73296-31-8

Basic information

• Product Name: Silane, trimethyl(phenyltelluro)-
• CAS NO: 73296-31-8
• Molecular Formula: C9H14SiTe
• Molecular Weight: 277.896
• Mol File: 73296-31-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(phenyltelluro)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(phenyltelluro)-(73296-31-8)
• EPA Substance Registry System: Silane, trimethyl(phenyltelluro)-(73296-31-8)

Safety Data

• Hazardous Substances Data: 73296-31-8(Hazardous Substances Data)

Upstream product

• 109-99-9 tetrahydrofuran 
• 75-77-4 chloro-trimethyl-silane 
• 100-58-3 phenylmagnesium bromide 
• 14683-12-6 tellurium 
• 591-51-5 phenyllithium 
• 629-05-0 n-octyne 
• 194346-19-5 (C₁₂H₉)TePt(P(C₂H₅)3)2Si(CH₃)3 
• 32294-60-3 diphenyl ditelluride 
• 41422-67-7 sodium phenyltelluride 

Downstream Products

• 96185-55-6 Trimethyl-(3-phenyltellanyl-propoxy)-silane 
• 91489-38-2 4-(phenyltelluro)butyl trimethylsilyl ether 
• 96185-56-7 Trimethyl-(1-methyl-4-phenyltellanyl-butoxy)-silane 
• 96206-05-2 Trimethyl-((1R,2R)-2-phenyltellanyl-cyclododecyloxy)-silane 
• 1825-61-2 Trimethylmethoxysilane 
• 872-89-9 methylphenyltelluride 
• 14642-79-6 benzyloxy-trimethylsilane 
• 32344-00-6 benzyl phenyl telluride 
• 6221-88-1 dodecyl trimethylsilyl ether 
• 96185-52-3 Trimethyl-((1R,2R)-2-phenyltellanyl-cyclohexyloxy)-silane 
• 1529-17-5 phenyltrimethylsilyl ether 
• 96185-53-4 Trimethyl-(1-methyl-2-phenyltellanyl-ethoxy)-silane 
• 420-56-4 trimethylsilyl fluoride 
• 32294-60-3 diphenyl ditelluride 

Relevant articles and documents

Regio- and stereoselective addition of trans-Pt(TeAr)(SiMe3)(PEt3)2 to terminal alkynes leading to cis-[(Z)-β-trimethylsilylalkenyl]platinum(II) complexes

Selective insertion of terminal alkynes RC≡CH into the Si—Pt bond of trans-Pt(TeAr)(SiMe3)(PEt3)2 took place readily to produce the corresponding novel alkenyl complexes cis-Pt(TeAr)[(Z)-CR=CHSiMe3](PEt3)2. The structure of the complex was characterized by an X-ray analysis.

Synthesis and Crystal Structures of Copper Zinc Phenylthiolate and the First Copper Zinc Selenolate and Tellurolate Complexes

Five copper zinc phenylchalcogenolate complexes [(iPr3PCu)3(ZnMe2)2(SPh)3] (1), [(iPr3PCu)2(ZnPh)4(SPh)6] (2), [(iPr3PCu)2(ZnEt)4(SPh)6] (3), [(iPr3PCu)3(ZnEt)(SePh)4] (4), and [(iPr3PCu)3Cu(iPr3PZn)(TePh)6] (5) were synthesized by the reaction of phosphine stabilized copper phenylchalcogenolate complexes with ZnR2 (R = Me, Et, Ph) with and without additional chalcogenol. The novel mixed metal compounds were characterized by single-crystal X-ray structure analysis and NMR spectroscopy. 4 and 5 are the first examples of compounds with a Zn–Se–Cu or a Zn–Te–Cu linkage, respectively.

NUCLEOPHILIC CLEAVAGES OF ESTERS AND ETHERS WITH PHENYLTELLUROTRIMETHYLSILANE

The title tellurosilane 1 reacted with esters and ethers in the presence of catalytic zinc iodide under very mild conditions, giving the corresponding products with C-telluration and O-silylation via nucleophilic cleavages of the C-O bonds.