825-83-2Relevant articles and documents
Palladium catalyzed synthesis of aryl thiols: Sodium thiosulfate as a cheap and nontoxic mercapto surrogate
Yi, Jun,Fu, Yao,Xiao, Bin,Cui, Wei-Chen,Guo, Qing-Xiang
experimental part, p. 205 - 208 (2011/02/26)
A Pd-catalyzed coupling reaction of ArBr/ArCl/ArOTf with sodium thiosulfate takes place in presence of Cs2CO3 at 80 °C. The reaction mixture is directly treated with Zn/HCl to afford aryl thiols in good to excellent yields.
Thermal reactions of chloroarenes with hydrogen sulfide in the presence of methanol
Deryagina,Sukhomasova,Levanova,Papernaya,Korchevin
, p. 1624 - 1630 (2007/10/03)
Gas-phase reactions of chloroarenes (ClC6H4X, X = H, 4-CH3, 4-OH, 4-Cl, 4-CF3) with hydrogen sulfide or its precursors were investigated in the presence of methanol, which was a stronger H-donor than hydrogen sulfide. Introducing methanol increased the selectivity of arenethiols formation at X = H and 4-CH3 and did not affect the reaction selectivity at acceptor X. The efficiency of methanol influence was considered from the viewpoint of free-radical reaction mechanism and the stability of the arenethiyl radicals. 2005 Pleiades Publishing, Inc.
ELECTROLYTE MATERIALS CONTAINING HIGHLY DISSOCIATED METAL ION SALTS
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, (2008/06/13)
The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy o
