78031-08-0

Basic information

• Product Name: Benzene, [(bromodifluoromethyl)thio]-
• CAS NO: 78031-08-0
• Molecular Formula: C7H5BrF2S
• Molecular Weight: 239.084
• Mol File: 78031-08-0.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: Benzene, [(bromodifluoromethyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(bromodifluoromethyl)thio]-(78031-08-0)
• EPA Substance Registry System: Benzene, [(bromodifluoromethyl)thio]-(78031-08-0)

Safety Data

• Hazardous Substances Data: 78031-08-0(Hazardous Substances Data)

Upstream product

• 75-61-6 dibromodifluoromethane 
• 108-98-5 thiophenol 
• 353-59-3 halon-1211 
• 930-69-8 sodium thiophenolate 
• 58201-66-4 (bromodifluormethyl)triphenylphosphonium bromide 

Downstream Products

• 80351-59-3 difluorobis(thiophenyl)methane 
• 776313-44-1 allyl 4,4-difluoro-2-methyl-4-phenylsulfanylbutanoate 
• 776313-48-5 12,12-difluoro-12-phenylsulfanyldodecan-1-ol 
• 776313-50-9 1,1-difluoro-3-butenyl phenyl sulfide 
• 776313-45-2 1,1-difluoro-3-phenylsulfonylpropyl phenyl sulfide 
• 13921-09-0 [(1-ethylpropyl)thio]benzene 
• 91638-68-5 (1-Ethyl-1-methyl-propylsulfanyl)-benzene 
• 861721-54-2 1,1-difluoro-2-phenyl-1-(phenylsulfonyl)propan-2-ol 
• 776313-42-9 1,1-difluoro-3-phenylpropyl phenyl sulfide 
• 536975-49-2 phenyl (trimethylsilyl)difluoromethyl sulfide 
• 80351-58-2 [(bromodifluoromethyl)sulfonyl]benzene 
• 456-56-4 phenyl trifluoromethylsulfide 
• 1535-67-7 difluoromethyl phenyl sulfide 
• 1421521-04-1 (E)-1-[3,3-difluoro-3-(phenylsulfonyl)prop-1-en-1-yl]-3-nitrobenzene 

Relevant articles and documents

An easier and quicker access to (benzenesulfonyl)difluoromethanesulfenamide reagent

(Benzenesulfonyl)difluoromethanesulfenamide (PhSO2-BB12H) is an interesting reagent to lead to various fluoroalkylselenotated molecules. This compound is obtained from [(benzenesulfonyl)difluoromethyl]trimethylsilane. Herein, a new process in two steps, w

Visible-Light-Induced Arylthiofluoroalkylations of Unactivated Heteroaromatics and Alkenes

Visible-light-induced arylthiofluoroalkylations of unactivated heteroaromatics and alkenes have been developed utilizing readily available arylthiofluoroalkyl sources. This method enables simultaneous installation of sulfur and fluoroalkyl moieties, two important functional groups, which demonstrates its potential use for late-stage modifications in the synthesis of functional molecules. This method can be easily utilized to fine-tune the properties of lead molecules in drug development by controlling the number of fluorine atoms in the reagents.

α-(Difluoromethyl)styrene: Improved approach to grams scale synthesis

Improved, efficient, grams scale synthesis of α-(difluoromethyl)styrene (DFMST) based on nucleophilic difluoromethylation process using difluoromethylphenyl sulfone, is presented. Difluoromethylating agent (PhSO2CF2H) was obtained in two-step synthetic sequence with 69% overall yield. Three-step DFMST synthetic route was easily implemented for the preparation of gram quantities of the monomer, allowing for polymerization studies. The syntheses were based on the use of commercially available and reasonable in price starting materials and reagents.