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Cas Database

825-83-2

825-83-2

Identification

  • Product Name:4-(Trifluoromethyl)thiophenol

  • CAS Number: 825-83-2

  • EINECS:-0

  • Molecular Weight:178.178

  • Molecular Formula: C7H5F3S

  • HS Code:29309090

  • Mol File:825-83-2.mol

Synonyms:p-Toluenethiol,a,a,a-trifluoro- (7CI,8CI);p-(Trifluoromethyl)benzenethiol;p-(Trifluoromethyl)thiophenol;a,a,a-Trifluoro-p-methylbenzenethiol;

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Safety information and MSDS

  • Pictogram(s):IrritantXi

  • Hazard Codes:Xi

Supplier and reference price

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  • Manufacture/Brand:TRC
  • Product Description:4-(Trifluoromethyl)thiophenol
  • Packaging:100mg
  • Price:$ 75
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:4-(Trifluoromethyl)benzenethiol >98.0%(GC)(T)
  • Packaging:1g
  • Price:$ 51
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:4-(Trifluoromethyl)benzenethiol >98.0%(GC)(T)
  • Packaging:5g
  • Price:$ 150
  • Delivery:In stock
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  • Manufacture/Brand:SynQuest Laboratories
  • Product Description:4-(Trifluoromethyl)thiophenol 95%
  • Packaging:50 g
  • Price:$ 408
  • Delivery:In stock
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  • Manufacture/Brand:SynQuest Laboratories
  • Product Description:4-(Trifluoromethyl)thiophenol 95%
  • Packaging:25 g
  • Price:$ 240
  • Delivery:In stock
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  • Manufacture/Brand:SynQuest Laboratories
  • Product Description:4-(Trifluoromethyl)thiophenol 95%
  • Packaging:5 g
  • Price:$ 56
  • Delivery:In stock
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:4-(Trifluoromethyl)thiophenol 95+%
  • Packaging:1g
  • Price:$ 18
  • Delivery:In stock
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:4-(Trifluoromethyl)thiophenol 95+%
  • Packaging:25g
  • Price:$ 256
  • Delivery:In stock
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:4-(Trifluoromethyl)thiophenol 95+%
  • Packaging:5g
  • Price:$ 56
  • Delivery:In stock
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  • Manufacture/Brand:Labseeker
  • Product Description:4-(TRIFLUOROMETHYL)BENZENE-1-THIOL 97
  • Packaging:200g
  • Price:$ 2383
  • Delivery:In stock
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Relevant articles and documentsAll total 13 Articles be found

Palladium catalyzed synthesis of aryl thiols: Sodium thiosulfate as a cheap and nontoxic mercapto surrogate

Yi, Jun,Fu, Yao,Xiao, Bin,Cui, Wei-Chen,Guo, Qing-Xiang

experimental part, p. 205 - 208 (2011/02/26)

A Pd-catalyzed coupling reaction of ArBr/ArCl/ArOTf with sodium thiosulfate takes place in presence of Cs2CO3 at 80 °C. The reaction mixture is directly treated with Zn/HCl to afford aryl thiols in good to excellent yields.

Copper-catalyzed coupling of thiourea with aryl iodides: The direct synthesis of aryl thiols

Qiao, Shu,Xie, Kun,Qi, Junsheng

scheme or table, p. 1441 - 1443 (2011/01/04)

A general, economical and efficient protocol for the direct copper-catalyzed coupling of thiourea with aryl iodides is developed and it will be potentially applied in large-scale industry as a preferred process.

Thermal reactions of chloroarenes with hydrogen sulfide in the presence of methanol

Deryagina,Sukhomasova,Levanova,Papernaya,Korchevin

, p. 1624 - 1630 (2007/10/03)

Gas-phase reactions of chloroarenes (ClC6H4X, X = H, 4-CH3, 4-OH, 4-Cl, 4-CF3) with hydrogen sulfide or its precursors were investigated in the presence of methanol, which was a stronger H-donor than hydrogen sulfide. Introducing methanol increased the selectivity of arenethiols formation at X = H and 4-CH3 and did not affect the reaction selectivity at acceptor X. The efficiency of methanol influence was considered from the viewpoint of free-radical reaction mechanism and the stability of the arenethiyl radicals. 2005 Pleiades Publishing, Inc.

Direct synthesis of thioethers from sulfonyl chlorides and activated alcohols

Martin, Michael T,Thomas, Alford M,York, Douglas G

, p. 2145 - 2147 (2007/10/03)

An efficient, safe one-pot synthesis of thioethers from aromatic sulfonyl chlorides and activated alcohols has been developed under non-aqueous conditions.

