80351-59-3

Basic information

• Product Name: Benzene, 1,1'-[(difluoromethylene)bis(thio)]bis-
• CAS NO: 80351-59-3
• Molecular Formula: C13H10F2S2
• Molecular Weight: 268.351
• Mol File: 80351-59-3.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-[(difluoromethylene)bis(thio)]bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-[(difluoromethylene)bis(thio)]bis-(80351-59-3)
• EPA Substance Registry System: Benzene, 1,1'-[(difluoromethylene)bis(thio)]bis-(80351-59-3)

Safety Data

• Hazardous Substances Data: 80351-59-3(Hazardous Substances Data)

Upstream product

• 1184-76-5 difluorodiiodomethane 
• 108-98-5 thiophenol 
• 353-59-3 halon-1211 
• 75-71-8 Dichlorodifluoromethane 
• 930-69-8 sodium thiophenolate 
• 78031-08-0 [(bromodifluoromethyl)sulfanyl]benzene 
• 58201-66-4 (bromodifluormethyl)triphenylphosphonium bromide 
• 3111-52-2 potassium thiophenolate 
• 882-33-7 diphenyldisulfane 
• 536975-49-2 phenyl (trimethylsilyl)difluoromethyl sulfide 
• 81290-20-2 (trifluoromethyl)trimethylsilane 
• 24850-33-7 allyltributylstanane 
• 762-72-1 allyl-trimethyl-silane 
• 1535-65-5 difluoromethyl phenyl sulfone 

Relevant articles and documents

One-pot preparation of (RSe)2CF2 and (RS)2CF2 compounds via insertion of TMSCF3-derived difluorocarbene into diselenides and disulfides

A method for the first direct insertion of difluorcarbene, generated from TMSCF3, into diselenides and disulfides is disclosed, producing novel difluoromethyl diselenoacetals and difluoromethyl dithioacetals. The reaction conditions tolerate a range of synthetically useful and biologically relevant functional groups. The process is scalable, with two representative compounds prepared at a gram-scale in good yields, and it utilizes cheap and available reagents.

Fluoride-induced nucleophilic (phenylthio)difluoromethylation of carbonyl compounds with [difluoro(phenylthio)methyl]trimethylsilane (TMS-CF 2SPh)

A fluoride-induced nucleophilic (phenylthio)difluoromethylation method using TMS-CF2SPh has been achieved. This new methodology efficiently transfers "PhSCF2" group into both enolizable and non-enolizable aldehydes and ketones to giv

The reactions of difluorodiiodomethane with nucleophiles

Treatment of difluorodiiodomethane with phenoxides (ArO-) in DMF at room temperature gives ArOCF2I in 7-15%, the carbonates (ArOCO2Ar) being the major products, while with thiophenoxides affords difluoromethylene derivativ