
• 1078202-81-9 C₁₂H₁₆N₂O₂Si 
• 16208-17-6 2,2-dihydroxy-1-(4-methoxyphenyl)ethan-1-one 
• 6595-28-4 2-azido-1-(4-methoxyphenyl)ethan-1-one 
• 6327-79-3 1-(4-methoxyphenyl)-3-phenylpropane-1,3-dione 
• 18362-51-1 1,3-bis(4'-methoxyphenyl)propane-1,3-dione 
• 15191-68-1 4,4,4-trifluoro-1-(4-methoxyphenyl)-1,3-butanedione 
• 2632-13-5 2-Bromo-4'-methoxyacetophenone 
• 100-09-4 4-methoxybenzoic acid 

Downstream Products

• 21160-26-9 2-methoxy-1-(4-methoxy-phenyl)-ethanone 
• 23786-14-3 4-methoxy-phenyl acetic acid methyl ester 
• 33108-93-9 α-chloro-α-oximino-p-methoxyacetophenone 
• 20341-14-4 N-[2-(1,3-benzodioxol-5-yl)ethyl]-2-(4-methoxyphenyl)acetamide 
• 86601-72-1 2-benzylamino-1-(4-methoxy-phenyl)-ethanol 
• 58518-78-8 p-methoxyphenacyl acetate 
• 5784-95-2 2-(4-methoxyphenyl)-1H-indole 
• 7397-16-2 (4-methoxy-phenyl)-glyoxal-bis-phenylhydrazone 
• 34800-47-0 2'-phenyl-(4-methoxyphenyl)acetohydrazide 
• 37818-09-0 1-(4-methoxy-phenyl)-2-((Z)-6-methyl-7,8-dihydro-6H-[1,3]dioxolo[4,5-g]isoquinolin-5-ylidene)-ethanone 
• 13651-21-3 3-p-Methoxybenzoyl-1,2-diphenylcyclopropen-⁽¹⁾ 
• 69163-82-2 5-(4-methoxyphenyl)-2-methyl-1,3-oxazole 
• 27046-38-4 5-(4-methoxy-phenyl)-3,6-dihydro-[1,3,4]thiadiazin-2-one p-tolylhydrazone 
• 23808-80-2 2-p-Chlorphenylimino-3-p-chlorphenyl-4-p-methoxyphenyl-thiazolin 

Relevant articles and documents

N-transfer reagent and method for preparing the same and its application

Provided are a novel N-transfer reagent and a method for preparing the same and its application. The N-transfer reagent is represented by the following Formula (I): The various novel N-transfer reagents of the present invention can be quickly prepared by employing different nitrobenzene precursors. The N-transfer reagents can directly convert a variety of amino compounds into diazo compounds under mild conditions. Particularly, the N-transfer reagents can facilitate the synthesis of the diazo compounds. The application of synthesizing diazo compounds of the present invention can greatly decrease the difficulty in operation, increase the safety during experiments, reduce the cost of production and the environmental pollution, and enhance the industrial value of diazo compounds.

Practical Application of the Aqueous 'Sulfonyl-Azide-Free' (SAFE) Diazo Transfer Protocol to Less α-C-H Acidic Ketones and Esters

The earlier described 'sulfonyl-Azide-free' ('SAFE') protocol for diazo transfer to CH-Acidic 1,3-dicarbonyl compounds (and their similarly activated congeners) has been extended to the less reactive monocarbonyl substrates, which previously required a se

Photoinduced Multicomponent Synthesis of α-Silyloxy Acrylamides, an Unexplored Class of Silyl Enol Ethers

The photoinduced, multicomponent reaction of α-diazoketones, silanols, and isocyanides affords α-silyloxy acrylamides, formally derived from α-keto amides. The presence of a secondary amido group makes classic preparative methods for silyl enol ethers unfeasible in this case, while the mild conditions required by this photochemical approach allow their synthesis in good yields; moreover, the general structure can be easily modified by varying each component of the multicomponent reaction. Fine-tuning of the reaction conditions (i.e., solvents, radiation, additives) can be exploited to obtain complete Z selectivity. The reactivity of this overlooked class of silyl enol ethers has been investigated, and features that could pave the way to new applications have been found.