ELECTROLYTE MATERIALS CONTAINING HIGHLY DISSOCIATED METAL ION SALTS

-

, (2008/06/13)

The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy o

Process route upstream and downstream products

Process route

4-chlorobenzotrifluoride
98-56-6

4-chlorobenzotrifluoride

α,α,α-trifluorotoluene
98-08-8

α,α,α-trifluorotoluene

4-trifluoromethylbenzenethiol
825-83-2

4-trifluoromethylbenzenethiol

1-(trifluoromethyl)-4-{[4-(trifluoromethyl)phenyl]sulfanyl}benzene
90141-51-8

1-(trifluoromethyl)-4-{[4-(trifluoromethyl)phenyl]sulfanyl}benzene

Conditions
Conditions Yield
With ethanethiol; at 600 ℃; for 0.0138889h; Product distribution; other reagents (hydrogensulfid), yield calc. on reacted comp.;
11.3 % Chromat.
66.8 % Chromat.
10.8 % Chromat.
With hydrogen sulfide; at 600 ℃; for 0.00833333h; Mechanism;
14.0 % Turnov.
47.4 % Turnov.
22.5 % Turnov.
With methanol; hydrogen sulfide; at 610 ℃; Title compound not separated from byproducts;
25.8 % Chromat.
14.3 % Chromat.
With methanol; diethyl sulphide; at 630 ℃; for 1.5h; Title compound not separated from byproducts;
Diethyl disulfide
110-81-6

Diethyl disulfide

4-chlorobenzotrifluoride
98-56-6

4-chlorobenzotrifluoride

α,α,α-trifluorotoluene
98-08-8

α,α,α-trifluorotoluene

4-trifluoromethylbenzenethiol
825-83-2

4-trifluoromethylbenzenethiol

5-trifluoromethylbenzo<b>thiophene
132896-18-5

5-trifluoromethylbenzothiophene

1-(trifluoromethyl)-4-{[4-(trifluoromethyl)phenyl]sulfanyl}benzene
90141-51-8

1-(trifluoromethyl)-4-{[4-(trifluoromethyl)phenyl]sulfanyl}benzene

Conditions
Conditions Yield
at 630 ℃; for 0.0175h; Product distribution; gas phase copyrolysis;
49.7%
17.2%
13%
9.3%
7.1%
p-trifluoromethylphenyl bromide
402-43-7

p-trifluoromethylphenyl bromide

4-trifluoromethylbenzenethiol
825-83-2

4-trifluoromethylbenzenethiol

Conditions
Conditions Yield
p-trifluoromethylphenyl bromide; With water; caesium carbonate; sodium thiosulfate; bis(dibenzylideneacetone)-palladium(0); XPhos; In toluene; tert-butyl alcohol; at 80 ℃; for 24h; Inert atmosphere;
With hydrogenchloride; zinc; In water; for 1h; Cooling with ice;
80%
With sulfur; magnesium; Multistep reaction; 1.) ether;
With sulfur; magnesium; In diethyl ether; 1.) reflux, 0.5 h;
4-chlorobenzotrifluoride
98-56-6

4-chlorobenzotrifluoride

4-trifluoromethylbenzenethiol
825-83-2

4-trifluoromethylbenzenethiol

Conditions
Conditions Yield
4-chlorobenzotrifluoride; With water; palladium diacetate; caesium carbonate; sodium thiosulfate; XPhos; In toluene; tert-butyl alcohol; at 80 ℃; for 24h; Inert atmosphere;
With hydrogenchloride; zinc; In water; for 1h; Cooling with ice;
85%
p-(trifluoromethyl)phenyl trifluoromethanesulfonate
146397-87-7

p-(trifluoromethyl)phenyl trifluoromethanesulfonate

4-trifluoromethylbenzenethiol
825-83-2

4-trifluoromethylbenzenethiol

Conditions
Conditions Yield
p-(trifluoromethyl)phenyl trifluoromethanesulfonate; With water; palladium diacetate; caesium carbonate; sodium thiosulfate; XPhos; In toluene; tert-butyl alcohol; at 80 ℃; for 24h; Inert atmosphere;
With hydrogenchloride; zinc; In water; for 1h; Cooling with ice;
70%
S-(4-(trifluoromethyl)phenyl) N,N-dimethylcarbamothioate
130782-68-2

S-(4-(trifluoromethyl)phenyl) N,N-dimethylcarbamothioate

4-trifluoromethylbenzenethiol
825-83-2

4-trifluoromethylbenzenethiol

Conditions
Conditions Yield
With sodium methylate; In N-methyl-acetamide; hydrogenchloride; methanol;
67%
4-Iodobenzotrifluoride
455-13-0

4-Iodobenzotrifluoride

4-trifluoromethylbenzenethiol
825-83-2

4-trifluoromethylbenzenethiol

Conditions
Conditions Yield
With copper(l) iodide; thiourea; L-proline; sodium t-butanolate; In dimethyl sulfoxide; at 90 ℃; for 24h; Inert atmosphere;
96%
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

4-trifluoromethylbenzenethiol
825-83-2

4-trifluoromethylbenzenethiol

Conditions
Conditions Yield
With pyridine; In chloroform;
4-(trifluoromethyl)phenylmagnesium bromide
402-51-7

4-(trifluoromethyl)phenylmagnesium bromide

4-trifluoromethylbenzenethiol
825-83-2

4-trifluoromethylbenzenethiol

Conditions
Conditions Yield
With sulfur;
With sulfur; In diethyl ether; for 1h;
para-trifluoromethylbenzenesulphonic acid
109787-11-3

para-trifluoromethylbenzenesulphonic acid

4-trifluoromethylbenzenethiol
825-83-2

4-trifluoromethylbenzenethiol

Conditions
Conditions Yield
With dimethylsilicon dichloride; In ethyl acetate; at 85 ℃; for 16h;

Global suppliers and manufacturers

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  • GIHI CHEMICALS CO.,LIMITED
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