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Cas Database

91427-49-5

91427-49-5

Identification

  • Product Name:Ethanol, 2-(2-chloroethoxy)-, benzoate

  • CAS Number: 91427-49-5

  • EINECS:

  • Molecular Weight:228.675

  • Molecular Formula: C11H13ClO3

  • HS Code:

  • Mol File:91427-49-5.mol

Synonyms:

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Safety information and MSDS view more

  • Signal Word:no data available

  • Hazard Statement:no data available

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

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Relevant articles and documentsAll total 3 Articles be found

Regiospecific thermal C-acylation of imidazo [1,2-a] pyridines via an N- acylimidazolium intermediate

Chayer, Said,Schmitt, Martine,Collot, Valerie,Bourguignon, Jean-Jacques

, p. 9685 - 9688 (1998)

Direct acylation of imidazo [1,2-a] pyridines in a sealed tube at 130°C and without catalyst gave various 3-acyl derivatives in satisfactory yields.

Cross-Dehydrogenating Coupling of Aldehydes with Amines/R-OTBS Ethers by Visible-Light Photoredox Catalysis: Synthesis of Amides, Esters, and Ureas

Pandey, Ganesh,Koley, Suvajit,Talukdar, Ranadeep,Sahani, Pramod Kumar

supporting information, p. 5861 - 5865 (2018/09/21)

A straightforward synthesis of amides, ureas, and esters is reported by visible-light cross-dehydrogenating coupling (CDC) of aldehydes (or amine carbaldehydes) and amines/R-OTBS ethers by photoredox catalysis. The reaction is found to be general and high yielding. A plausible mechanistic pathway has been proposed for these transformations and is supported by appropriate controlled experiments.

Group 5 and group 6 metal halides as very efficient catalysts for acylative cleavage of ethers

Guo, Qiaoxia,Miyaji, Taichi,Hara, Ryuichiro,Shen, Baojian,Takahashi, Tamotsu

, p. 7327 - 7334 (2007/10/03)

Group 5 and 6 metal chlorides such as MoCl5, WCl6, NbCl5 and TaCl5 were found as very efficient catalysts for acylative cleavage of the C-O bond of ethers. Compared with conventional Lewis acid catalysts such as ZnCl2, AlCl3, SnCl4 and TiCl4, group 5 and 6 metal chlorides showed better results in the catalytic C-O bond cleavage of dibutyl ether with benzoyl chloride.

Process route upstream and downstream products

Process route

sodium benzoate
532-32-1

sodium benzoate

3-oxa-1,5-dichloropentane
111-44-4

3-oxa-1,5-dichloropentane

diethyleneglycol dibenzoate
120-55-8,9004-86-8

diethyleneglycol dibenzoate

2-(2-chloroethoxy)ethyl benzoate
91427-49-5

2-(2-chloroethoxy)ethyl benzoate

Conditions
Conditions Yield
With diethylamine; at 140 ℃;
benzoyl chloride
98-88-4

benzoyl chloride

(E)-3-Ureido-but-2-enoic acid ethyl ester
5435-44-9,22243-66-9

(E)-3-Ureido-but-2-enoic acid ethyl ester

1,2-ethanediol, dibenzoate
94-49-5,9004-86-8

1,2-ethanediol, dibenzoate

2-chloroethyl benzoate
939-55-9

2-chloroethyl benzoate

2-(2-chloroethoxy)ethyl benzoate
91427-49-5

2-(2-chloroethoxy)ethyl benzoate

Conditions
Conditions Yield
tert-butyl (2-(2-chloroethoxy)ethoxy)dimethylsilane
119382-85-3

tert-butyl (2-(2-chloroethoxy)ethoxy)dimethylsilane

benzaldehyde
100-52-7

benzaldehyde

2-(2-chloroethoxy)ethyl benzoate
91427-49-5

2-(2-chloroethoxy)ethyl benzoate

Conditions
Conditions Yield
With Bromotrichloromethane; In acetonitrile; at 20 ℃; for 28h; Inert atmosphere; Irradiation;
65%
benzoyl chloride
98-88-4

benzoyl chloride

2-chloroethyl benzoate
939-55-9

2-chloroethyl benzoate

2-(2-chloroethoxy)ethyl benzoate
91427-49-5

2-(2-chloroethoxy)ethyl benzoate

Conditions
Conditions Yield
With molybdenum(V) chloride; In 1,2-dichloro-ethane; at 80 ℃; for 168h;
52%
5%
benzoyl chloride
98-88-4

benzoyl chloride

7-Methyl-imidazo[1,2-a]pyridine
874-39-5

7-Methyl-imidazo[1,2-a]pyridine

2-(2-chloroethoxy)ethyl benzoate
91427-49-5

2-(2-chloroethoxy)ethyl benzoate

7-methylimidazo[1,2-a](pyridin-3-yl)(phenyl)methanone

7-methylimidazo[1,2-a](pyridin-3-yl)(phenyl)methanone

Conditions
Conditions Yield
In 1,4-dioxane; at 130 ℃; for 30h;
47%
53%
diethylene glycol benzoate
20587-61-5

diethylene glycol benzoate

2-(2-chloroethoxy)ethyl benzoate
91427-49-5

2-(2-chloroethoxy)ethyl benzoate

Conditions
Conditions Yield
With pyridine; thionyl chloride;
benzoyl chloride
98-88-4

benzoyl chloride

2-(2-chloroethoxy)ethyl benzoate
91427-49-5

2-(2-chloroethoxy)ethyl benzoate

Conditions
Conditions Yield
With zinc(II) chloride;
sodium benzoate
532-32-1

sodium benzoate

3-oxa-1,5-dichloropentane
111-44-4

3-oxa-1,5-dichloropentane

2-(2-chloroethoxy)ethyl benzoate
91427-49-5

2-(2-chloroethoxy)ethyl benzoate

Conditions
Conditions Yield
at 140 ℃;
sodium benzoate
532-32-1

sodium benzoate

3-oxa-1,5-dichloropentane
111-44-4

3-oxa-1,5-dichloropentane

diethyleneglycol dibenzoate
120-55-8,9004-86-8

diethyleneglycol dibenzoate

2-(2-chloroethoxy)ethyl benzoate
91427-49-5

2-(2-chloroethoxy)ethyl benzoate

Conditions
Conditions Yield
With diethylamine; at 140 ℃;
benzoyl chloride
98-88-4

benzoyl chloride

(E)-3-Ureido-but-2-enoic acid ethyl ester
5435-44-9,22243-66-9

(E)-3-Ureido-but-2-enoic acid ethyl ester

1,2-ethanediol, dibenzoate
94-49-5,9004-86-8

1,2-ethanediol, dibenzoate

2-chloroethyl benzoate
939-55-9

2-chloroethyl benzoate

2-(2-chloroethoxy)ethyl benzoate
91427-49-5

2-(2-chloroethoxy)ethyl benzoate

Conditions
Conditions Yield

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